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1. 天津理工大学 材料科学与工程学院 天津,300384
2. 中国科学院 宁波材料技术与工程研究所,浙江 宁波,315201
Received:09 April 2015,
Revised:03 May 2015,
Published:03 July 2015
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左红文, 欧阳新华, 王娟等. 基于含芴菲并咪唑衍生物的可湿法加工的蓝光有机电致发光器件[J]. 发光学报, 2015,36(7): 834-840
ZUO Hong-wen, OUYANG Xin-hua, WANG Juan etc. Solution-processable Blue Organic Light-emitting Diodes Based on Fluorene of Phenanthroimidazole Derivatives[J]. Chinese Journal of Luminescence, 2015,36(7): 834-840
左红文, 欧阳新华, 王娟等. 基于含芴菲并咪唑衍生物的可湿法加工的蓝光有机电致发光器件[J]. 发光学报, 2015,36(7): 834-840 DOI: 10.3788/fgxb20153607.0834.
ZUO Hong-wen, OUYANG Xin-hua, WANG Juan etc. Solution-processable Blue Organic Light-emitting Diodes Based on Fluorene of Phenanthroimidazole Derivatives[J]. Chinese Journal of Luminescence, 2015,36(7): 834-840 DOI: 10.3788/fgxb20153607.0834.
设计合成了一种新型A-D-A含芴菲并咪唑和炔基基团的蓝光分子(FI)
采用紫外吸收、光致发光光谱和循环伏安对材料进行了表征
发现该物质具有稳定的蓝光发射。采用旋涂的方法制备了非掺杂蓝光有机发光二极管
器件的最大电流效率为1.52 cdA
-1
最大功率效率为0.63 lmW
-1
.
A novel A-D-A blue emitter containing fluorene
phenanthroimidazole and acetylene group moieties was synthesized and characterized
named as FI. Its photophysical and photochemical properties were systematically investigated. The results showed FI exhibits excellent solubility
fluorescence
thermal stability and film formation
which is a good candidate for the fabrication of solution-processable organic light-emitting diodes. A non-doped blue organic light-emitting diode based on FI as the emitter showed the maximum luminance efficiency of 1.52 cdA
-1
and the maximum power efficiency could reach 0.63 lmW
-1
.
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Lai W Y, He Q Y, Zhu R, et al. Kinked star-shaped fluorene/triazatruxene co-oligomer hybrids with enhanced functional properties for high-performance, solution-processed, blue organic light-emitting diodes [J]. Adv. Funct. Mater., 2008, 18(2):265-276.
Jou J H, Kumar S, Fang P H, et al. Highly efficient ultra-deep blue organic light-emitting diodes with a wet- and dry-process feasible cyanofluorene acetylene based emitter [J]. J. Mater. Chem. C, 2015, 3(10):2182-2194.
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Zhang X Y, Lin J, Ouyang X H, et al. Novel host materials based on phenanthro-imidazole derivatives for highly efficient green phosphorescent OLEDs [J]. J.Photochem. Photobio. A, 2013, 268:37-43.
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