Fluorescence Property of Non-crystal CS/RB Nano-films

ZHAI Xiao-yu; PAN Liang-liang; DING Yu-feng; LI Si-qi; XIONG Qing-yun; WANG Jing; JIANG Bi

doi:10.3788/fgxb20163711.1353

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Fluorescence Property of Non-crystal CS/RB Nano-films

更新时间：2020-08-12

- Fluorescence Property of Non-crystal CS/RB Nano-films
- Chinese Journal of Luminescence Vol. 37, Issue 11, Pages: 1353-1359(2016)
- 作者机构：
  
  1. 北京化工大学理学院, 材料科学与工程学院北京,100029
  2. Department of Chemistry, SUNY Stony Brook University, Stony Brook, NY 11794-3400, USA
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163711.1353
  CLC： O484.4
- Received：23 June 2016，
  
  Revised：14 July 2016，
  
  Published：05 November 2016
- 稿件说明：
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翟晓宇, 潘靓靓, 丁玉凤等. 非晶CS/RB纳米薄膜的荧光性质[J]. 发光学报, 2016,37(11): 1353-1359

ZHAI Xiao-yu, PAN Liang-liang, DING Yu-feng etc. Fluorescence Property of Non-crystal CS/RB Nano-films[J]. Chinese Journal of Luminescence, 2016,37(11): 1353-1359
翟晓宇, 潘靓靓, 丁玉凤等. 非晶CS/RB纳米薄膜的荧光性质[J]. 发光学报, 2016,37(11): 1353-1359 DOI： 10.3788/fgxb20163711.1353.

ZHAI Xiao-yu, PAN Liang-liang, DING Yu-feng etc. Fluorescence Property of Non-crystal CS/RB Nano-films[J]. Chinese Journal of Luminescence, 2016,37(11): 1353-1359 DOI： 10.3788/fgxb20163711.1353.

摘要

采用低真空物理气相沉积法制备单组份氰基对称二苯代乙烯（CS）纳米薄膜和罗丹明B（RB）纳米薄膜以及CS/RB叠层纳米薄膜。使用荧光分光光度计、X射线衍射仪（XRD）和扫描电子显微镜（SEM）表征薄膜样品的荧光性质、结构和表面形貌。与粉末晶态样品相比，薄膜样品的荧光发射峰数量变多，发射波长范围拓宽到120nm。有机小分子的非晶聚集态和纳米叠层结构的的纳米效应导致了样品的荧光性质的变化。

Abstract

Single-component CS and RB nano-films and two-component CS/RB nano-films were fabricated by low vacuum physical vapor deposition (LVPVD) method. Fluorospectro photometer

XRD and SEM were used to characterize the fluorescence

structure and surface morphology of the nano-films. Compared with the powder samples

the fluorescence emission peaks of the nano-films are more

the full widths at half-maximum of the peaks are larger

and the emission wavelength range exceeds 120 nm. The novel fluorescence of the nano-films is caused by the non-crystal state of aggregation of organic low-weight molecules and the effect of the nano layered structure.

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Keywords

references

FRIEND R H, GYMER R W, HOLMES A B, et al.. Electroluminescence in conjugated polymers [J]. Nature, 1999, 397(6715):121-128.

TU S, KIM S H, JOSEPH J, et al.. Self-assembly of a donor-acceptor nanotube. A strategy to create bicontinuous arrays [J]. J. Am. Chem. Soc., 2011, 133(47):19125-19130.

YANAGI H, OHARA T, MORIKAWA T. Self-waveguided gain-narrowing of blue light emission from epitaxially oriented p-sexiphenyl crystals [J]. Adv. Mater., 2001, 13(19):1452.

O'CARROLL D, LIEBRWIRTH I, REDMOND G. Microcavity effects and optically pumped lasing in single conjugated polymer nanowires [J]. Nat. Nanotechnol., 2007, 2(3):180-184.

ZHAO Y S, FU H, PENG A, et al.. Low-dimensional nanomaterials based on small organic molecules: preparation and optoelectronic properties [J]. Adv. Mater., 2008, 20(15):2859-2876.

SHI C, GUO Z, YAN Y, et al.. Self-assembly solid-state enhanced red emission of quinolinemalononitrile: optical waveguides and stimuli response [J]. ACS Appl. Mater. & Interf., 2013, 5(1):192-198.

CHE Y, ZANG L. Enhanced fluorescence sensing of amine vapor based on ultrathin nanofibers [J]. Chem. Commun., 2009, 34(34):5106-5108.

NING Z, CHEN Z, ZHANG Q, et al.. Aggregation-induced emission (AIE)-active starburst triarylamine fluorophores as potential non-doped red emitters for organic light-emitting diodes and Cl2 gas chemodosimeter [J]. Adv. Funct. Mater., 2007, 17(18):3799-3807.

SAGARA Y, KATO T. Mechanically induced luminescence changes in molecular assemblies [J]. Nat. Chem., 2009, 1(8):605-610.

YAN D, LU J, MA J, et al.. Layered host-guest materials with reversible piezochromic luminescence [J]. Angew. Chem. Int. Ed., 2011, 50(31):7037-7040.

YAN D, LU J, MA J, et al.. Reversibly thermochromic, fluorescent ultrathin films with a supramolecular architecture [J]. Angew. Chem. Int. Ed., 2011, 50(3):720-723.

STRASSERT C A, CHEN-HAN C, GALVEZ LOPEZ M D, et al.. Switching on luminescence by the self-assembly of a Platinum(Ⅱ) complex into gelating nanofibers and electroluminescent films [J]. Angew. Chem. Int. Ed., 2011, 50(4):946-950.

MUTAI T, SATOU H, ARAKI K. Reproducible on-off switching of solid-state luminescence by controlling molecular packing through heat-mode interconversion [J]. Nat. Mater., 2005, 4(9):685-687.

ZHAO Y, GAO H, FAN Y, et al.. Thermally induced reversible phase transformations accompanied by emission switching between different colors of two aromatic-amine compounds [J]. Adv. Mater., 2009, 21(31):3165-3169.

ZHANG Z, XU B, SU J, et al.. Color-tunable solid-state emission of 2,2'-biindenyl-based fluorophores[J]. Angew. Chem. Int. Ed., 2011, 50(49):11654-11657.

HIRATA S, TOTANI K, ZHANG J, et al.. Efficient persistent room temperature phosphorescence in organic amorphous materials under ambient conditions [J]. Adv. Funct. Mater., 2013, 23(27):3386-3397.

LEHN J M. Supramolecular Chemistry: Concepts and Perspectives [M]. New York: VCH, 1995.

GAUTAM R. DESIRAJU. Supramolecular synthons in crystal engineeringa new organic synthesis [J]. Angew. Chem. Int. Ed., 1995, 34(21):2311-2327.

NANGIA A. Crystal engineering-inclusion compounds, molecular networks, cocrystals, and polymorphs [J]. Cryst. Growth & Design, 2008, 8(4):1079-1081.

FRISCIC T, MACGILLIVRAY L R. Modularity in organic solid state and supramolecular chemistry [J]. Croat. Chem. Acta, 2006, 79(2):327.

MACGILLIVRAY L R, PANAEFSTATHIOU G S, FRISCIC T, et al.. Supramolecular control of reactivity in the solid state: from templates to ladderanes to metal-organic frameworks [J]. Acc. Chem. Res., 2008, 41(2):280-291.

殷子文,康艺馨,赵赫,等. 多层纳米Au/DPO薄膜的荧光特性 [J]. 发光学报, 2014, 35(8):964-968. YIN Z W, KANG Y X, ZHAO H, et al.. Fluorescence characteristics of multi-layer nano-Au /DPO film [J]. Chin. J. Lumin., 2014, 35(8):964-968. (in Chinese)

ZHANG C, ZOU C L, YAN Y, et al.. Two-photon pumped lasing in single-crystal organic nanowire exciton polariton resonators [J]. J. Am. Chem. Soc., 2011, 133(19):7276-7279.

KUNZELMAN J, KINAMI M, CRENSHAW B, et al.. Oligo(p-phenylene vinylene)s as a "new" class of piezochromic fluorophores [J]. Adv. Mater., 2008, 20(1):119-122.

YAN D, DELORI A, PATEL B, et al.. Ultrasound-assisted construction of halogen-bonded nanosized cocrystals that exhibit thermosensitive luminescence [J]. Chemistry, 2013, 19(25):8213-8219.

BALAKRISHNAN K, DATAR A, OITKER R, et al.. Nanobelt self-assembly from an organic n-type semiconductor: propoxyethyl-PTCDI [J]. J. Am. Chem. Soc., 2005, 127(30):10496-10497.

HUO L, ZHANG S, GUO X, et al.. Replacing Alkoxy groups with Alkylthienyl groups: a feasible approach to improve the properties of photovoltaic polymers [J]. Angew. Chem. Int. Ed., 2011, 50(41):9697-9702.

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