Synthesis and Characterization of Nd3+ Doped LaF3 Nanocrystals for Liquid Laser Medium

CHEN Zhuo; BO Shu-hui; TIAN Chang-yong; ZHEN Zhen; LIU Xin-hou

doi:10.3788/fgxb20153602.0129

您当前的位置：

首页 >

文章列表页 >

Synthesis and Characterization of Nd³⁺ Doped LaF₃ Nanocrystals for Liquid Laser Medium

更新时间：2020-08-12

- Synthesis and Characterization of Nd³⁺ Doped LaF₃ Nanocrystals for Liquid Laser Medium
- Chinese Journal of Luminescence Vol. 36, Issue 2, Pages: 129-134(2015)
- 作者机构：
  
  1. 中国科学院理化技术研究所中国科学院光化学转换与功能材料重点实验室北京,100190
  2. 中国科学院理化技术研究所中国科学院功能晶体与激光技术重点实验室北京,100190
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153602.0129
  CLC： O614.33
- Received：03 September 2014，
  
  Revised：19 November 2014，
  
  Published Online：03 December 2014，
  
  Published：03 February 2015
- 稿件说明：
移动端阅览
陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd3+离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134

CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd3+ Doped LaF3 Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134
陈卓, 薄淑晖, 田昌勇等. 用于液体激光介质的Nd3+离子掺杂氟化镧纳米颗粒的制备与性能表征[J]. 发光学报, 2015,36(2): 129-134 DOI： 10.3788/fgxb20153602.0129.

CHEN Zhuo, BO Shu-hui, TIAN Chang-yong etc. Synthesis and Characterization of Nd3+ Doped LaF3 Nanocrystals for Liquid Laser Medium[J]. Chinese Journal of Luminescence, 2015,36(2): 129-134 DOI： 10.3788/fgxb20153602.0129.

摘要

设计并合成了掺杂不同Nd

离子浓度的氟化镧纳米颗粒

并用油酸进行了表面修饰

使得这类纳米颗粒可分散于常见的有机溶剂中形成透明、均一、稳定的溶液.对纳米颗粒的结构、晶相以及发光性能进行了表征.固体和溶液材料在1 060 nm都有强的发射峰

说明纳米晶格可有效地保护Nd

离子免受外界环境对发光的猝灭影响.纳米颗粒有机溶液的吸收损耗和散射损耗测试结果表明

其总损耗系数能够满足激光介质材料的损耗要求

为该材料的实用化打下了基础.

Abstract

LaF

nanocrytals with different Nd

concentration were designed

synthesized and modified by oleic acid. This kind of nanocrystals can be dissolved in many organic solvents and form a transparent

uniform and stable solution. The structure

crystal phase and luminescence properties of LaF

:Nd

nanocrytals were characterized and studied. The nanocrytals show strong emission at 1 060 nm not only in solid but also in solution. This illustrates that the nanocrystal lattice can efficiently protect Nd

ions from the influence of environment on the luminescence. Meanwhile

the absorption loss and scattering loss of LaF

nanocrystals in organic solution were tested by our own system. The total loss coefficient can meet the requirements for laser medium material. These results show that LaF

:Nd

nanocrystals may be used for liquid laser medium in the future.

关键词

Keywords

references

Lu W, Yan L, Menyuk C R. Kerr-lens mode-locking of Nd:glass laser [J]. Opt. Commun., 2001, 200(1-6): 159-163.

Cantatore J L, Kriegel D A. Laser surgery: An approach to the pediatric patient [J]. J. Am. Acad. Dermatol., 2004, 50(2):165-184.

Nava E, Stucchi E. Development of lasers for spaceborne Doppler wind lidar applications [J]. Opt. Laser Eng., 2003, 39:255-263.

Ren G G. Current situation and development trend of high energy laser weapon [J]. Laser Optoelectron. Prog.(激光与光电子学进展), 2008, 45(9):62-69 (in Chinese).

Zhou S H. The heat managements of the solid-state lasers [J]. Chin. J. Quant. Electron.(量子电子学报), 2005, 22(4):497-509 (in Chinese).

Zhou S H, Zhao H, Tang X J. High average power laser diode pumped solid-state laser [J]. Chin. J. Lasers (中国激光), 2009, 36(7):1605-1618 (in Chinese).

Mei S S. Solid-state lasers marching to 100 kWA pilot study on overseas development of high energy solid state lasers [J]. Laser Optoelectron. Prog.(激光与光电子学进展), 2005, 42(10):2-8 (in Chinese).

Li J D, Guo M X, Fu W Q, et al. Thermal distortion influence on single-slab heat capacity laser output [J]. Chin. J. Lasers (中国激光), 2007, 34(1):45-49 (in Chinese).

Heller A. A high-gain room-temperature liquid laser: Trivalent neodymium in selenium oxychloride [J]. Appl. Phys. Lett., 1966, 9(3):106-107.

Heller A. Formation of hot OH bonds in the radiationless relaxations of excited rare earth ions in aqueous solutions [J]. J. Am. Chem. Soc., 1966, 88:2058-2059.

Winston H, Marsh O J, Suzuki C K. Fluorescence of europium thenoyltrifluoroacetonate I: Evaluation of laser threshold parameters [J]. J. Chem. Phys., 1963, 39(2):267-271.

Miao T Z, Zhang Z, Feng W X, et al. Temperature-dependent self-assembly of near-infrared (NIR) luminescent Zn2Ln and Zn2Ln3 (Ln=Nd, Yb or Er) complexes from the flexible Salen-type Schiff-base ligand [J]. Spectrochim. Acta Part A: Mol. Biomol. Spectrosc., 2014, 132:205-214.

Xu X D, Wang X D, Meng J Q, et al. Crystal growth, spectral and laser properties of Nd:LuAG single crystal [J]. Laser Phys. Lett., 2009, 6(9):678-681.

Lin J, Li C X. Hydrothermal synthesis, formation mechanisms and luminescence properties of the rare earth fluorides nano- and micro-materials [J]. Chin. J. Lumin.(发光学报), 2011, 32(6):519-534 (in Chinese).

Zhuo Z, Li T, Li S G, et al. A new composite YVO4/Nd:Y0.9La0.1VO4 crystal laser end-pumped with a fiber coupled diode array [J]. Laser Phys. Lett., 2009, 6(6):445-449.

Yu K H, Qiu X M, Xu X X, et al. Enhanced photoluminescence of Nd2O3 nanoparticles modified with silane-coupling agent: Fluorescent resonance energy transfer analysis [J]. Appl. Phys. Lett., 2007, 90(9):091916-1-3.

Yu R B, Yu K H, Wei W, et al. Nd2O3 nanoparticles modified with a silane-coupling agent as a liquid laser medium [J]. Adv. Mater., 2007, 19:838-842.

Wang G, Peng Q. Tunable photoluminescence of NaYF4:Eu nanocrystals by Sr2+ codoping [J]. Solid State Chem., 2011, 184:59-63.

Achary S N, Tyagi A K, Seshagiri T K, et al. Synthesis, powder XRD studies on LiF-BaF2/EuF3 systems and thermo-stimulated luminescence (TSL) of Eu3+ doped LiBaF3 [J]. Mater. Sci. Eng. B, 2006, 129:256-260.

Shen L F, Laibinis P E, Hatton T A. Bilayer surfactant stabilized magnetic fluids: Synthesis and interactions at interfaces [J]. Langmuir, 1999, 15(2):447-453.

Kim J, Lee J H, An H J, et al. Luminescence properties of LaF3:Ce nanoparticles encapsulated by oleic acid [J]. Mater. Res. Bull., 2014, 57:110-115.

Thistlethwaite P J, Hook M S. Diffuse reflectance Fourier transform infrared study of the absorption of oleate/oleic acid onto titania [J]. Langmuir, 2000, 16(11):4993-4998.

Thistlethwaite P J, Gee M L, Wilson D. Diffuse reflectance infrared Fourier transform spectroscopic studies of the adsorption of oleate/oleic acid onto zirconia [J]. Langmuir, 1996, 12(26):6487-6491.

Nara M, Torii H, Tasumi M. Correlation between the vibrational frequencies of the carboxylate group and the types of its coordination to a metal ion: An ab initio molecular orbital study [J]. J. Phys. Chem., 1996, 100(51):19812-19817.

Delphine P, Yan S, Mohamed B T, et al. Optical properties of Nd3+ and Yb3+-doped AgM(IO3)4 metal iodates: Transparent host matrices for mid-IR lasers and nonlinear materials [J]. J. Mater. Chem. C, 2014, 2:2715-2723.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Hydrothermal Systheis and Upconversion Emission Properties of GdInO₃: Yb³⁺/Ho³⁺ Phosphors

Dependent of Upconversed Emission on Excited Power in Yb³⁺-Er³⁺-codoped Fluorides

Effect of Sm³⁺ Doping on Structural and Luminescent Properties of CaMoO₄ ∶ Eu³⁺ Red Phosphors

Effects of Excitation Wavelength and the Eu²⁺-doped Content on Phosphorescence of Sr₄Al₁₄O₂₅ ∶ Eu²⁺ , Dy³⁺

Photoluminescent Properties of La and Ce Doped ZnO Nanocrystals

Related Author

PENG Guang-huai

LIAO Jin-sheng

KONG Li-yun

WANG Ming-hua

LV Shao-zhe

ZHANG Li-ping

REN Jian-yue

ZHANG Ji-sen

Related Institution

School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology

Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

Heilongjiang Key Laboratory of Advanced Functional Materials and Excited State Processes, School of Physics and Electronics Engineering, Harbin Normal University

江西财经大学新能源技术与应用研究中心

School of Materials Science and Engineering, Shandong University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰