Synthesis, Structure and Luminescent Property of 1D Complex [Tb(3,5-pdc)(3,5-Hpdc)(H2O)(phen)]n

WANG Hong-sheng; WANG Lei; LI Gong-chun; LI Ying-ying; HUANG Bao-jun; WU Chang-zeng

doi:10.3788/fgxb20153601.0050

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Synthesis, Structure and Luminescent Property of 1D Complex [Tb(3,5-pdc)(3,5-Hpdc)(H₂O)(phen)]_n

更新时间：2020-08-12

- Synthesis, Structure and Luminescent Property of 1D Complex [Tb(3,5-pdc)(3,5-Hpdc)(H₂O)(phen)]_n
- Chinese Journal of Luminescence Vol. 36, Issue 1, Pages: 50-56(2015)
- 作者机构：
  
  许昌学院化学化工学院,河南许昌,461000
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20153601.0050
  CLC： O482.31;O614.341
- Received：09 October 2014，
  
  Revised：09 November 2014，
  
  Published：03 January 2015
- 稿件说明：
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王宏胜, 王磊, 李公春等. 1D配合物[Tb(3,5-pdc)(3,5-Hpdc)(H2O)(phen)]n的合成、晶体结构及发光性质[J]. 发光学报, 2015,36(1): 50-56

WANG Hong-sheng, WANG Lei, LI Gong-chun etc. Synthesis, Structure and Luminescent Property of 1D Complex [Tb(3,5-pdc)(3,5-Hpdc)(H2O)(phen)]n[J]. Chinese Journal of Luminescence, 2015,36(1): 50-56
王宏胜, 王磊, 李公春等. 1D配合物[Tb(3,5-pdc)(3,5-Hpdc)(H2O)(phen)]n的合成、晶体结构及发光性质[J]. 发光学报, 2015,36(1): 50-56 DOI： 10.3788/fgxb20153601.0050.

WANG Hong-sheng, WANG Lei, LI Gong-chun etc. Synthesis, Structure and Luminescent Property of 1D Complex [Tb(3,5-pdc)(3,5-Hpdc)(H2O)(phen)]n[J]. Chinese Journal of Luminescence, 2015,36(1): 50-56 DOI： 10.3788/fgxb20153601.0050.

摘要

用硝酸铽与3

5-吡啶二甲酸、邻菲罗啉在水热条件下进行反应

合成了配合物[Tb(3

5-pdc)(3

5-Hpdc)(H

O)(phen)]

5-H

pdc =3

5-吡啶二甲酸

phen=1

10-邻菲罗啉)。单晶X射线衍射测试表明

该配合物属单斜晶系

空间群

晶胞参数分别为:

=2.734 9(3) nm

=1.099 48(12) nm

=2.200 0(3) nm

= 90

=132.147 3(12)

= 8

=4 904.8(10) nm

。配合物中Tb

与配体3

5-pdc

和3

5-Hpdc

交替连接形成了一维链结构

链与链之间通过邻菲罗啉芳香环的堆积弱相互作用形成了三维结构。在波长为352 nm的紫外光激发下

配合物发射出Tb

的特征荧光。

Abstract

A terbium complex [Tb(3

5-pdc)(3

5-Hpdc)(H

O)(phen)]

5-H

pdc=3

5-pyridinedicarboxylic acid

phen=1

10-phenanthroline) was synthesized by reacting terbium nitrate with 3

5-H

pdc and phen at hydrothermal condition. X-ray diffraction analysis of single crystal shows that the complex is crystallized in monoclinic system

C2/c

space group. The cell parameters are as follows:

= 2.734 9(3) nm

=1.099 48(12) nm

=2.200 0(3) nm

=132.147 3(12)

= 90

=4.904 8(10) nm

. One-dimensional chain structure is constructed by alternated connection between Tb

ions and 3

5-pyridinedicarboxylates for the complex. A three-dimensional coordination polymer is formed by the stacking interaction between the phen ligands. The complex exhibits intense characteristic luminescence of Tb

ion under 352 nm excitation.

关键词

Keywords

references

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