Effect of Lithium Ion on The Up-conversion Efficiency of Yb3+ and Tm3+ in Silicate Glass

SU Jun; LI Cong; ZHANG Zhen-hua; ZHAO Hui-feng; JIANG Hong

doi:10.3788/fgxb20173804.0430

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Effect of Lithium Ion on The Up-conversion Efficiency of Yb³⁺ and Tm³⁺ in Silicate Glass

更新时间：2020-08-12

- Effect of Lithium Ion on The Up-conversion Efficiency of Yb³⁺ and Tm³⁺ in Silicate Glass
- Chinese Journal of Luminescence Vol. 38, Issue 4, Pages: 430-434(2017)
- 作者机构：
  
  1. 海南中航特玻科技有限公司, 海南海口 571924
  2. 海南省特种玻璃重点实验室海南大学,海南海口,570228
  3. 特种玻璃国家重点实验室海南中航特玻材料有限公司,海南海口,571924
- 作者简介：
- 基金信息：
  
  Supported by Special Program of Science and Technology of AVIC(TFKY2015002)
- DOI：10.3788/fgxb20173804.0430
  CLC： TQ171;O482.31
- Received：21 October 2016，
  
  Revised：23 November 2016，
  
  Published：05 April 2017
- 稿件说明：
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苏俊, 李聪, 张振华等. Li+对硅酸盐玻璃中Yb3+、Tm3+上转换效率的影响[J]. 发光学报, 2017,38(4): 430-434

SU Jun, LI Cong, ZHANG Zhen-hua etc. Effect of Lithium Ion on The Up-conversion Efficiency of Yb3+ and Tm3+ in Silicate Glass[J]. Chinese Journal of Luminescence, 2017,38(4): 430-434
苏俊, 李聪, 张振华等. Li+对硅酸盐玻璃中Yb3+、Tm3+上转换效率的影响[J]. 发光学报, 2017,38(4): 430-434 DOI： 10.3788/fgxb20173804.0430.

SU Jun, LI Cong, ZHANG Zhen-hua etc. Effect of Lithium Ion on The Up-conversion Efficiency of Yb3+ and Tm3+ in Silicate Glass[J]. Chinese Journal of Luminescence, 2017,38(4): 430-434 DOI： 10.3788/fgxb20173804.0430.

摘要

利用高温熔融法制备了不同Li

含量的掺杂Yb

、Tm

的硅酸盐玻璃样品'玻璃样品在980 nm半导体激光器的泵浦下能够产生477 nm的蓝光和654 nm的红光。由上转换的荧光强度和泵浦功率的双对数拟合直线得到'添加Li

能够增加上转换过程中Tm

向上跃迁的几率'Tm

的

和

能级的粒子数布居增加'从而提高辐射跃迁的几率。红外光谱和拉曼光谱表明Li

的添加对玻璃基质的声子能量影响不大'却使得声子态密度减小'使上转换效率提高'从而提高Yb

、Tm

在硅酸盐玻璃中的发光强度。

Abstract

and Tm

co-doped silicate glasses with different contents of Li

were prepared by high temperature melting

which could emit 477 nm blue and 654 nm red light under 980 nm LD pumping. The double logarithmic linear fitting of light emission intensity and pump power show that the probability of Tm

upward transition in up-conversion process increases after the adding of Li

because of the number of electrons populated at

and

energy levels of Tm

increasing

which leads to improving the probability of radiation transition. The infrared spectra and Raman spectra show that the addition of Li

has little effect on phonon energy of the glass substrate

however

the density of phonon states decreases. Finally

the luminescence intensity of Yb

and Tm

in silicate glass is improved by increasing the up-conversion efficiency.

关键词

Keywords

references

AUZEL F. Up-conversion and Excited State Absorption in Laser Crystals and Glasses:Advantages and Disadvantages[M]. Di Bartolo B. Nonlinear Spectroscopy of Solids. New York:Springer, 1994:531-553.

姜永章, 夏海平, 张加忠, 等. 单晶体-NaYF4:Dy3+的制备及光谱特性[J]. 光子学报, 2015, 44(8):0816001. JIANG Y Z, XIA H P, ZHANG J Z, et al.. Growth and optical spectra of Dy3+ doped -NaYF4 single crystal[J]. Acta Photon. Sinica, 2015, 44(8):0816001. (in Chinese)

HALDER A, PAUL M C, HARUN S W, et al.. Visible and near infrared up-conversion luminescence in Yb3+/Tm3+ co-doped yttria-alumino-silicate glass based optical fibers[J]. J. Lumin., 2013, 143:393-401.

KAM C H, BUDDHUDU S. Near infrared to red and yellow to blue upconversion emissions from Pr3+:ZrF4-BaF2-LaF3-YF3-AlF3-NaF glasses[J]. J. Quant. Spectrosc. Radiat. Transfer, 2004, 85(1):1-12.

LAVN V, LAHOZ F, MARTN I R, et al.. Infrared-to-visible photon avalanche upconversion dynamics in Ho3+-doped fluorozirconate glasses at room temperature[J]. Opt. Mater., 2005, 27(11):1754-1761.

GONG H, LIN L, ZHAO X, et al.. Mixing up-conversion excitation behaviors in Er3+/Yb3+-codoped aluminum germanate glasses for visible waveguide devices[J]. J. Alloys Compd., 2010, 503(1):133-137.

ZHOU J J, CHEN G X, WU E, et al.. Ultrasensitive polarized up-conversion of Tm3+-Yb3+ doped -NaYF4 single nanorod[J]. Nano Lett., 2013, 13(5):2241-2246.

XU L, SONG B, XIAO S C, et al.. Up-conversion luminescence of Tm3+/Yb3+ co-doped oxy-fluoride glasses[J]. J. Rare Earths, 2010, 28(2):194-197.

SUYVER J F, AEBISCHER A, GARCA-REVILLA S, et al.. Anomalous power dependence of sensitized upconversion luminescence[J]. Phys. Rev. B, 2005, 71(12):125123.

于晓波, 赵昕, 李长敏, 等. 光学玻璃最大声子能量的红外光谱估算[J]. 大连工业大学学报, 2008, 27(2):155-157. YU X B, ZHAO X, LI C M, et al.. Infrared spectrum estimation for maximum phonon energy in optical glasses[J]. J. Dalian Polytech. Univ., 2008, 27(2):155-157. (in Chinese)

SUN H T, YU C L, ZHOU G, et al.. Up-conversion luminescence analysis in ytterbium-sensitized erbium-doped oxide-halide tellurite and germanate-niobic-lead glasses[J]. Spectrochim. Acta Part A:Mol. Biomol. Spectrosc., 2005, 62(4-5):1000-1003.

PAN Z D, MORGAN S H, DYER K, et al.. Host-dependent optical transitions of Er3+ ions in lead-germanate and lead-tellurium-germanate glasses[J]. J. Appl. Phys., 1996, 79(12):8906-8913.

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