Spectral Analysis of Ca/Zn-nano Carboxymethyl Chitosan

SUN Shuang; DONG Li-dan; WEI Chang-ping; LI Jing

doi:10.3788/fgxb20163712.1479

您当前的位置：

首页 >

文章列表页 >

Spectral Analysis of Ca/Zn-nano Carboxymethyl Chitosan

更新时间：2020-08-12

- Spectral Analysis of Ca/Zn-nano Carboxymethyl Chitosan
- Chinese Journal of Luminescence Vol. 37, Issue 12, Pages: 1479-1483(2016)
- 作者机构：
  
  长春理工大学化学与环境工程学院, 吉林长春 130022
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163712.1479
  CLC： O614.43+2
- Received：03 June 2016，
  
  Revised：14 July 2016，
  
  Published：10 December 2016
- 稿件说明：
移动端阅览
孙双, 董丽丹, 魏长平等. Ca/Zn-纳米羧甲基壳聚糖的光谱分析[J]. 发光学报, 2016,37(12): 1479-1483

SUN Shuang, DONG Li-dan, WEI Chang-ping etc. Spectral Analysis of Ca/Zn-nano Carboxymethyl Chitosan[J]. Chinese Journal of Luminescence, 2016,37(12): 1479-1483
孙双, 董丽丹, 魏长平等. Ca/Zn-纳米羧甲基壳聚糖的光谱分析[J]. 发光学报, 2016,37(12): 1479-1483 DOI： 10.3788/fgxb20163712.1479.

SUN Shuang, DONG Li-dan, WEI Chang-ping etc. Spectral Analysis of Ca/Zn-nano Carboxymethyl Chitosan[J]. Chinese Journal of Luminescence, 2016,37(12): 1479-1483 DOI： 10.3788/fgxb20163712.1479.

摘要

以壳聚糖为原料，经羧甲基化、纳米化与Ca

、Zn

复合制备出纳米羧甲基壳聚糖含钙、锌复合物，采用红外光谱、X射线衍射光谱、扫描电镜等光学手段对样品进行结构表征，考察了复合物的凝血、止血性能。结果表明：纳米羧甲基壳聚糖结构中含有磷酸盐结构，Ca/Zn-纳米羧甲基壳聚糖结构中含有Ca

与Zn

，Ca

和Zn

与纳米羧甲基壳聚糖成功复合；复合物的结晶性下降、溶解性提高、形貌均匀圆整，且凝血、止血时间明显缩短；Ca-纳米羧甲基壳聚糖比Zn-纳米羧甲基壳聚糖结构更稳定，凝血、止血效果更好。

Abstract

With chitosan as raw material

Ca/Zn-nano carboxymethyl chitosan complexing was prepared through carboxymethylation

nanocrystallization and complexing with Ca

. The structure was characterized by infrared spectroscopy

X-ray diffraction spectroscopy and scanning electron microscopy. The properties of coagulation and hemostatic were investigated. The results show that the polyphosphate structure is contained in nano carboxymethyl chitosan

as Ca

and Zn

are contained in Ca/Zn-nano carboxymethyl chitosan. Ca

and Zn

compound successfully with nano carboxymethyl chitosan. The composite has lower crystallization

higher solubility

more uniform round morphology and significant shorter coagulation and hemostasis time. Compared with Zn-nano carboxymethyl chitosan

Ca-nano carboxymethyl chitosan is possessed better structure and better properties of coagulation and hemostasis.

关键词

Keywords

references

王姗,房喻,张颖,等. 壳聚糖-CdS复合膜制备及其对吡啶的传感特性[J]. 物理化学学报, 2003, 19(6):514-518. WANG S, FANG Y, ZHANG Y, et al.. Preparation of chitosan/Cds composite films and their sensing properties to pyridine[J]. Acta Phys. Chim. Sinica, 2003, 19(6):514-518. (in Chinese)

程沁园. 壳聚糖止血活性及其生物安全性评价研究[D]. 无锡:江南大学, 2013. CHENG Q Y. The Hemostatic Activity and Biological Safety Evaluation of Chitosan[D]. Wuxi:Jiangnan University, 2013. (in Chinese)

尹刚. 温敏性壳聚糖止血膜止血作用的实验研究[D]. 上海:第二军医大学, 2014. YIN G. Experimental Study on Hemostasis of Thermosensitive Chitosan Hemostatic Film[D]. Shanghai:Second Military Medical University, 2014. (in Chinese)

WANG D S, LI J G, LI H P, et al.. Preparation and drug releasing property of magnetic chitosan-5-fluorouracil nano-particles[J]. Trans. Nonferrous Met. Soc. China, 2009, 19(5):1232-1236.

王志华,江阳阳,余晓华,等. 壳聚糖及其水溶性衍生物对小鼠免疫功能的影响[J]. 食品科学, 2016, 37(1):198-202. WANG Z H, JIANG Y Y, YU X H, et al.. Effect of chitosan and its water-soluble derivatives on immune function in mice[J]. Food Sci., 2016, 37(1):198-202. (in Chinese)

TUNGTONG S, OKONOGI S, CHOWWANAPOONPOHN S, et al.. Solubility, viscosity and rheological properties of water-soluble chitosan derivatives[J]. Maejo Int. J. Sci. Technol., 2012, 6(2):315-322.

郭苗苗,吴迪,刘辉,等. O-羧甲基壳聚糖止血海绵止血和愈创效果研究[J]. 中国药师, 2012, 15(11):1538-1544. GUO M M, WU D, LIU H, et al.. Studies on hemostatic and wound healing effect of O-carboxymethyl chitosan hemostatic sponges[J]. China Pharm., 2012, 15(11):1538-1544. (in Chinese)

马烽,陆丰艳,秦岩,等. N, O-羧甲基壳聚糖磁性复合微球的制备与表征[J]. 材料工程, 2014(8):41-45. MA F, LU F Y, QIN Y, et al.. N, O-preparation and characterization of carboxymethyl chitosan magnetic composite microspheres[J]. J. Mater. Eng., 2014(8):41-45. (in Chinese)

吴伟萍,彭承宏,韩宝三,等. 羧甲基壳聚糖在大鼠创伤出血模型的止血效果的观察[J]. 外科理论与实践, 2010, 15(3):240-244. WU W P, PENG C H, HAN B S, et al.. Hemostatic effect of O-carboxymethyl chitosan powder on the trauma surface in rats[J]. J. Surg. Concepts. Pract., 2010, 15(3):240-244. (in Chinese)

CAI W D, CHU J X, HAN B Q, et al.. Preparation and properties of carboxymethyl chitosan calcium[J]. J. Clin. Rehab. Tissue Eng. Res., 2010, 14(3):567-570.

LI J, WEI C P, WANG F M, et al.. Study on the preparation and performance of carboxymethyl chitosan calcium and carboxymethyl chitosan zinc composite materials[J]. Mater. Sci. Forum, 2016, 852:1319-1324.

丁寅. 高分子无机纳米粒子复合造影材料的研究[D]. 南京:南京大学, 2009. DING Y. Inorganic Nanoparticle Composite Polymer Materials Contrast[D]. Nanjing:Nanjing University, 2009. (in Chinese)

Views

327

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Sensing Properties of Chitosan Derivatives-based Polymer Carbon Dots to Pd²⁺

Hydrothermal Preparation of Chitosan Carbon Dots and Their Selectivity to Metal Ions

Synthesis of Amphiphilic Polymer Carbon Dots Fluorescence Materials from Octyl Chitosan and Their Applications in Drug Delivery

Synthesis and Spectral Properties of Naphthalimide Grafted Chitosan Fluorescent Probe for Aluminum Ion

Synthesis of Chitosan-based Polymer Carbon Dots Fluorescent Materials and Their UV Aging Resistance Properties for Paper

Related Author

YU Shu-juan

YUAN Guang-zhi

WANG Feng

LU Shi-yan

LI Yuan-yuan

TANG Li-rong

WANG Xue-qin

HONG Bi-yun

Related Institution

Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials, Nanning Normal University

College of Material Engineering, Fujian Agriculture and Forestry University

Jinshan College of Fujian Agriculture and Forestry University

College of Chemistry and Materials Science, Guangxi Teachers Education University

College of Chemistry and Chemical Engineering, Xianyang Normal University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰