RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films

LI Peng; FAN Di; GAO Jie; LI Bin; HAN Guang-xi

doi:10.3788/fgxb20143512.1480

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RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films

更新时间：2020-08-12

- RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films
- Chinese Journal of Luminescence Vol. 35, Issue 12, Pages: 1480-1486(2014)
- 作者机构：
  
  1. 发光学及应用国家重点实验室中国科学院长春光学精密机械与物理研究所,吉林长春,130033
  2. 长春市中科软件有限公司,吉林长春,130012
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143512.1480
  CLC： O625.8
- Received：26 May 2014，
  
  Revised：16 June 2014，
  
  Published Online：18 July 2014，
  
  Published：03 December 2014
- 稿件说明：
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李鹏, 范镝, 高颉等. 不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究[J]. 发光学报, 2014,35(12): 1480-1486

LI Peng, FAN Di, Gao Jie etc. RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films[J]. Chinese Journal of Luminescence, 2014,35(12): 1480-1486
李鹏, 范镝, 高颉等. 不对称卟啉共价固载于硅基介孔薄膜材料模拟RS触发器的研究[J]. 发光学报, 2014,35(12): 1480-1486 DOI： 10.3788/fgxb20143512.1480.

LI Peng, FAN Di, Gao Jie etc. RS Latch Realization by Using Asymmetric Porphyrin Covalently Connecting to Mesoporous Silica Films[J]. Chinese Journal of Luminescence, 2014,35(12): 1480-1486 DOI： 10.3788/fgxb20143512.1480.

摘要

合成了5-(4-氨基苯基)-10

20-三苯基卟啉(ATPP)

并成功将其以共价嫁接的形式固载于介孔二氧化硅薄膜.基于卟啉化合物对酸碱的特异性响应

实现了对RS触发器逻辑功能的模拟.卟啉化合物被共价固载于介孔薄膜材料使得该分子逻辑器件具有相对较大的表面积、周期性排布的均一孔道结构以及高的光透过性等介孔薄膜材料的优异性质.这种混合多孔结构不但有利于嫁接于介孔材料中的卟啉与酸碱的更有效相互作用

而且还使酸碱输入能够被更加彻底地清除.

Abstract

5-(4-aminophenyl)-10

20-triphenyl-porphyrin (H

ATPP) was prepared and covalently connected to mesoporous silica thin films. Based on the porphyrin compounds's characteristic of being sensitive to acid and base

the molecular logics of RS-latch for sequential logic were achieved. The molecular logics have the advantages of larger surface area

periodic arranged uniform pore structure

and high transmission because of the covalent connection of porphyrin compounds to mesoporous silica. This hybrid mesoporous structure is not only advantageous to the interaction between the inputs and response materials

but also advantageous to the separation of the response materials and inputs without information loss.

关键词

Keywords

references

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Related Institution

State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

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College of Material Science and Chemical Engineering, Zhejiang University

Institute of Functiona Materials for Photonics and Electronics, Ningbo University

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