Near-infrared Quantum Cutting of Sr3Al2O6: Tb3+, Yb3+ Phosphors

LIU Yan-hua; BAI Wen-xia; GENG Zhong-rong; FENG Li-bang

doi:10.3788/fgxb20173804.0423

您当前的位置：

首页 >

文章列表页 >

Near-infrared Quantum Cutting of Sr₃Al₂O₆: Tb³⁺, Yb³⁺ Phosphors

更新时间：2020-08-12

- Near-infrared Quantum Cutting of Sr₃Al₂O₆: Tb³⁺, Yb³⁺ Phosphors
- Chinese Journal of Luminescence Vol. 38, Issue 4, Pages: 423-429(2017)
- 作者机构：
  
  兰州交通大学机电工程学院,甘肃兰州,730070
- 作者简介：
- 基金信息：
  
  Supported by Youth Science Foundation of Lanzhou Jiaotong University(2012015)
- DOI：10.3788/fgxb20173804.0423
  CLC： TP394.1;O482.31
- Received：23 October 2016，
  
  Revised：29 November 2016，
  
  Published：05 April 2017
- 稿件说明：
移动端阅览
刘艳花, 拜文霞, 耿中荣等. Sr3Al2O6：Tb3+，Yb3+荧光粉的近红外量子剪裁效应[J]. 发光学报, 2017,38(4): 423-429

LIU Yan-hua, BAI Wen-xia, GENG Zhong-rong etc. Near-infrared Quantum Cutting of Sr3Al2O6: Tb3+, Yb3+ Phosphors[J]. Chinese Journal of Luminescence, 2017,38(4): 423-429
刘艳花, 拜文霞, 耿中荣等. Sr3Al2O6：Tb3+，Yb3+荧光粉的近红外量子剪裁效应[J]. 发光学报, 2017,38(4): 423-429 DOI： 10.3788/fgxb20173804.0423.

LIU Yan-hua, BAI Wen-xia, GENG Zhong-rong etc. Near-infrared Quantum Cutting of Sr3Al2O6: Tb3+, Yb3+ Phosphors[J]. Chinese Journal of Luminescence, 2017,38(4): 423-429 DOI： 10.3788/fgxb20173804.0423.

摘要

硅材料带隙与太阳光子光谱的失配导致了比较严重的光子损失'大大降低了硅太阳能电池的效率。为了减少入射光子的损失'可以利用具有近红外量子剪裁效应的光谱转换材料来提高硅太阳能电池的效率。本研究采用溶胶凝胶法制备了Sr

：Tb

'Yb

荧光粉'并研究了其近红外量子剪裁效应。实验结果表明：在320 nm的紫外光激发下'Sr

：Tb

'Yb

荧光粉发射出Tb

：

的可见光；另外'由于Tb

、Yb

离子之间的合作能量传递'得到了Yb

：

5/2

7/2

的近红外发光。荧光寿命衰减证明Tb

到Yb

之间的确存在合作能量传递'而且存在量子剪裁效应'其中'能量传递效率为35.9%'量子剪裁效率为135.9%。由于Yb

的发射光谱与硅太阳能电池的吸收匹配'Sr

：Tb

'Yb

荧光粉有可能作为潜在的光谱转换材料应用于硅太阳能电池以提高其光电转换效率。

Abstract

The mismatch between band gap of silicon cell and solar spectra results in serious loss of energy

which greatly reduces the efficiency of silicon solar cell. In order to decrease the loss of incident photons like ultraviolet (UV) photons

the photoluminescence materials with near-infrared (NIR) quantum cutting (QC) effect can be used as spectra transformation materials to enhance the efficiency of silicon solar cells. As a novel kind of efficient NIR quantum cutting material

:Tb

phosphors promising for silicon solar cells were successfully prepared using sol-gel method. The luminescence properties of Sr

:Tb

were investigated using photoluminescence (PL) spectra and decay lifetime curves. The results show that the phosphors can emit visible light of Tb

under the excitation of 320 nm

while NIR light is emitted by Yb

5/2

7/2

through cooperative energy transfer from one Tb

ion to two Yb

ions. Decay lifetimes of Tb

and quantum efficiency (QE) were studied for Sr

:Tb

and Sr

:Tb

. The results show that there is effective cooperative energy transfer from Tb

to Yb

in which maximum energy transfer efficiency (ETE) and the corresponding quantum efficiency are estimated to be 35.9% and 135.9%

respectively. The results demonstrate that Sr

:Tb

phosphors are promising candidate for improving the efficiency of silicon based solar cell by means of down-conversion.

关键词

Keywords

references

WEGH R T, DONKER H, OSKAM K D, et al.. Visible quantum cutting in LiGdF4:Eu3+ through downconversion[J]. Science, 1999, 283(5402):663-666.

赵磊. 几类稀土氧化物发光材料中能量传递及量子剪裁现象的研究[D]. 兰州:兰州大学, 2015. ZHAO L. Energy Transfer and Quantum Cutting of Rare-earth-based Oxide Phosphors[D]. Lanzhou:Lanzhou University, 2015. (in Chinese)

RABOUW F T, MEIJERINK A. Modeling the cooperative energy transfer dynamics of quantum cutting for solar cells[J]. J. Phys. Chem. C, 2015, 119(5):2364-2370.

ZHANG Q Y, HUANG X Y. Recent progress in quantum cutting phosphors[J]. Prog. Mater. Sci., 2010, 55(5):353-427.

陈晓波, 杨国建, 张蕴芝, 等. 稀土材料红外多光子量子剪裁现象[J]. 光谱学与光谱分析, 2012, 32(10):2597-2600. CHEN X B, YANG G J, ZHANG Y Z, et al.. Infrared multiphoton quantum cutting phenomena of rare earth materials[J]. Spectrosc. Spect. Anal., 2012, 32(10):2597-2600. (in Chinese)

陈晓波, 周固, 周永芬, 等. 钒酸钇的基质施主合作能量传递导致的镱离子的近红外量子剪裁发光[J]. 光谱学与光谱分析, 2015, 35(2):315-319. CHEN X B, ZHOU G, ZHOU Y F, et al.. Near-infrared quantum cutting downconversion luminescence of Yb3+ ion cooperative energy transferred from YVO4 matrix donor[J]. Spectrosc. Spect. Anal., 2015, 35(2):315-319. (in Chinese)

ZHOU X J, WANG G C, ZHOU K N, et al.. Near-infrared quantum cutting in Pr3+/Yb3+ co-doped transparent tellurate glass via two step energy transfer[J]. Opt. Mater., 2013, 35(3):600-603.

李云青, 崔彩娥, 黄平, 等. Pr3+,Yb3+双掺的CaWO4荧光粉的近红外量子剪裁[J]. 光子学报, 2015, 44(7):0716001-1-5. LI Y Q, CUI C E, HUANG P, et al.. Near infrared quantum cutting in Pr3+,Yb3+ co-doped CaWO4 phosphors[J]. Acta Photon. Sinica, 2015, 44(7):0716001-1-5. (in Chinese)

LI J, ZHANG J H, ZHANG X, et al.. Cooperative downconversion and near infrared luminescence of Tm3+/Yb3+ codoped calcium scandate phosphor[J]. J. Alloys Compd., 2014, 583:96-99.

ZHANG Q Y, LIANG X F. Cooperative downconversion in Y3Al5O12:Re3+,Yb3+ (Re=Tb, Tm, and Pr) nanophosphors[J]. J. Soc. Inf. Disp., 2008, 16(7):755-758.

ZHAO J, GUO C F, LI T. Enhanced near-infrared emission by co-doping Ce3+ in Ba2Y(BO3)2Cl:Tb3+,Yb3+ phosphor[J]. RSC Adv., 2015, 5(36):28299-28304.

SUN J Y, CUI D P, SUN G C, et al.. Near-infrared luminescence and energy transfer in CaMoO4:Ho3+,Yb3+ phosphor[J]. J. Mater. Sci., 2014, 49(2):527-531.

徐嘉林, 金维召, 刘旺, 等. Ho,Yb:Tb3Ga5O12纳米粉体制备及发光性能研究[J]. 中国光学, 2015, 8(4):608-614. XU J L, JIN W Z, LIU W, et al.. Preparation and luminescent properties of Ho,Yb:Tb3Ga5O12 nano-powder[J]. Chin. Opt., 2015, 8(4):608-614. (in Chinese)

蔡淑珍, 刘琳琳, 李明明, 等. Er3+,Yb3+共掺杂的NaYF4荧光粉的制备及下转换发光研究[J]. 发光学报, 2014, 35(9):1058-1064. CAI S Z, LIU L L, LI M M, et al.. Synthesis and down-conversion luminescence of Er3+,Yb3+ codoped NaYF4 phosphors[J]. Chin. J. Lumin., 2014, 35(9):1058-1064. (in Chinese)

CHEN J D, GUO H, LI Z Q, et al.. Near-infrared quantum cutting in Ce3+,Yb3+ co-doped YBO3 phosphors by cooperative energy transfer[J]. Opt. Mater., 2010, 32(9):998-1001.

YANG Y M, LIU L L, LI M M, et al.. Near-infrared quantum cutting in Ce3+,Yb3+ doped Gd(PO3)3 phosphors[J]. Sci. Adv. Mater., 2015, 7(7):1304-1309.

BAI W X, LIU Y H, WANG Y P, et al.. Cooperative down-conversion and near-infrared luminescence of Tb3+-Yb3+ co-doped CaMoO4 broadband phosphor[J]. Ceram. Int., 2015, 41(10):12896-12900.

ZHANG P, XU M X, ZHENG Z T, et al.. Synthesis and characterization of europium-doped Sr3Al2O6 phosphors by sol-gel technique[J]. J. Sol-Gel Sci. Technol., 2007, 43(1):59-64.

张继森, 张立国, 任建岳, 等. Ce3+和Yb3+共掺杂的Y3Al5O12可见及量子剪裁近红外发光性质[J]. 发光学报, 2014, 35(8):891-896. ZHANG J S, ZHANG L G, REN J Y, et al.. Properties of visible and NIR emissions with quantum cutting in Ce3+-Yb3+-codoped Y3Al5O12 powder materials[J]. Chin. J. Lumin., 2014, 35(8):891-896. (in Chinese)

PAGE P, GHILDIYAL R, MURTHY K V R. Photoluminescence and thermoluminescence properties of Sr3Al2O6:Tb3+[J]. Mater. Res. Bull., 2008, 43(2):353-360.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Effect of Yb³⁺/Nd³⁺ Doped on Luminescent Properties of Sr₉Ga(PO₄)₇∶Cr³⁺

Luminescence and Energy Transfer of Tb³⁺ in K₃La（PO₄）₂

Tb³⁺ Doped Transparent Germanate Glass Ceramics: Preparation and Enhanced Luminescence for X-ray Detection

Upconversion Luminescence of Mn²⁺ in Yb³⁺-Mn²⁺ Codoped CaF₂ Materials

Luminescent Properties of Rare Earth Ions Doped LaAlO₃:RE³⁺ (RE=Eu, Tb, Sm, Tm) Phosphors

Related Author

XIE Xin

GE Wanyin

ZHANG Qian

YANG Maohao

WU Chenge

HE Peng

YIN Honglei

OU Yi-yi

Related Institution

School of Materials Science and Engineering， Shaanxi University of Science and Technology

Department of Physics & Astronomy， Georgia Southern University， Statesboro

School of Chemistry， Sun Yat-sen University

College of Materials and Chemistry, China Jiliang University

Institute of Optoelectronic Materials and Devices, China Jiliang University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰