One-step Synthesis of Sulfur- and Nitrogen-co-doped Carbon Quantum Dots for Fe(Ⅲ) Detection

ZHANG Wen-yu; CHANG Qing; ZHOU Yu-feng; WEI Zhi-jia; LI Kai-kai; HU Sheng-liang

doi:10.3788/fgxb20163704.0410

您当前的位置：

首页 >

文章列表页 >

One-step Synthesis of Sulfur- and Nitrogen-co-doped Carbon Quantum Dots for Fe(Ⅲ) Detection

更新时间：2020-08-12

- One-step Synthesis of Sulfur- and Nitrogen-co-doped Carbon Quantum Dots for Fe(Ⅲ) Detection
- Chinese Journal of Luminescence Vol. 37, Issue 4, Pages: 410-415(2016)
- 作者机构：
  
  中北大学材料科学与工程学院,山西太原,030051
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163704.0410
  CLC： 0657;O613
- Received：18 December 2015，
  
  Revised：20 January 2016，
  
  Published：05 April 2016
- 稿件说明：
移动端阅览
张文宇, 常青, 周雨锋等. 一步合成硫、氮共掺杂的碳量子点及其在Fe<sup>3+</sup>检测中的应用[J]. 发光学报, 2016,37(4): 410-415

ZHANG Wen-yu, CHANG Qing, ZHOU Yu-feng etc. One-step Synthesis of Sulfur- and Nitrogen-co-doped Carbon Quantum Dots for Fe(Ⅲ) Detection[J]. Chinese Journal of Luminescence, 2016,37(4): 410-415
张文宇, 常青, 周雨锋等. 一步合成硫、氮共掺杂的碳量子点及其在Fe<sup>3+</sup>检测中的应用[J]. 发光学报, 2016,37(4): 410-415 DOI： 10.3788/fgxb20163704.0410.

ZHANG Wen-yu, CHANG Qing, ZHOU Yu-feng etc. One-step Synthesis of Sulfur- and Nitrogen-co-doped Carbon Quantum Dots for Fe(Ⅲ) Detection[J]. Chinese Journal of Luminescence, 2016,37(4): 410-415 DOI： 10.3788/fgxb20163704.0410.

摘要

碳量子点的光致发光性质不仅决定于尺寸还依赖于它的表面态

因此通过在碳量子点表面掺杂或嫁接不同元素与基团有望调节它的荧光发射行为。为了研究多种元素掺杂对碳量子点发光性质的影响

本文以对氨基苯磺酸为原料

通过水热法一步合成了氮、硫共掺杂的碳量子点。实验结果表明:制备的碳量子点尺寸分布均匀

氮、硫分别以氨基和磺酸基团的形式存在于碳量子点的表面。与已有的报道不同

碳量子点展现出了非激发波长依赖的蓝光发射行为

三价铁离子可有效猝灭其荧光

铁离子浓度在0~10

-3

molL

-1

范围内与碳量子点的荧光猝灭程度呈现良好的线性关系

检出限约为10

-7

molL

-1

。制备的碳量子点对三价铁离子具有高选择性、高灵敏性以及较好的抗干扰能力

能作为三价铁离子检测的传感器。

Abstract

Not only do the photoluminescence (PL) properties of carbon quantum dots (CQDs) depend on their sizes

but also rely on their surface states. Accordingly

the PL behaviors of CQDs could be tuned by doping and/or grafting heteroatoms and groups. In this work

sulfur-and nitrogen-co-doped carbon quantum dots (SN-CQDs) were firstly synthesized by one-step hydrothermal method using p-aminobenzenesulfonicacid as carbon source. Experimental results indicate that the obtained SN-CQDs have a uniform size and are modified by amine and sulphonic acid groups at their surface. Unlike previous reports

the SN-CQDs show the excitation-wavelength-independent photoluminescence behavior and their fluorescence can be quenched by Fe

ions. There is a good linear relationship between the Fe

concentrations within 0-10

-3

molL

-1

and the fluorescence quenching rates of SN-CQDs. The detecting limit for Fe

ions is about 10

-7

molL

-1

. The obtained SN-CQDs have the ability of high selectivity

high sensitivity and good anti-jamming capability to ferric iron ions. Accordingly

SN-CQDs can be used for the detection of Fe

ions in the environment and organism.

关键词

Keywords

references

AISEN P, WESSLING-RESNICK M, LEIBOLD E A. Iron metabolism [J]. Curr. Opin. Chem. Biol., 1999, 3(2):200-206.

LIEU P T, HEISKALA M, PETERSON P A, et al.. The roles of iron in health and disease [J]. Mol. Aspects Med., 2001, 22(1-2):1-87.

CONRAD M E, UMBREIT J N, MOORE E G. Iron absorption and transport [J]. Am. J. Med. Sci., 1999, 318(4):213-229.

SIRIVECH S, DRISKELL J, FRIEDEN E. NADH-FMN oxidoreductase activity and iron content of organs from riboflavin and iron-deficient rats [J]. J. Nutr., 1977, 107(5):739-745.

KALINOWSKI D S, RICHARDSON D R. Future of toxicology-iron chelators and differing modes of action and toxicity: the changing face of iron chelation therapy [J]. Chem. Res. Toxicol., 2007, 20(5):715-720.

HARDIKAR P S, JOSHI S M, BHAT D S, et al.. Spuriously high prevalence of prediabetes diagnosed by HbA1c in young Indians partly explained by hematological factors and iron deficiency anemia [J]. Diabetes Care, 2012, 35(4):797-802.

FILIPPATOS G, FARMAKIS D, COLET J C, et al.. Intravenous ferric carboxymaltose in iron-deficient chronic heart failure patients with and without anaemia: a subanalysis of the FAIR-HF trial [J]. Eur. J. Heart Fail., 2013, 15(11):1267-1276.

EVANS E H, DAWSON J B, FISHER A, et al.. Advances in atomic emission, absorption and fluorescence spectrometry and related techniques [J]. J. Anal. At. Spectrom., 2002, 17(6):622-651.

MICHALSKI R. Applications of ion chromatography for the determination of inorganic cations[J]. Crit. Rev. Anal. Chem., 2009, 39(4):230-250.

RAY S C, SAHA A, JANA N R, et al.. Fluorescent carbon Nanoparticle: synthesis, characterization and bio-imaging application [J]. J. Phys. Chem. C, 2009, 113(43):18546-18551.

LI H T, HE X D, LIU Y, et al.. One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties [J]. Carbon, 2011, 49(2):605-609.

ZHOU L, LI Z H, LIU Z, et al.. Luminescent carbon dot-gated nanovehicles for pH-triggered intracellular controlled release and imaging [J]. Langmuir, 2013, 29(21):6396-6403.

赵清,常青,杨金龙,等. 碳点嫁接海藻酸钙复合结构的制备及其对Cu2+的检测 [J]. 发光学报, 2014, 35(3):387-392. ZHAO Q, CHANG Q, YANG J L, et al.. Preparation of complex carbon-dot-grafted calcium alginate and its application as fluorescent sensor for Cu2+ [J]. Chin. J. Lumin., 2014, 35(3):387-392. (in Chinese)

丁艳丽,胡胜亮,常青. 氨基修饰碳点与酞菁锌复合结构的制备与性能 [J]. 高等学校化学学报, 2015, 36(4):619-624. DING Y L, HU S L, CHANG Q. Preparation and characterization of composites of amine-functionalized carbon dots and zinc phthalocyaine [J]. Chem. J. Chin. Univ., 2015, 36(4):619-624.(in Chinese)

GUO X, WANG C F, YU Z Y, et al.. Facile access to versatile fluorescent carbon dots toward light-emitting diodes [J]. Chem. Commun., 2012, 48(21):2692-2694.

LI Y, ZHAO Y, CHENG H H, et al.. Nitrogen-doped graphene quantum dots with oxygen-rich functional groups [J]. J. Am. Chem. Soc., 2012, 134(1):15-18.

LI W, ZHANG Z H, KONG B, et al.. Simple and green synthesis of nitrogen-doped photoluminescent carbonaceous nanospheres for bioimaging [J]. Angew. Chem., 2013, 52(31):8151-8155.

LIU Y S, ZHAO Y N, ZHANG Y Y. One-step green synthesized fluorescent carbon nanodots from bamboo leaves for copper (Ⅱ) ion detection [J]. Sens. Actuators B, 2014, 196:647-652.

LAI T T, ZHENG E H, CHEN L X, et al.. Hybrid carbon source for producing nitrogen-doped polymer nanodots: one-pot hydrothermal synthesis, fluorescence enhancement and highly selective detection of Fe (Ⅲ) [J]. Nanoscale, 2013, 5(17):8015-8021.

LIANG Q H, MA W J, SHI Y, et al.. Easy synthesis of highly fluorescent carbon quantum dots from gelatin and their luminescent properties and applications [J]. Carbon, 2013, 60:421-428.

SUN D, BAN R, ZHANG P H, et al.. Hair fiber as a precursor for synthesizing of sulfur- and nitrogen-co-doped carbon dots with tunable luminescence properties [J]. Carbon, 2013, 64:424-434.

ZHANG Y Y, WU M, WANG Y Q, et al.. A new hydrothermal refluxing route to strong fluorescent carbon dots and its application as fluorescent imaging agent [J]. Talanta, 2013, 117:196-202.

AMJADI M, MANZOORI J L, HALLAJ T, et al.. Strong enhancement of the chemiluminescence of the cerium (IV)-thiosulfate reaction by carbon dots, and its application to the sensitive determination of dopamine [J]. Microchim. Acta, 2014, 181(5-6):671-677.

CHANDRA S, PATRA P, PATHAN S H, et al.. Luminescent S-doped carbon dots: an emergent architecture for multimodal applications [J]. J. Mater. Chem. B, 2013, 1(18):2375-2382.

QU D, ZHENG M, DU P, et al.. Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts [J]. Nanoscale, 2013, 5(24):12272-12277.

LI S H, LI Y C, CAO J, et al.. Sulfur-doped graphene quantum dots as a novel fluorescent probe for highly selective and sensitive detection of Fe3+ [J]. Anal. Chem., 2014, 86(20):10201-10207.

HU S L, ZHAO Q, CHANG Q, et al.. Enhanced performance of Fe3+ detection via fluorescence resonance energy transfer between carbon quantum dots and Rhodamine B [J]. RSC Adv., 2014, 4(77):41069-41075.

Views

142

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Preparation of Carbon Quantum Dots from Cigarette Filters for Detection of Dopamine

Fluorescence Quenching Method for Determination of Sunset Yellow in Drinks with Carbon Quantum Dots

Preparation of Coal-based Carbon Quantum Dots and Determination of Cr（Ⅵ） in Environmental Water

Investigation on Mechanism of Enhanced Luminescence Efficiency of Carbon Quantum Dots Through Thiol-ene Cross-linking

Microwave Preparation of Common Lophatherum Herb Carbon Quantum Dots and Application in Cell Imaging

Related Author

PENG Xiao-shan

SU An-mei

WEN Hui-zhong

ZHONG Qing-mei

CHEN Yu-ye

WANG Yi-lin

YU Shu-yi

QIN Xiu

Related Institution

Guangxi Key Laboratory of Biorefinery, School of Chemistry and Chemical Engineering, Guangxi University

Hebei Vocational University of Industry and Technology

College of Chemical Engineering， University of Science and Technology Liaoning

School of Electronics and Information， Zhengzhou University of Light Industry

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰