ZHANG Lei, YANG Yang, GAO Jie-chao etc. Study on Amplified Spontaneous Emission Properties of EnBOD Material[J]. Chinese Journal of Luminescence, 2015,36(6): 661-665
ZHANG Lei, YANG Yang, GAO Jie-chao etc. Study on Amplified Spontaneous Emission Properties of EnBOD Material[J]. Chinese Journal of Luminescence, 2015,36(6): 661-665 DOI: 10.3788/fgxb20153606.0661.
Study on Amplified Spontaneous Emission Properties of EnBOD Material
Amplified spontaneous emission (ASE) properties of organic material EnBOD were studied under ultraviolet pulse laser pumping. EnBOD sample in dilute toluene solution shows narrow-band absorption and PL spectra
with the maximum peak located at 508 nm and 527 nm
respectively. The ASE efficiency changes with the solution concentration. The maximum ASE efficiency of 22.6% was obtained when the EnBOD sample concentration is 0.008 molL
-1
in which the ASE threshold is 29.5 kWcm
-2
ASE peak is 542 nm and full width at half maximum is about 12.4 nm. The ASE output intensity attenuated to 61.2% of the initial strength under the pulse pump frequency of 200 000. The results indicated that EnBOD is a kind of laser material with low ASE threshold and good light stability.
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Tang C W, Vanslyke S A. Organic electroluminescnet diodes [J]. Appl. Phys. Lett., 1987, 51(12):913-915.
Hu X H, Li F S, Xu S, et al. Effect of solvent dilution on preparation of PEDOT:PSS transparent conductive films and device performance of organic solar cells [J]. Chin. J. Lumin.(发光学报), 2014, 35(3):322-326 (in Chinese).
Ryu G S, Kim J S, Jeong S H, et al. A printed OTFT-backplane for AMOLED display [J]. Org. Electron., 2013, 14(4):1218-1224.
Galindo S, Ahmadpour M, Gerling L G, et al. Influence of the density of states on the open-circuit voltage in small-molecule solar cells [J]. Org. Electron., 2014, 15(10):2553-2560.
Kumar P, Sharma A, Yadav S, et al. Morphology optimization for achieving air stable and high performance organic field effect transistors [J]. Org. Electron., 2013, 14(6):1663-1672.
Jou J H, Kumar S, Agrawal A, et al. Approaches for fabricating high efficiency organic light emitting diodes [J]. J. Mater. Chem. C, 2015, 3(13):2974-3002.
Tsutsumi N, Kawahira T, Sakai W. Amplified spontaneous emission and distributed feedback lasing from a conjugated compound in various polymer matrices [J]. Appl. Phys. Lett., 2003, 83(13):2533-2535.
Hide F, Daz-Garca M A, Schwartz B J, et al. Semiconducting polymers: A new class of solid-state laser materials [J]. Science, 1996, 273(5283):1833-1836.
Cheng H, Hou Y B, Qin L, et al. Amplified spontaneous emission from the blend films of F8BT and P3HT [J]. Chin. J. Lumin.(发光学报), 2014, 35(8):1003-1008 (in Chinese).
Hermann S, Shallcross R C, Meerholz K. Simple fabrication of an organic laser by microcontact molding of a distributed feedback grating [J]. Adv. Mater., 2014, 26(34):6019-6024.
Ning S Y, Wu Z X, Dong H, et al. Enhancement of amplified spontaneous emission in organic gain media by the metallic film [J]. Org. Electron., 2014, 15(9):2052-2058.
Qu S Q, Li Y T, Wang L J, et al. Waveguide and ultralow-threshold amplified spontaneous emission in an aligned ordered solid state based on a highly fluorescent twin-tapered bi-1,3,4-oxadiazole derivative [J]. Chem. Commun., 2011, 47(14):4207-4209.
Boens N, Leena V, Dehaen W. Fluorescent indicators based on BODIPY [J]. Chem. Soc. Rev., 2012, 41(3): 1130-1172.
Osati S, Ali H, Van Lier J E. Synthesis and spectral properties of phthalocyanine-BODIPY conjugates [J]. Tetrahedron Lett., 2015, 56(16):2049-2053.
Durn-Sampedro G, Agarrabeitia A R, Cerdn L, et al. Carboxvlates versus fluorines: Boosting the emission properties of commercial BODIPYs in liquid and solid media [J]. Adv. Funct. Mater., 2013, 23(34):4195-4205.
Duran-Sampedro G, Esnal I, Agarrabeitia A R, et al. First highly efficient and photostable E and C derivatives of 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY) as dye lasers in the liquid phase, thin films, and solid-state rods [J]. Chem. Eur. J., 2014, 20(9):2646-2653.
Pavlopoulos T G, Shah M, Boyer J H. Laser action from a tetramethylpyrromethene-BF2 complex [J]. Appl. Opt., 1988, 27(24):4998-4999.
Sunahara H, Urano Y, Kojima H, et al. Design and synthesis of a library of BODIPY-based environmental polarity sensors utilizing photoinduced electron-transfer-controlled fluorescence ON/OFF switching [J]. J. Am. Chem. Soc., 2007, 129(17):5597-5604.