Spectroscopic Properties of Tb3+ Doped Silicate Glass Ceramics Containing SrF2 Nanocrystals

QIAN Shan; JIA Shi-jie; HUANG Li-hui; ZHAO Shi-long; XU Shi-qing

doi:10.3788/fgxb20173807.0849

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Spectroscopic Properties of Tb³⁺ Doped Silicate Glass Ceramics Containing SrF₂ Nanocrystals

更新时间：2020-08-12

- Spectroscopic Properties of Tb³⁺ Doped Silicate Glass Ceramics Containing SrF₂ Nanocrystals
- Chinese Journal of Luminescence Vol. 38, Issue 7, Pages: 849-854(2017)
- 作者机构：
  
  中国计量大学材料科学与工程学院,浙江杭州,310018
- 作者简介：
- 基金信息：
  
  Supported by National Natural Science Foundation of China (11375166,51372236)
- DOI：10.3788/fgxb20173807.0849
  CLC： O482.31
- Received：02 February 2017，
  
  Revised：08 March 2017，
  
  Published：05 July 2017
- 稿件说明：
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钱珊, 贾世杰, 黄立辉等. Tb3+掺杂含SrF2纳米晶硅酸盐微晶玻璃的光谱性质[J]. 发光学报, 2017,38(7): 849-854

QIAN Shan, JIA Shi-jie, HUANG Li-hui etc. Spectroscopic Properties of Tb3+ Doped Silicate Glass Ceramics Containing SrF2 Nanocrystals[J]. Chinese Journal of Luminescence, 2017,38(7): 849-854
钱珊, 贾世杰, 黄立辉等. Tb3+掺杂含SrF2纳米晶硅酸盐微晶玻璃的光谱性质[J]. 发光学报, 2017,38(7): 849-854 DOI： 10.3788/fgxb20173807.0849.

QIAN Shan, JIA Shi-jie, HUANG Li-hui etc. Spectroscopic Properties of Tb3+ Doped Silicate Glass Ceramics Containing SrF2 Nanocrystals[J]. Chinese Journal of Luminescence, 2017,38(7): 849-854 DOI： 10.3788/fgxb20173807.0849.

摘要

通过高温熔融法和后续热处理制得Tb

掺杂含SrF

纳米晶的透明硅酸盐微晶玻璃。利用X射线衍射（XRD）、透射电子显微镜（TEM）、紫外可见透过光谱、荧光光谱、荧光寿命和X射线激发发光光谱（XEL）探讨了基础玻璃和微晶玻璃的结构和光谱特性。XRD结果表明，玻璃中析出晶体为SrF

纳米晶，衍射峰随着热处理温度的升高和时间的延长而逐渐明显，晶粒也随热处理温度的升高和时间的延长越来越大。在376 nm紫外光和X射线激发下，与基础玻璃相比，微晶玻璃发光显著增强，且发光强度随热处理温度的升高和时间的延长而逐渐增强。

Abstract

doped transparent fluorosilicate glass ceramics containing SrF

nanocrystals were prepared by melt-quenching method with subsequent heat treatment. The structure and luminescence properties of the as-made glass and glass-ceramics were investigated by X-ray diffraction(XRD)

transmission electron microscope(TEM)

transmittance spectra

photoluminescence spectra

fluorescence lifetime and X-ray excited luminescence spectra(XEL). The XRD results show that the precipitated crystalline in the glass matrix is SrF

nanocrystal. The diffraction peaks become obvious and the crystal gradually increases with the increasing of the heat treatment temperature and time. Under 376 nm light and X-ray

much more intense emissions are observed in Tb

doped oxyfluoride glass ceramics containing SrF

nanocrystals compared with the as-made glass. With the increasing of the heat-treatment temperature and time

the emission intensities are enhanced.

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references

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