Synthesis and Luminescence Properties of Tb<sup>3+</sup> Doped Sodalite Fluorescent Phosphor

Ayituerxun·ABUDUREYIMU; HE Jiu-yang; Aierken·SIDIKE

doi:10.3788/fgxb20163706.0676

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Synthesis and Luminescence Properties of Tb³⁺ Doped Sodalite Fluorescent Phosphor

更新时间：2020-08-12

- Synthesis and Luminescence Properties of Tb³⁺ Doped Sodalite Fluorescent Phosphor
- Chinese Journal of Luminescence Vol. 37, Issue 6, Pages: 676-681(2016)
- 作者机构：
  
  1. 新疆师范大学物理与电子工程学院, 新疆乌鲁术齐,830054
  2. 新疆矿物发光材料及其微结构实验室, 新疆乌鲁术齐,830054
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163706.0676
  CLC： O482.31
- Received：25 January 2016，
  
  Revised：16 March 2016，
  
  Published：05 June 2016
- 稿件说明：
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阿依吐尔逊·,阿布都热依穆, 何久洋等. Tb³⁺掺杂方钠石荧光粉的制备及发光性质研究[J]. 发光学报, 2016,37(6): 676-681

Ayituerxun·,ABUDUREYIMU, HE Jiu-yang etc. Synthesis and Luminescence Properties of Tb³⁺ Doped Sodalite Fluorescent Phosphor[J]. Chinese Journal of Luminescence, 2016,37(6): 676-681
阿依吐尔逊·,阿布都热依穆, 何久洋等. Tb³⁺掺杂方钠石荧光粉的制备及发光性质研究[J]. 发光学报, 2016,37(6): 676-681 DOI： 10.3788/fgxb20163706.0676.

Ayituerxun·,ABUDUREYIMU, HE Jiu-yang etc. Synthesis and Luminescence Properties of Tb³⁺ Doped Sodalite Fluorescent Phosphor[J]. Chinese Journal of Luminescence, 2016,37(6): 676-681 DOI： 10.3788/fgxb20163706.0676.

摘要

采用高温固相法制备了一系列Tb

掺杂方钠石荧光粉样品Na

:Tb

。通过XRD、SEM、荧光光谱、热猝灭分析仪对样品的晶体结构及其发光性能进行研究。样品晶粒由大小不等、形状不规则的多面体块状颗粒构成。样品在242nm(对应于Tb

离子自旋允许的

跃迁)激发下发出单色性能较好的绿色荧光

相应的色坐标为(0.3240

0.5872)

色纯度为87.4%

发光量子效率为0.74。随着Tb

掺杂浓度的增加

出现浓度猝灭现象。当浓度为5%时

样品的绿色荧光最强。研究结果表明

样品满足PDP器件的使用要求

可作为三基色材料中的绿色组分。

Abstract

A series of Na

%Tb

(

9) phosphors were synthesized under a weak reducing atmosphere by traditional solid state reaction. The crystal structure and luminescence properties of the samples were studied by XRD

SEM

fluorescence spectra and thermal break out analyzer. The samples are composed of plane particle which are different size and irregular polyhedron structure. The samples can be excited efficiently by 242 nm (corresponding to the transition

in Tb

) and emit green fluorescence with better monchromaticity. The color coordinate of the green fluorescence is (0.324 0

0.587 2)

the color purity is 87.4%

and the luminescent quantum efficiency is 0.74. With the increasing of Tb

doping concentration

the concentration quenching phenomenon occurs. When the concentration is 5%

the strongest Tb

green emission can be realized. The results show that the samples may meet the use requirements of PDP device

and can be used as the green group of the tri-phosphor materials.

关键词

Keywords

references

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⁰

Synthesis and Luminescence Properties of Tb3+ Doped Sodalite Fluorescent Phosphor

DOI：10.3788/fgxb20163706.0676

摘要

Abstract

关键词

Keywords

references

Synthesis and Luminescence Properties of Tb³⁺ Doped Sodalite Fluorescent Phosphor