Properties of NIR Emissions with Energy-transfer Processes in Cr3+- and Yb3+-doped Y3Al5O12 Powder Materials

ZHANG Ji-sen; ZHANG Li-guo; REN Jian-yue; DUAN Pei-hua; LUO Yong-shi; LYU Shao-zhe

doi:10.3788/fgxb20153603.0262

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Properties of NIR Emissions with Energy-transfer Processes in Cr³⁺- and Yb³⁺-doped Y₃Al₅O₁₂ Powder Materials

更新时间：2020-08-12

- Properties of NIR Emissions with Energy-transfer Processes in Cr³⁺- and Yb³⁺-doped Y₃Al₅O₁₂ Powder Materials
- Chinese Journal of Luminescence Vol. 36, Issue 3, Pages: 262-266(2015)
- 作者机构：
  
  中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153603.0262
  CLC： O482.31
- Received：10 December 2014，
  
  Revised：05 January 2015，
  
  Published：03 March 2015
- 稿件说明：
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张继森, 张立国, 任建岳等. YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程[J]. 发光学报, 2015,36(3): 262-266

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue etc. Properties of NIR Emissions with Energy-transfer Processes in Cr3+- and Yb3+-doped Y3Al5O12 Powder Materials[J]. Chinese Journal of Luminescence, 2015,36(3): 262-266
张继森, 张立国, 任建岳等. YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程[J]. 发光学报, 2015,36(3): 262-266 DOI： 10.3788/fgxb20153603.0262.

ZHANG Ji-sen, ZHANG Li-guo, REN Jian-yue etc. Properties of NIR Emissions with Energy-transfer Processes in Cr3+- and Yb3+-doped Y3Al5O12 Powder Materials[J]. Chinese Journal of Luminescence, 2015,36(3): 262-266 DOI： 10.3788/fgxb20153603.0262.

摘要

室温下观察了YAG:Cr

材料在近红外区域的发光特性

并通过对Cr

和Yb

5/2

能级辐射跃迁寿命以及它们布居时间的比较研究

提出了从Cr

到Yb

的能量传递机制

同时借助于能级图描述了从Cr

到Yb

的能量传递以及Cr

和Yb

的近红外发光过程。

Abstract

- and Yb

-doped YAG powder samples were prepared and the energy transfer (ET) mechanism in the samples was evaluated by the photoluminescence (PL)

photoluminescence excitation (PLE) and light-emitting lifetime. By taking advantage of the spin allowed

and

absorption of Cr

and the efficient energy transfer from Cr

to Yb

the broadband spectral conversion makes Yb

5/2

7/2

transition give off a desirable emission around 1 000 nm

which is according to the maximum spectral response of c-Si solar cells

and hence would lead to the enhancement of silicon solar photovoltaic conversion efficiency.

关键词

Keywords

references

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