Synthesis and Spectral Tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)

DONG Xiao-rui; FU Zuo-ling; WANG Chang-geng; ZHANG Fang-cheng

doi:10.3788/fgxb20143511.1311

您当前的位置：

首页 >

文章列表页 >

Synthesis and Spectral Tuning of CaZrO₃:Ln (Ln=Pr³⁺, Sm³⁺, Tb³⁺, Dy³⁺, Tm³⁺)

更新时间：2020-08-12

- Synthesis and Spectral Tuning of CaZrO₃:Ln (Ln=Pr³⁺, Sm³⁺, Tb³⁺, Dy³⁺, Tm³⁺)
- Chinese Journal of Luminescence Vol. 35, Issue 11, Pages: 1311-1316(2014)
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 吉林大学物理学院,吉林长春,130021
  3. 东北电力大学理学院,吉林吉林,132012
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143511.1311
  CLC： O482.31
- Received：12 August 2014，
  
  Revised：16 September 2014，
  
  Published：03 November 2014
- 稿件说明：
移动端阅览
董晓睿, 付作岭, 王长庚等. CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) 荧光粉的制备与光谱调控[J]. 发光学报, 2014,35(11): 1311-1316

DONG Xiao-rui, FU Zuo-ling, WANG Chang-geng etc. Synthesis and Spectral Tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)[J]. Chinese Journal of Luminescence, 2014,35(11): 1311-1316
董晓睿, 付作岭, 王长庚等. CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+) 荧光粉的制备与光谱调控[J]. 发光学报, 2014,35(11): 1311-1316 DOI： 10.3788/fgxb20143511.1311.

DONG Xiao-rui, FU Zuo-ling, WANG Chang-geng etc. Synthesis and Spectral Tuning of CaZrO3:Ln (Ln=Pr3+, Sm3+, Tb3+, Dy3+, Tm3+)[J]. Chinese Journal of Luminescence, 2014,35(11): 1311-1316 DOI： 10.3788/fgxb20143511.1311.

摘要

采用高温固相法合成了稀土离子Pr

、Sm

、Tb

、Dy

、Tm

掺杂的正交相CaZrO

荧光粉。利用X射线粉末衍射(XRD)对样品的结构进行表征

并通过荧光光谱对其发光性质进行了研究。在适当近紫外或蓝光激发下

CaZrO

:Pr

产生很强的绿光发射

CaZrO

:Sm

可发射550~700 nm的红橙光

在CaZrO

中可获得良好的蓝光发射。研究结果表明

通过改变CaZrO

中的掺杂离子可实现其发光颜色的调控

稀土离子掺杂CaZrO

荧光粉是很有潜力的新型发光材料。

Abstract

The orthorhombic CaZrO

(

=Pr

) were successfully synthesized by solid-state reaction method. The crystalline structure of the samples were characterized by X-ray diffraction (XRD). The luminescence properties were investigated using photoluminescence spectra. Under appropriate near UV- or blue light-radiation

CaZrO

:Pr

showed strong green light emission

CaZrO

:Sm

showed well reddish orange light in the range of 550-700 nm

and CaZrO

:Tm

generated well blue light emission. The results indicate that spectral tuning can be realized by adjusting active ions in CaZrO

thus rare earth ions-doped CaZrO

phosphors can be exploited as new luminescence materials.

关键词

Keywords

references

Gordon W O, Carter J A, Tissue B M. Long-lifetime luminescence of lanthanide-doped gadolinium oxide naoparticles for immunoassays [J]. J. Lumin., 2004, 108(1-4):339-342.

Puchalska M, Zych E. The effect of charge compensation by means of Na+ ions on the luminescece behavior of Sm3+-doped CaAl4O7 phosphor [J]. J. Lumin., 2012, 132(3):826-831.

Zhang S Y, Nakai Y, Tsuboi T, et al. Luminescence and microstructural features of Eu-activated LiBaPO4 phoshor [J]. Chem. Mater., 2011, 23(5):1216-1224.

Zhang J H, Lv W, Hao Z D, et al. Color-tunable white-light emitting BaMg2Al6Si9O30:Eu2+, Tb3+,Mn2+ phosphors via energy transfer [J]. Chin. Opt.(中国光学), 2012, 5(3):203-208 (in Chinese).

Iwahara H, Asakura Y, Katahira K, et al. Prospect of hydrogen technology using proton-donducting ceramic [J]. Solid State Ionics, 2004, 168(3-4):299-310.

Zhang H, Fu X, Niu S, et al. Synthesis and photoluminescence properties of Eu3+-doped AZrO3(A=Ca, Sr, Ba) perovskite [J]. J. Alloys Compd., 2008, 459(1-2):103-106.

Pan Y, Su Q, Xu H, et al. Synthesis and red luminescence of Pr3+-doped CaTiO3nanophosphor from polymer precursor [J]. J. Solid State Chem., 2003, 174(1):69-73.

Lemanski K, Gagor A, Kurnatowska M, et al. Spectoscopic properties of Nd3+ ions in nano-perovskite CaTiO3 [J]. J. Solid State Chem., 2011, 184(10):2713-2718.

Zhang J S, Chen B J, Liang Z Q, et al. Optical transition and thermal quenching mechanism in CaSnO3:Eu3+ phosphors [J]. J. Alloys Compd., 2014, 612(5):204-205.

He G G, Liu Y L, Lei B F. Luminescence properties of CaSnO3:Pr3+ perovskite phosphor [J]. Chin. J. Lumin.(发光学报), 2007, 28(3):389-392 (in Chinese).

Ha M G, Byeon M R, Hong T E, et al. Sm3+-doped CaTiO3 phosphor: Synthesis, structure, and photoluminescent properties [J]. Ceram. Int., 2012, 38(2):1365-1370.

Wu Y B, Sun Z, Ruan K B, et al. Structural and optical properties of Ca0. 88TiO3:0.12Eu3+ red phosphors [J]. Chin. J. Lumin.(发光学报), 2014, 35(8):932-938 (in Chinese).

Liu X M, Lin J. LaGaO3:A (A=Sm3+ and/or Tb3+) as promising phosphors for field emission displays [J]. J. Mater. Chem., 2008, 18(2):221-228.

Rog G, Dudek M, Rog A K, et al. Calcium zirconate: Preparation, properties and application to the solid oxide galvanic cells [J]. Electrochim. Acta, 2002, 47(28):4523-4529.

Yu T, Chen C H, Chen X F, et al. Fabrication and characterization of perovskite CaZrO3 oxide thin films [J]. Ceram. Int., 2004, 30(7):1279-1282.

Lee W J, Wakahara A, Kim B H. Decreasing of CaZrO3 sintering temperature with glass frit addition [J]. Ceram. Int., 2005, 31(7):521-524.

Szczerba J, Pezich Z. The effect of natural dolomite admixtures on calaiumzironate-periclase materials microstructure evolution [J]. Ceram. Int., 2010, 36(2):535-547.

Ross N L, Chaplin T D. Compressibility of CaZrO3 perovskite: Comparison with Ca-oxide perovskite original research article [J]. J. Solid State Chem., 2003, 172(1):123-126.

Stoch P, Szczerba J, Lis J, et al. Crystal structure and abinito calculations of CaZrO3 [J]. J. Eur. Ceram. Soc., 2012, 32(3):665-670.

Hou Z F. Abignition calculations of elastic modulus and electronic structures of cubic CaZrO3 [J]. Phys. B, 2008, 403(17):2624-2628.

Ianos R, Barvinschi P. Solution combustion synthesis of calcium zirconate, CaZrO3, powders [J]. J. Solid State Chem., 2010, 183(3):491-496.

Rij L V, Winnubst L, Jun L, et al. Analysis of the preparation of In-doped CaZrO3 using a peroxo-oxalate complexation method [J]. J. Mater. Chem., 2000, 10(11):2515-2521.

Yu T,Chen C H, Lu Y K, et al. Preparation of sol-gel-derived Ca1-xSrxZrO3 perovskite dielectric thin films [J]. J. Electroceram., 2007, 18(1-2):149-154.

Zhou M H, Ahmad A, Sol-gel processing of In-doped CaZrO3 solid electrolyte and the impedimetric sensing characteristics of humidity and hydrogen [J]. Sens. Actuat. B, 2008, 129(1):285-291.

Du Q Q, Zhou G J, Zhou J, et al. Enhanced photoluminescence of CaZrO3:Er3+ by efficient energy transfer from Ce3+ [J]. Mater. Res. Bull., 2012, 47(11):3774-3779.

Hao Z D, Zhang J H, Zhang X, et al. Blue-green-emitting phosphor CaSc2O4:Tb3+: Tunable luminescence manipulated by cross-relaxation [J]. J. Electronchem. Soc., 2009, 156(3):H193-H196.

Nugent L J, Baybarz R D, Burnett J L, et al. Elentron-transfer and f-d absorption bands of some lanthanide and actinide complexes and the standard (Ⅱ-Ⅲ) oxidation potential for each member of the lanthanide and actinide series [J]. J. Phys. Chem., 1973, 77(12):1528-1539.

Zhang H W, Fu X Y, Niu S Y, et al. Blue luminescence of nanocrystalline CaZrO3:Tm3+phosphors synthesized by a modified Pechini sol-gel method [J]. J. Lumin., 2008, 128(8):1348-1352.

Zhang A Y, Lv M K, Wang S F, et al. Novel photoluminescence of SrZrO3 nanocrystals synthesized through a facile combustion method [J]. J. Alloys Compd., 2007, 433(1-2):L7-L11.

Yamamoto H, Mikami M, Shimomura Y, et al. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+ [J]. J. Lumin., 2000, 87-89(5):1079-1082.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Dual-mode Optical Thermometry with High Sensitivity Achieved in Na₃Y(VO₄)₂∶Yb³⁺/Er³⁺

Research Progress in Up-conversion Fluorescent Fluosilicate Glass Ceramics

Spectra Control of Perovskite Luminescence and Optoelectronic Devices

Structure Change of GdF₃:Yb³⁺,Er³⁺ and Influence on Properties of Upconversion Luminescence by High Temperature Annealing

Photoluminescence Properties and Color Tunable of NaTaOGeO₄: Tb³⁺ Co-doped with Mn²⁺ Ion

Related Author

XIANG Guotao

YI Yuanyuan

ZHANG Yu

XIONG Ming

XU Qinyu

CHEN Hongdou

CHANG Ying

YAO Lu

Related Institution

Department of Mathematics and Physics， Chongqing University of Posts and Telecommunications

School of Physics and Electronic Engineering， Jiangsu Normal University

College of Physics and Optoelectronic Engineering， Harbin Engineering University

School of Physics and Electronic Engineering， Taishan University， Taishan

State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰