Preparation of TiO2/Eu3+ Down-conversion Film and Its Application in Dye-sensitized Solar Cells

WANG Hui-li; NIE Ming-qi; HAO Hong-shun; HU Zhi-qiang; GAO Wen-yuan; LIU Gui-shan

doi:10.3788/fgxb20143510.1182

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Preparation of TiO₂/Eu³⁺ Down-conversion Film and Its Application in Dye-sensitized Solar Cells

更新时间：2020-08-12

- Preparation of TiO₂/Eu³⁺ Down-conversion Film and Its Application in Dye-sensitized Solar Cells
- Chinese Journal of Luminescence Vol. 35, Issue 10, Pages: 1182-1187(2014)
- 作者机构：
  
  大连工业大学纺织与材料工程学院, 辽宁大连 116034
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143510.1182
  CLC： TB321;TM914.4
- Received：30 July 2014，
  
  Revised：09 August 2014，
  
  Published：03 October 2014
- 稿件说明：
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王辉利, 聂铭歧, 郝洪顺等. TiO2/Eu3+下转换薄膜的制备及其在染料敏化太阳能电池中的应用[J]. 发光学报, 2014,35(10): 1182-1187

WANG Hui-li, NIE Ming-qi, HAO Hong-shun etc. Preparation of TiO2/Eu3+ Down-conversion Film and Its Application in Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2014,35(10): 1182-1187
王辉利, 聂铭歧, 郝洪顺等. TiO2/Eu3+下转换薄膜的制备及其在染料敏化太阳能电池中的应用[J]. 发光学报, 2014,35(10): 1182-1187 DOI： 10.3788/fgxb20143510.1182.

WANG Hui-li, NIE Ming-qi, HAO Hong-shun etc. Preparation of TiO2/Eu3+ Down-conversion Film and Its Application in Dye-sensitized Solar Cells[J]. Chinese Journal of Luminescence, 2014,35(10): 1182-1187 DOI： 10.3788/fgxb20143510.1182.

摘要

采用溶胶-凝胶法制备了TiO

/Eu

下转换薄膜，并对其光学特性和光电性能进行了分析。将其应用到染料敏化太阳能电池（DSSC）中，利用其下转换特性将部分紫外光转换为能被染料吸收利用的可见光，提高了DSSC的光照强度，促进了短路电流的增大。荧光光谱显示，下转换薄膜在受到394 nm紫外光照射时可发射出550~640 nm的可见光，具有下转换功能特性。下转换薄膜可以增加电池对太阳光的吸收范围，当涂有二层下转换薄膜时，短路电流密度从8.05 mAcm

-2

提高到9.62 mAcm

-2

，光电转换效率从3.67%提高到4.32%，转换效率相对提高了17.7%。

Abstract

TiO

/Eu

down-conversion film was prepared by sol-gel method

and its optical and photoelectric properties were analyzed. Applying it to dye-sensitized solar cells (DSSC)

partial UV light can be converted to visible light and absorbed by dye according to its down-conversion feature

as thus

the visible light intensity and short circuit currents are improved. The fluorescence spectra show that the down-conversion film can emit 550-640 nm visible light under 394 nm UV light excitation

which indicates a down-conversion feature of the film. The down-conversion film can increase the wavelength range of DSSC absorption. When bilayer down-conversion films are coated on DSSC

the short circuit current increases from 8.05 mAcm

-2

to 9.62 mAcm

-2

the photoelectric conversion efficiency increases from 3.67% to 4.32%.

关键词

Keywords

references

O'Regan B, Grtzel M. A low-cost high-cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J]. Nature, 1991, 353:737-740.

Gao S W, Lan Z, Wu W X, et al. Fabrication and photovoltaic performance of high efficiency front-illuminated dye-sensitized solar cell based on ordered TiO2 nanotube arrays[J]. Acta Phys.-Chim. Sinica (物理化学学报), 2014, 30(3): 446-452 (in Chinese).

Hu Z Q, Qin Y, Jiang Y Y, et al. Preparation of spinel CoAl2O4 nanopowders and their applications to DSSC[J]. Opt. Precision Eng.(光学精密工程), 2013, 21(8):2016-2022 (in Chinese).

Hu Z Q, Liu X Q, Huang D F, et al. The preparation and properties of DSSC CuAl2O4/TiO2 photoanodes[J]. J. Mater. Eng.(材料工程), 2012(2):63-66 (in Chinese).

Avellaneda C O, Gonalves A D, Benedetti J E, et al. Preparation and characterization of core-shell electrodes for application in gel electrolyte-based dye-sensitized solar cells[J]. Electrochim. Acta, 2010, 55(4):1468-1474.

Li S Q, Lin J M, Wu J H, et al. Applications of upconversion luminescence of Ho3+ in dye sensitized solar cell[J]. J. Funct. Mater.(功能材料), 2009, 40(1):82-85 (in Chinese).

Wang J L, Lin J M, Wu J H, et al. The application of down-conversion luminescent powder Y2O3/Sm3+ in dye-sensitized solar cell[J]. J. Xiamen Univ.(厦门大学学报), 2011, 50(z):98-101 (in Chinese).

Chen S Y, Lin J M, Wu J H. Facile synthesis of Y2O3:Dy3+ nanorods and its application in dye-sensitized solar cells[J]. Appl. Surf. Sci., 2014, 293:202-206.

Chen S Y, Lin J M, Wu J H. Improving photoelectrical performance of dye sensitized solar cells by doping Y2O3:Tb3+ nanorods[J]. J. Mater. Sci.: Mater. Electron., 2014, 25(5):2060-2065.

Setiawati E, Kawano K. Stabilization of anatase phase in the rare earth: Eu and Sm ion doped nanoparticle TiO2[J]. J. Alloys Compd., 2008, 451(1):293-296.

Li L, Lei J G, Ji T H, et al. Preparation and characterization of Yb3+, Er3+ and Eu3+-codoped TiO2 nanobelts[J]. J. Funct. Mater.(功能材料), 2012, 43(1):24-27 (in Chinese).

Geng J, Tian L H. Photoluminescence properties of Sr2+ doped Ca2Nb2O7:Eu3+ red-emitting phosphor[J]. Chin. J. Lumin.(发光学报), 2014, 35(8):945-949 (in Chinese).

Liu Z G, Yan S J, Wang M T, et al. Spectral properties and energy transfer of zinc borosilicate glass doped with Eu3+, Ce3+[J]. Bull. Chin. Ceram. Soc.(硅酸盐通报), 2012, 31(3):559-562 (in Chinese).

Yang Y, Chen Y J, Xiao L J, et al. Synthesis and luminescent properties of Sr3B2O6:Eu3+, Li+ phosphor[J]. Chin. J. Lumin.(发光学报), 2014, 35(3):317-321 (in Chinese).

Yang J, Chen B J, Pun E Y B, et al. Excitation wavelength-sensitive multi-colour fluorescence in Eu/Tb ions doped yttrium aluminium garnet glass ceramics[J]. J. Lumin., 2013, 134:622-628.

Liu G J, Hu X Y, Pan J, et al. Preparation and luminescence properties of Eu3+ doped TiO2 nano-power[J]. Acta Photon. Sinica (光子学报), 2010, 39(9):1547-1552 (in Chinese).

Hu Z Q, Qin Y, Jiang Y Y, et al. Preparation of spinel CoAl2O4 nanopowders and their applications to DSSC[J]. Opt. Precision Eng.(光学精密工程) , 2013, 21(8):2016-2022 (in Chinese).

Ma T L, Yun S N. Dye-sensitized Solar Cells-theoretical Basis to Technical Applicition [M]. Beijing: Chemical Industry Press, 2013:14-15 (in Chinese).

Nie M Q, Hu Z Q, Qin Y Y, et al. Preparation of TiO2/Sm3+ down-conversion film and its application in dye-sensitized solar cell[J]. Chin. J. Lumin.(发光学报), 2014, 35(8):974-979 (in Chinese).

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