Visual Recognition for Hg2+ and Ag+ of Carbazole-thiourea Schiff Base Fluorescence Probe

YIN Fang-fang; ZHU Wei-ju; FANG Min; XU Ying; LI Cun

doi:10.3788/fgxb20153610.1137

您当前的位置：

首页 >

文章列表页 >

Visual Recognition for Hg²⁺ and Ag⁺ of Carbazole-thiourea Schiff Base Fluorescence Probe

更新时间：2020-08-12

- Visual Recognition for Hg²⁺ and Ag⁺ of Carbazole-thiourea Schiff Base Fluorescence Probe
- Chinese Journal of Luminescence Vol. 36, Issue 10, Pages: 1137-1144(2015)
- 作者机构：
  
  安徽大学化学化工学院安徽省绿色高分子材料重点实验室, 安徽合肥 230601
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153610.1137
  CLC： O625.64
- Received：12 June 2015，
  
  Revised：29 July 2015，
  
  Published：10 October 2015
- 稿件说明：
移动端阅览
殷芳芳, 朱维菊, 方敏等. 咔唑-硫脲席夫碱荧光探针对Hg2+和Ag+的可视化识别[J]. 发光学报, 2015,36(10): 1137-1144

YIN Fang-fang, ZHU Wei-ju, FANG Min etc. Visual Recognition for Hg2+ and Ag+ of Carbazole-thiourea Schiff Base Fluorescence Probe[J]. Chinese Journal of Luminescence, 2015,36(10): 1137-1144
殷芳芳, 朱维菊, 方敏等. 咔唑-硫脲席夫碱荧光探针对Hg2+和Ag+的可视化识别[J]. 发光学报, 2015,36(10): 1137-1144 DOI： 10.3788/fgxb20153610.1137.

YIN Fang-fang, ZHU Wei-ju, FANG Min etc. Visual Recognition for Hg2+ and Ag+ of Carbazole-thiourea Schiff Base Fluorescence Probe[J]. Chinese Journal of Luminescence, 2015,36(10): 1137-1144 DOI： 10.3788/fgxb20153610.1137.

摘要

以3-溴代-N-丁基咔唑和4-苯基-3-氨基硫脲为原料

合成了一种新型含咔唑基的硫脲席夫碱

使用紫外-可见光谱、荧光光谱、核磁氢谱以及质谱等对其成分结构、离子识别性能、识别模式进行了研究。结果表明:

对Hg

和Ag

具有快速响应的可视化选择性识别。当Hg

或Ag

加入后

溶液的颜色由无色立刻变为黄色;同时

溶液中加入Hg

和Ag

后

荧光光谱有不同变化

且其他离子的存在并不干扰

对Hg

和Ag

的选择性识别。研究还发现

对Hg

和Ag

的荧光识别模式不同:加入Ag

后

与Ag

生成了配合物

发生荧光猝灭;加入Hg

后

先与Hg

络合发生荧光猝灭

然后脱去HgS。

Abstract

A thiourea Schiff base (

) containing carbazole was synthesized from carbazole derivative and 4-phenyl-3-amino thiourea as reagents. The structure of compound

was characterized by

H NMR and MS. The recognition performance and the binding mode of

and metal ions were investigated by UV-Vis and fluorescence spectroscopies. The results show that

has a quick visual selective recognition response to Hg

and Ag

. The addition of metal ions caused the color of

changed from colorless to yellow

and it can be identified by the naked eyes. The fluorescence spectrum of

has different changes with the adding of Hg

or Ag

to the solution. The presence of other ions does not interfere with the selective recognition of

for Hg

and Ag

. It is also found that the binding model of

and Hg

/Ag

for fluorescent recognition is different:

coordinates with Ag

to form complex which causes fluorescence quenching effect;

coordinates with Hg

to form complex which causes fluorescence quenching effect

then the complex removes HgS to produce a new compound.

关键词

Keywords

references

Li Z Q, Zhou Y, Yin K, et al. A new fluorescenceturn-on type chemosensor for Fe3+ based on naphthalimide and coumarin [J]. Dyes Pigm., 2014, 105:7-11.

Zhang X, Shiraishi Y, Hirai T. Fe(Ⅲ)-and Hg(Ⅱ)-selective dual channel fluorescence of a rhodamine-azacrown ether conjugate [J]. Tetrahedron Lett., 2008, 49(26):4178-4181.

Zhang S, Yu T, Sun M T, et al. Highly sensitive and selective fluorescence detection of copper (Ⅱ) ion based on multi-ligand metal chelation [J]. Talanta, 2014, 126:185-190.

Rathinam B, Chien C C, Chen B C, et al. Fluorogenic and chromogenic detection of Cu2+ and Fe3+ species in aqueous media by rhodamine-triazole conjugate [J]. Tetrahedron, 2013, 69(1):235-241.

Cai Y L, Meng X M, Wang S X, et al. A quinoline based fluorescent probe that can distinguish zinc(Ⅱ) from cadmium(Ⅱ) in water [J]. Tetrahedron Lett., 2013, 54(9):1125-1128.

Zhou Y, Li Z X, Zang S Q, et al. A novel sensitive turn-on fluorescent Zn2+ chemosensor based on an easy to prepare C-3-symmetric Schiff-base derivative in 100% aqueous solution [J]. Org. Lett., 2012, 14(5):1214-1217.

Liu Y M, Fei Q, Shan H Y, et al. A novel fluorescent 'off-on-off' probe for relay recognition of Zn2+ and Cu2+ derived from N,N-bis(2-pyridylmethyl)amine [J]. Analyst, 2014, 139(8):1868-1875.

Liu H Y, Wan X J, Liu T Q, et al. Cascade sensitive and selective fluorescence OFF-ON-OFF sensor for Cr3+ cation and F anion [J]. Sens. Actuators, B, 2014, 200:191-197.

Vasimalai N, Sheeba G, John A S, et al. Ultrasensitive fluorescence-quenched chemosensor for Hg(Ⅱ) in aqueous solution based on mercaptothiadiazole capped silver nanoparticles [J]. Mater, 2012, 213:193-199.

Wu X L, Lai J P, Zhao Y B. Sensitive sensor for mercury ion in aqueous solution by "naked-eye" and fluorescence recognition [J]. Chem. J. Chin. Univ.(高等学校化学学报), 2012, 33(4):695-699 (in Chinese).

Saeed M M, Ahmed M. Adsorption and thermoldynamic studies of Co(Ⅱ) and Hg(Ⅱ) on 2-nitroso-1-naphthol immobilized polyurethane foam using radiotracer technique [J]. Radiochim. Acta, 2004, 92(1):47-54.

Wang Y, Hou L J, Wu Y B, et al. Alizarin complexone as a highly selective ratiometric fluorescent probe for Al3+ detection in semi-aqueous solution [J]. J. Photochem. Photobiol. A, 2014, 281:40-46.

Mirzaeia M, Saeed J. Selective and sensitive optical chemosensor for detection of Ag(Ⅰ) ions based on 2(4-hydroxy pent-3-en-2-ylideneamine) phenol in aqueous samples [J]. Spectrochim. Acta Part A, 2011, 82(1):351-354.

Anand T, Sivaraman G, Anandh P, et al. Colorimetric and turn-on fluorescence detection of Ag(Ⅰ) ion [J]. Tetrahedron Lett., 2014, 55(3):671-675.

Wang L L, Li B, Zhang L M, et al. Three-input-three-output logic operations based on absorption and fluorescence dual-mode from a thiourea compound [J]. Dalton Trans., 2013, 42(2):459-65.

Ghanei-Motlagh M, Fayazi M, Taher M A. On the potentiometric response of mercury(Ⅱ) membrane sensorsbased on symmetrical thiourea derivatives-experimental and theoretical approaches [J]. Sens. Actuators, B, 2014, 199:133-141.

Bharati P, Bharti A, Bharty M K, et al. Square planar Ni(Ⅱ) complexes of pyridine-4-carbonyl-hydrazine carbodithioate, 1-phenyl-3-pyridin-2-yl-isothiourea and 4-(2-methoxyphenyl)piperazine-1-carbodithioate involving N-S bonding: An approach to DFT calculation and thermal studies [J]. Polyhedron, 2013, 63:156-166.

Saleem M, Abdullah R, Ali A, et al. Facile synthesis, cytotoxicity and bioimaging of Fe3+ selective fluorescent chemosensor [J]. Bioorg. Med. Chem., 2014, 22(7):2045-2051.

Zhang H J, Qin X, Liu K, et al. Synthesis, antibacterial activities and molecular docking studies of Schiff bases derived from N-(24-benzaldehyde-amino)phenyl-N'-phenyl-thiourea [J]. Bioorg. Med. Chem., 2011, 19(18):5708-5715.

Yang L L, Zhu W J, Fang M, et al. A new carbazole-based Schiff-base as fuorescent chemosensor for selective detection of Fe3+and Cu2+ [J]. Spectrochim. Acta A, 2013, 109:186-192.

Dai H J, Liu F, Gao Q Q, et al. A highly selective fluorescent sensor for mercury ion (Ⅱ) based on azathia-crown ether possessing a dansyl moiety [J]. J. Lumin., 2011, 26(6):523-530.

Wu S P, Liu S R. A new water-soluble fluorescent Cu(Ⅱ) chemosensor based on tetrapeptide histidyl-glycyl-glycyl-glycine (HGGG) [J]. Sens. Actuators, B, 2009, 141(1):187-191.

Feng G D, Ding Y Y, Gong Z Y, et al. Determination of mercury(Ⅱ) in aquatic plants using quinoline-thiourea conjugates as a fluorescent probe [J]. Anal. Sci., 2013, 29(7):735-740.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis, Aggregation Induced Luminescence and Piezochromic Properties of Thiophene Ethylene Derivatives

DNA Binding Activity of Copper Complex with Schiff Base Derived from Oligochitosan and Furfuraldehyde

Interaction of Schiff Base Rare Earth Complexes with Herring Sperm DNA

Synthesis and Luminescence Property of Schiff Base Modified α-Cyanostilbene Derivative Fluorescent Liquid Crystals Material

Fluorescence Detecting of Carbazole-containing Poly(phenyleneethynylene)'s Thin Film to TNT Volatile

Related Author

QIU Beibei

ZHAO Lanlan

MA Xueyan

ZHAI You

FENG Wang

MEI Qunbo

FENG Xiao-qiang

LI Xiao-fang

Related Institution

School of Materials Science and Engineering， Nanjing University of Posts and Telecommunications

School of Chemical Engineering and Technology, Tianshui Normal University

College of Chemical Engineering and Technology, Tianshui Normal University

Chemistry Department, Ding Xi Teachers' College

Department of Chemistry, Key Laboratory of Functional Inorganic Materials of Anhui Province, Anhui University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰