Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin

LI Chen; LI Jian-feng; DUAN Wu-biao; LIU Bo

doi:10.3788/fgxb20163702.0158

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Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin

更新时间：2020-08-12

- Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin
- Chinese Journal of Luminescence Vol. 37, Issue 2, Pages: 158-164(2016)
- 作者机构：
  
  1. 北京交通大学理学院北京,100044
  2. 中国科学院大学材料科学与光电技术学院北京,101408
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20163702.0158
  CLC： O621.3
- Received：19 October 2015，
  
  Revised：03 November 2015，
  
  Published：10 February 2016
- 稿件说明：
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李晨, 李剑峰, 段武彪等. 一种新型尾式卟啉的合成及其光电性质研究[J]. 发光学报, 2016,37(2): 158-164

LI Chen, LI Jian-feng, DUAN Wu-biao etc. Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin[J]. Chinese Journal of Luminescence, 2016,37(2): 158-164
李晨, 李剑峰, 段武彪等. 一种新型尾式卟啉的合成及其光电性质研究[J]. 发光学报, 2016,37(2): 158-164 DOI： 10.3788/fgxb20163702.0158.

LI Chen, LI Jian-feng, DUAN Wu-biao etc. Synthesis, Spectral and Electrochemical Properties of A New Tailed Porphyrin[J]. Chinese Journal of Luminescence, 2016,37(2): 158-164 DOI： 10.3788/fgxb20163702.0158.

摘要

合成了新型尾式5-(2-(-咪唑基间甲基苯甲酰胺基)苯基)-10

20-三苯基卟啉(H

TPP-BzIm)及其Fe、Co、Zn配合物

并用核磁、质谱、红外光谱、紫外-可见光谱等对其化合物进行了表征

通过紫外吸收、荧光分析、循环伏安法研究了化合物的光电性质。结果表明

与四苯基卟啉(H

TPP)相比

该尾式卟啉及其配合物的紫外和荧光光谱均出现较明显红移。Fe和Co卟啉的循环伏安曲线表明不仅发生了卟啉环上的氧化还原反应

还发生了金属离子的氧化还原反应。

Abstract

A new tailed-porphyrin H

TPP-BzIm and different transition metalloporphyrins (Fe

Zn) were synthesized and characterized by

H NMR

UV-Vis. The spectral and electrochemical properties were studied by UV-Vis spectrum

fluorescence spectrum and cyclic voltammetry method. Compared with tetraphenyporphyrin(H

TPP)

the absorption and emission peaks of the tailed porphyrin have obvious red-shifts. The CV curves of Fe

Co metalloporphyrins indicate that Fe and Co undergo the changing of oxidation state in addition to the redox on the porphyrin ring.

关键词

Keywords

references

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