Efficient Perovskite-organic Bulk Heterojunction Hybrid Integrated Solar Cells

TANG Tong; ZUO Hong-wen; WANG Ya-ling; QIN Wen-jing; CAO Huan-qi; YANG Li-ying; YAO Cong; G

doi:10.3788/fgxb20153609.1047

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Efficient Perovskite-organic Bulk Heterojunction Hybrid Integrated Solar Cells

更新时间：2020-08-12

- Efficient Perovskite-organic Bulk Heterojunction Hybrid Integrated Solar Cells
- Chinese Journal of Luminescence Vol. 36, Issue 9, Pages: 1047-1052(2015)
- 作者机构：
  
  1. 天津理工大学显示材料与光电器件教育部重点实验室天津,300384
  2. 天津理工大学天津市光电显示材料与器件重点实验室天津,300384
  3. 中国电子科技集团第18研究所天津,300384
  4. 中国科学院宁波材料所,浙江宁波,315201
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153609.1047
  CLC： TM914.4
- Received：05 June 2015，
  
  Revised：17 July 2015，
  
  Published：03 September 2015
- 稿件说明：
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唐摇彤, 左红文, 王亚凌等. 高效钙钛矿-有机本体异质结杂化串联太阳能电池[J]. 发光学报, 2015,36(9): 1047-1052

TANG Tong, ZUO Hong-wen, WANG Ya-ling etc. Efficient Perovskite-organic Bulk Heterojunction Hybrid Integrated Solar Cells[J]. Chinese Journal of Luminescence, 2015,36(9): 1047-1052
唐摇彤, 左红文, 王亚凌等. 高效钙钛矿-有机本体异质结杂化串联太阳能电池[J]. 发光学报, 2015,36(9): 1047-1052 DOI： 10.3788/fgxb20153609.1047.

TANG Tong, ZUO Hong-wen, WANG Ya-ling etc. Efficient Perovskite-organic Bulk Heterojunction Hybrid Integrated Solar Cells[J]. Chinese Journal of Luminescence, 2015,36(9): 1047-1052 DOI： 10.3788/fgxb20153609.1047.

摘要

制备了一种有机铅卤钙钛矿-有机本体异质结杂化串联太阳能电池。采用紫外可见吸收光谱、原子力显微镜对薄膜形貌进行了表征。结果表明:有机本体异质结层可以有效改善钙钛矿的表面形貌

增强了可见光的吸收。优化后的串联结构电池的短路电流可达19.14mA/cm

开路电压为0.76V

光电转换效率达到了6.54%。钙钛矿电池和有机本体异质结电池串联结构可以同时提高短路电流及填充因子

二者具有较好的相容性和协同作用。

Abstract

An integrated perovskite/organic bulk-heterojunction (BHJ) photovoltaic device was fabricated for efficient light harvesting and energy conversion. The structure of the solar cells consists of two photovoltaic layers

namely a methylammonium lead iodide (CH

PbI

) and poly(3-hexylthiophene) (P3HT) blended with methanofullerene [6

6]-phenyl C

-butyric acid methyl ester (PCBM) organic BHJ active layer. The power conversion efficiency (PCE) of 6.54% was achieved in the integrated device with a

of 19.14 mA/cm

of 0.76V

and a

of 45.0%. Compared to that of CH

PbI

/PCBM planar device

the enhanced performance indicates that the BHJ film absorbs light and contributes to the current density of the device. Our research further demonstrates the compatibility and synergistic potential of the perovskite and organic bulk-heterojunction (BHJ) photovoltaic device.

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references

Martin A G, Keith E, Yoshihiro H, et al. Solar cell efficiency tables (Version 45) [J]. Prog. Photovolt.: Res. Appl., 2015, 23(1):1-9.

Wu J, Xie Z Y. Polymer solar cells fabricated with doctor-blade coating technique [J]. Chin. J. Lumin.(发光学报), 2012, 33(5):540-544 (in Chinese).

Yan X M, Wang Q K. Study on application of CdSe/ZnSe/ZnS quantum dots in monocrystalline silicon solar cells [J]. Chin. J. Lumin.(发光学报), 2013, 34(10):1358-1361 (in Chinese).

Kim H S, Lee C R, Im J H, et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9% [J]. Sci. Rep., 2012, 2:591-597.

Lee M M, Teuscher J, Miyasaka T, et al. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites [J]. Science, 2012, 338:643-647.

Crossland E J W, Noel N, Sivaram V, et al. Mesoporous TiO2 single crystals delivering enhanced mobility and optoelectronic device performance [J]. Nature, 2013, 495:215-219.

Heo J H, Im S H, Noh J H, et al. Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors [J]. Nat. Photon., 2013, 7:486-491.

Burschka J, Pellet N, Moon S J, et al. Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J]. Nature, 2013, 499:316-319.

Xing G H, Mathews N, Sun S Y, et al. Long-range balanced electron and hole-transport lengths in organic-inorganic CH3NH3PbI3 [J]. Science, 2013, 342(6156):344-347.

Zhou H P, Chen Q, Li G, et al. Interface engineering of highly efficient perovskite solar cells [J]. Science, 2014, 345(6196):542-546.

Nie W Y, Tsai H, Asadpour R, et al. High-efficiency solution processed perovskite solar cells with millimeter scale grains [J]. Science, 2015, 347(6221):522-525.

Shi D, Adinolfi V, Comin R, et al. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals [J]. Science, 2015, 347(6221):519-522.

Dong Q F, Fang Y J, Shao Y C, et al. Electron-hole diffusion lengths >175 m in solution-grown CH3NH3PbI3 single crystals [J]. Science, 2015, 347(6225):967-970.

Wu X X, Trinh M T, Niesner D, et al. Trap states in lead iodide perovskites [J]. J. Am. Chem. Soc., 2015, 137(5):2089-2096.

Kojima A, Teshima K, Shirai Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells [J]. J. Am. Chem. Soc., 2009, 131:6050-6051.

Jeng J Y, Chiang Y F, Lee M H, et al. (CH3NH3)PbI3 perovskite fullerene planar heterojunction hybrid solar cells [J]. Adv. Mater., 2013, 25(27):3727-3732.

Etgar L, Gao P, Xue Z S, et al. Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells [J]. J. Am. Chem. Soc., 2012, 134:17396-17399.

Xu X J, Yang L Y, Tian H, et al. Enhanced performance and stability in polymer photovoltaic cells by using ultraviolet treated PEDOT: PSS [J]. Chin. Phys. Lett., 2013, 30(7):077201-1-5.

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