Sol-gel Green Synthesis and Luminescent Properties of CeO2: Eu3+ Nanopowders

LI Jing-lei; LI Ke-yan; SHI Shi-kao; JIANG Lan-hong; WANG Shu-ping; GENG Li-na; ZHANG Jian

doi:10.3788/fgxb20163704.0405

您当前的位置：

首页 >

文章列表页 >

Sol-gel Green Synthesis and Luminescent Properties of CeO₂: Eu³⁺ Nanopowders

更新时间：2020-08-12

- Sol-gel Green Synthesis and Luminescent Properties of CeO₂: Eu³⁺ Nanopowders
- Chinese Journal of Luminescence Vol. 37, Issue 4, Pages: 405-409(2016)
- 作者机构：
  
  1. 河北师范大学化学与材料科学学院,河北石家庄,050024
  2. 清华大学材料学院北京,100084
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163704.0405
  CLC： O482.31
- Received：25 November 2015，
  
  Revised：24 January 2016，
  
  Published：05 April 2016
- 稿件说明：
移动端阅览
李敬磊, 李科研, 石士考等. 纳米粉体CeO2:Eu3+的溶胶-凝胶绿色合成及其发光性质[J]. 发光学报, 2016,37(4): 405-409

LI Jing-lei, LI Ke-yan, SHI Shi-kao etc. Sol-gel Green Synthesis and Luminescent Properties of CeO2: Eu3+ Nanopowders[J]. Chinese Journal of Luminescence, 2016,37(4): 405-409
李敬磊, 李科研, 石士考等. 纳米粉体CeO2:Eu3+的溶胶-凝胶绿色合成及其发光性质[J]. 发光学报, 2016,37(4): 405-409 DOI： 10.3788/fgxb20163704.0405.

LI Jing-lei, LI Ke-yan, SHI Shi-kao etc. Sol-gel Green Synthesis and Luminescent Properties of CeO2: Eu3+ Nanopowders[J]. Chinese Journal of Luminescence, 2016,37(4): 405-409 DOI： 10.3788/fgxb20163704.0405.

摘要

采用溶胶-凝胶法

以硝酸铈为原料

加入适量淀粉为分散剂

并通过氨水来调节溶液pH值

合成稀土Eu

掺杂的CeO

红色纳米粉体。通过X射线衍射仪、场发射扫描电子显微镜、荧光分光光度计等手段研究不同煅烧温度对粉体结构、形貌、发光及显色性能的影响。结果表明

所得样品为立方晶系的萤石结构

空间群为

Fm3m

颗粒呈近似球形

粒径范围在10~60 nm之间。随着煅烧温度的升高

CeO

晶粒尺寸逐渐增大

荧光粉的红色发光也逐渐增强。经800 ℃烧结后

近紫外(370 nm)和蓝光区(468 nm)的光都能对粉体有效地激发

这有利于其在固态照明中的应用。在溶胶-凝胶制备过程中

采用淀粉作分散剂

具有工艺简单、绿色环保的优点

有利于纳米氧化铈粉体的大规模制备。

Abstract

-doped CeO

red nanopowders were sol-gel synthesized by using cerium nitrate as raw materials and starch as dispersing agent. In the sol-gel process

the pH value was adjusted by ammonia. The crystal structure

morphology

luminescence properties and chromaticity coordinates of the nanopowders calcined at different temperatures were analyzed by X-ray diffraction patterns

field emission scanning electron microscopy and spectrofluorometer. The results reveal that the obtained samples are of cubic fluorite structure with the space group

Fm3m

. The particles are approximately spherical with the size of 10-60 nm. With the increase of calcination temperature

the size of CeO

increases gradually and the red luminescence of the nanopowders is obviously enhanced. After calcination at 800 ℃

the nanopowders can be effectively excited at near UV (370 nm) and blue (468 nm) regions

which is beneficial to the application in solid state lighting. The approach using starch as dispersing agent in sol-gel processes is simple

green and economical for large scale preparation of nanoceria.

关键词

Keywords

references

ZHENG W, HUANG P, TU D, et al.. Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection [J]. Chem. Soc. Rev., 2015, 44(6):1379-1415.

SINGH S K. Red and near infrared persistent luminescence nano-probes for bioimaging and targeting applications [J]. RSC Adv., 2014, 102(4):58674-58698.

LUPAN O, VIANA B, PAUPORTE T, et al.. Controlled mixed violet blue red electroluminescence from Eu: nano-phosphors/ZnO-nanowires/p GaN light-emitting diodes [J]. J. Phys. Chem. C, 2013, 117(50):26768-26775.

FERNNDEZ-GARCA M, MARTNEZ-ARIAS A, HANSON J C, et al.. Nanostructured oxides in chemistry: characterization and properties [J]. Chem. Rev., 2004, 104(9):4063-4104.

LI L, YANG H K, MOON B K, et al.. Photoluminescence properties of CeO2:Eu3+ nanoparticles synthesized by a Sol-Gel method [J]. J. Phys. Chem. C, 2009, 113(2):610-617.

XU Z H, LIN J. Hydrothermal synthesis, morphology control and luminescent properties of nano/microstructured rare earth oxide species [J]. Rev. Nanosci. Nanotechnol., 2013, 2(4):225-246.

LIU X H, CHEN S J, WANG X D. Synthesis and photoluminescence of CeO2:Eu3+ phosphor powders [J]. J. Lumin., 2007, 127(2):650-654.

SAHOO S K, MOHAPATRA M, ANAND S. Characterization and optical properties of Eu-doped cubic nano ceria synthesized by using the co-precipitation-hydrothermal route [J]. J. Korean Phys. Soc., 2013, 62(2):297-304.

ANSARI A A, SINGH S P, MALHOTRA B D. Optical and structural properties of nanostructured CeO2:Tb3+ film [J]. J. Alloys Compd., 2011, 509(2):262-265.

SHI S K, HOSSU M, HALLB R, et al.. Solution combustion synthesis, photoluminescence and X-ray luminescence of Eu-doped nanoceria CeO2:Eu [J]. J. Mater. Chem., 2012, 22(44):23461-23467.

JANSSEN L P B M, Moscicki L. Thermoplastic Starch: A Green Material for Various Industries [M]. Weinheim: Wiley-VCH, 2009.

ZAK A K, MAJID W H A, MAHMOUDIAN M R, et al.. Starch-stabilized synthesis of ZnO nanopowders at low temperature and optical properties study [J]. Adv. Powder Technol., 2013, 24(3):618-624.

STAROSZCZYK H, JANAS P. Microwave-assisted synthesis of zinc derivatives of potato starch [J]. Carbohydr. Polym., 2010, 80(3):962-969.

周青超,柏泽龙,鲁路,等. 白光LED远程荧光粉技术研究进展与展望 [J]. 中国光学, 2015, 8(3):313-328. ZHOU Q C, BAI Z L, LU L, et al.. Remote phosphor technology for white LED applications: advances and prospects [J]. Chin. Opt., 2015, 8(3):313-328. (in Chinese)

杨志平,梁晓双,赵引红,等. 橙红色荧光粉Ca3Y2(Si3O9)2:Sm3+的制备及发光性能的表征 [J]. 光子学报, 2014, 43(3):0316002-1-6. YANG Z P, LIANG X S, ZHAO Y H, et al.. Preparation and luminescence properties of reddish-orange phosphors Ca3Y2-(Si3O9)2:Sm3+ [J]. Acta Photon. Sinica, 2014, 43(3):0316002-1-6.(in Chinese)

WANG H L, ZHANG S, LI Y B, et al.. Bias effect on microstructure and mechanical properties of magnetron sputtered nanocrystalline titanium carbide thin films [J]. Thin Solid Films, 2008, 516(16):5419-5423.

WEI Z G, SUN L D, LIAO C S, et al.. Size-dependent chromaticity in YBO3:Eu nanocrystals: correlation with microstructure and site symmetry [J]. J. Phys. Chem. B, 2002, 106(41):10610-10617.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Rare Earth Ion Doped Perovskite Nanocrystals

Sol-gel Chemical Synthesis of Eu³⁺-doped Lanthanum Cerium Composite Oxide Phosphor

Luminescence Properties of₂(Ba_1-xSr_xO)(1-y)P₂O₅·yB₂O₃：Eu²⁺

Luminescent Properties of the Rare Earth Ions in Long Afterglow Phosphor Sr₂MgSi₂O₇：Eu²⁺,Dy³⁺

Progress on the Study of Nanoscale Rare Earth Luminescent Materials

Related Author

Qiang HU

Xue BAI

Hong-wei SONG

Ya-xin YUE

Lu LIU

Shi-kao SHI

Ji-ye WANG

Rui-long ZONG

Related Institution

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University

Department of Chemistry, Tsinghua University

Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University

Institute of Optoelectronics Technology, Beijing Jiaotong University

Department of physics, University of Science and Technology of China

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰