Preparation and Luminescent Properties of Terbium-doped Hydroxyapatite

QIAO Yin-po; LI Yan-xiao; YIN Hai-rong; LIU Pan; LI Si-yuan; ZHANG Pan

doi:10.3788/fgxb20153601.0063

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Preparation and Luminescent Properties of Terbium-doped Hydroxyapatite

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- Preparation and Luminescent Properties of Terbium-doped Hydroxyapatite
- Chinese Journal of Luminescence Vol. 36, Issue 1, Pages: 63-68(2015)
- 作者机构：
  
  陕西科技大学材料科学与工程学院,陕西西安,710021
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153601.0063
  CLC： O482.31
- Received：06 October 2014，
  
  Revised：16 November 2014，
  
  Published：03 January 2015
- 稿件说明：
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乔荫颇, 李艳肖, 殷海荣等. 铽掺杂羟基磷灰石的制备及其荧光特性[J]. 发光学报, 2015,36(1): 63-68

QIAO Yin-po, LI Yan-xiao, YIN Hai-rong etc. Preparation and Luminescent Properties of Terbium-doped Hydroxyapatite[J]. Chinese Journal of Luminescence, 2015,36(1): 63-68
乔荫颇, 李艳肖, 殷海荣等. 铽掺杂羟基磷灰石的制备及其荧光特性[J]. 发光学报, 2015,36(1): 63-68 DOI： 10.3788/fgxb20153601.0063.

QIAO Yin-po, LI Yan-xiao, YIN Hai-rong etc. Preparation and Luminescent Properties of Terbium-doped Hydroxyapatite[J]. Chinese Journal of Luminescence, 2015,36(1): 63-68 DOI： 10.3788/fgxb20153601.0063.

摘要

在室温下采用化学沉淀法制备了铽掺杂的羟基磷灰石(Tb-HAP)

通过X射线衍射分析(XRD)、傅里叶变换红外光谱(FT-IR)和荧光光谱(PL)等对其结构和荧光性能进行了表征分析。XRD和FT-IR测试表明

的掺杂对羟基磷灰石的结构没有显著影响。荧光光谱分析表明:在545 nm波长监测下

测得的最佳激发波长为378 nm。样品的发光强度随Tb

在样品中的掺杂摩尔分数先增大后减小

在8%时发光最强。此外

Tb-HAP样品的荧光寿命随着Tb

掺杂摩尔分数的增加呈现减小的趋势。

Abstract

Hydroxyapatite particles doped with Tb

(Tb-HAP) were prepared

via

chemical deposition method. The crystalline phase

structural and fluorescent properties of the samples were investigated by X-ray diffraction (XRD)

Fourier transform infarred (FT-IR) spectroscopy

and photoluminescence (PL) measurements

respectively. XRD and FT-IR results show that Tb

doping has no significant influence on the structure of HAP. PL spectra of Tb-HAP samples show that the best excitation light is 378 nm when the wavelength of the monitoring light is 545 nm. The luminescent intensity of Tb-HAP sample reaches the maximum when the doping mole fraction of Tb

is 8%. Furthermore

the fluorescent life of Tb-HAP samples present a decreasing trend along with the increasing of Tb

concentration.

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Keywords

references

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