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Upconversion Fluorescence Photon Generation and Quantum Yield Quantification of Tm3+ in Waveguide-typed Aluminum Germanate Glasses
- Chinese Journal of Luminescence Vol. 37, Issue 12, Pages: 1471-1478(2016)
- 作者机构：
1. 大连工业大学 纺织与材料工程学院, 辽宁 大连 116034
2. 大连工业大学 信息科学与工程学院, 辽宁 大连 116034
- 作者简介：
- 基金信息：
DOI：10.3788/fgxb20163712.1471
CLC： TQ171;O482.31Received：11 July 2016，
Revised：15 September 2016，
Published：10 December 2016
- 稿件说明：
移动端阅览
朱彩玲, 林海, 王志强等. 波导适用型铝锗酸盐玻璃中铥离子上转换荧光光子输出与量子产率定量[J]. 发光学报, 2016,37(12): 1471-1478
ZHU Cai-ling, LIN Hai, WANG Zhi-qiang etc. Upconversion Fluorescence Photon Generation and Quantum Yield Quantification of Tm<sup>3+</sup> in Waveguide-typed Aluminum Germanate Glasses[J]. Chinese Journal of Luminescence, 2016,37(12): 1471-1478
朱彩玲, 林海, 王志强等. 波导适用型铝锗酸盐玻璃中铥离子上转换荧光光子输出与量子产率定量[J]. 发光学报, 2016,37(12): 1471-1478 DOI： 10.3788/fgxb20163712.1471.
ZHU Cai-ling, LIN Hai, WANG Zhi-qiang etc. Upconversion Fluorescence Photon Generation and Quantum Yield Quantification of Tm<sup>3+</sup> in Waveguide-typed Aluminum Germanate Glasses[J]. Chinese Journal of Luminescence, 2016,37(12): 1471-1478 DOI： 10.3788/fgxb20163712.1471.
摘要
制备了适用于钾钠离子交换波导的Tm
3+
/Yb
3+
掺杂铝锗酸盐玻璃，利用积分球配以光纤光谱仪在975 nm激光泵浦下对玻璃的上转换荧光进行测试，解析出样品的绝对荧光特征参量。测试与计算结果显示，在380℃的KNO
3
熔盐中，Tm
3+
/Yb
3+
掺杂的铝锗酸盐玻璃的钾钠离子交换有效扩散系数为0.070 m
2
/min，热离子交换过程易于控制。铝锗酸盐玻璃样品中，Tm
3+
主要发出477 nm蓝光和806 nm近红外光，其中近红外光为支配性发射。绝对荧光参数和激发功率密度呈正相关，当功率密度达到1 482 W/cm
2
时，三光子上转换蓝光的绝对光谱功率、净发射光子数和量子产率分别为269 W、6.4610
14
/s和1.4310
-4
，双光子近红外光上转换对应的3个参量分别为4 024 W、1.6310
16
/s和3.6110
-3
。基于波导适用型铝锗酸盐玻璃中Tm
3+
上转换荧光的绝对化表征，为进一步研发光电子器件和激光材料提供了有益的数据参考。
Abstract
Tm
3+
/Yb
3+
doped aluminum germanate glasses adapting for K
+
-Na
+
ion-exchanged waveguide were fabricated. Absolute characteristic parameters for upconversion (UC) fluorescence of glass samples were measured by integrating sphere coupled with fiber optic spectrometer under the excitation of 975 nm pump laser. The measurement and calculation results show that the effective diffusion coefficient of K
+
-Na
+
thermal ion-exchange is 0.070 m
2
/min when Tm
3+
/Yb
3+
doped aluminum germanate glasses are immersed in KNO
3
molten salt at 380℃
indicating that the K
+
-Na
+
ion-exchange process is controllable. Tm
3+
in aluminum germanate glasses emits 477 nm blue and 806 nm near-infrared (NIR) fluorescence
and the NIR emission plays a dominant role. The absolute fluorescence parameter is identified as a positive correlation with laser power density. When the power density is 1 482 W/cm
2
the emission spectral power
emission photon and quantum yield for blue three-photon UC fluorescence are 269 W
6.4610
14
/s and 1.4310
-4
and the ones for NIR two-photon UC fluorescence are 4 024 W
1.6310
16
/s and 3.6110
-3
respectively. The absolute characterization for UC fluorescence of Tm
3+
in waveguide-typed aluminum germanate glasses provides a valuable reference in developing photoelectronic devices and laser materials.
关键词
Keywords
references
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