CHEN Yun-han, ZHANG Xue, ZHOU Jie etc. Effect of Red, Green CdSe@ZnS Quantum Dots Ratios on Standard Three-band White LED Devices[J]. Chinese Journal of Luminescence, 2014,35(8): 992-997
CHEN Yun-han, ZHANG Xue, ZHOU Jie etc. Effect of Red, Green CdSe@ZnS Quantum Dots Ratios on Standard Three-band White LED Devices[J]. Chinese Journal of Luminescence, 2014,35(8): 992-997 DOI: 10.3788/fgxb20143508.0992.
Effect of Red, Green CdSe@ZnS Quantum Dots Ratios on Standard Three-band White LED Devices
Highly-fluorescent green and red CdSe/ZnS core/shell gradient alloy quantum dots (QDs) were synthesized by one-step method. The phosphine-free three-band white light LEDs were fabricated by directly incorporating QDs/epoxy composites with blue InGaN chip. The influences of the content and proportion of red (650 nm) and green (550 nm) QDs on the color coordinate and efficiency of white LED were researched. When the red/green QDs ratio is 2:3
the standard three-band RGB QDs-WLED can be achieved with a CIE-1931 color coordinates of (0.322 8
0.335 9)
CCT of 5 725 K
CRI of 72.7
and power efficiency of 26.61 lm/W. FWHM of the red
blue
and green peak of the white QDs-LED is 30
25
and 38 nm
respectively.
关键词
Keywords
references
Rossetti R, Nakahara S, Brus L E, et al. Quantum size effects in the redox potentials, resonance raman-spectra, and elecronics-spectra of cds crystallites in aqueous-solution [J]. Chem. Phys., 1983, 79(3):1086-1109.
Zhao Y B, Su Z S, Jin F M, et al. High efficiency phosphorescent organic light-emitting devices based on multiple quantum well structure [J]. Chin. J. Lumin.(发光学报), 2012, 33(8):803-807 (in Chinese).
Bruchez M, Moronne M, Gin P, et al. Semiconductor nanocrystals as fluorescent biological labels. [J]. Science, 1998, 281(5385):2013-2016
Reiss P, Protiere M, Li L. Core/shell semiconductor nanocrystals [J]. Small, 2009, 5:154-168.
Talapin D V, Mekis I, Gotzinger S, et al. CdSe/CdS/ZnS and CdSe/ZnSe/ZnS core-shell-shell nanocrystals [J]. Phys. Chem. B, 2004, 108(49):18826-18831.
Xie R, Kolb U, Li J, et al. Synthesis and characterization of highly luminescent CdSe-core CdS/Zn0.5Cd0.5S/ZnS multishell nanocrystals [J]. Am. Chem. Soc., 2005, 127(20):7480-7488.
Chen H S, Wang S J. White-light emission from organics-capped ZnSe quantum dots and application in white-light-emitting diodes [J]. Appl. Phys. Lett., 2005, 86(13):131905-1-3.
Lim J, Jun S, Jang E, et al. Preparation of highly luminescent nanocrystals and their application to light-emitting diodes [J]. Adv. Mater., 2007, 19(15):1927-1931.
Wang Y C, Wang M, Su X Y, et al. First principles on the electron structure and optical properties of the Mg-doped CdSe system [J]. Chin. J. Lumin.(发光学报), 2010, 31(6):842-847 (in Chinese).
Liu A H, Yang L Y. Improved performance of organic light emitting diodes using combined hole-injecting layer [J]. Chin. J. Lumin.(发光学报), 2012, 33(4):422-427 (in Chinese).
Lee J, Sundar V C, Bawendi M G, et al. Full color emission from Ⅱ-Ⅵ semiconductor quantum dot polymer composites [J]. Adv. Mater., 2000, 12:1102-1205.
Chen H S, Hsu C K, Hong H Y. InGaN-CdSe-ZnSe quantum dots white LEDs [J]. IEEE Photon. Technol. Lett., 2006,18:193-195.
Wang H, Lee K S, Ryu J H, et al. White light emitting diodes realized by using an active packaging method with CdSe/ZnS quantum dots dispersed in photosensitive epoxy resins [J]. Nanotechnol., 2008, 19(14):145202-1-5.
Jang H S, Yang H, Kim S W, et al. White light-emitting diodes with excellent color rendering based on organically capped CdSe quantum dots and Sr3SiO5:Ce3+,Li+ phosphors [J]. Adv. Mater., 2008, 20:2696-2702.
Jang E, Jun S, Jang H, et al. White-light-emitting diodes with quantum dot color converters for display backlights [J]. Adv. Mater., 2011, 22:3076-3080.
Bae W K, Char K, Lee S. Single-step synthesis of quantum dots with chemical composition gradients [J]. Chem. Mater., 2008, 20:531-539.
Jung C J, Lee Y K. Kinetic studies on the formation of various Ⅱ-Ⅵ semiconductor nanocrystals and synthesis of gradient alloy quantum dots emitting in the entire visible range [J]. Mater. Chem., 2012, 22(10):10827-1-7.
Zhu Y, Narendran N. Investigation of romote-phosphor white light emitting diode with mutiple phosphor layers [J]. Appl. Phys., 2010, 49(10):100203-1-4.
Yutaka K, Ferry I, Hendri W, et al. Fabrication and characterization of a yellow-emitting BCNO phosphor for white light-emitting diodes [J]. Electrochem. Solid-State Lett., 2009, 12(3):J33-J38.
Narendran N, Gu Y, Freyssinier J P, et al. Solid-state lighting: Failure analysis of white LEDs [J]. Cryst. Growth, 2004, 268(3-4):449-456.
Regina M M, Gerd M, Michael R, et al. Highly efficient all-nitride phosphor-converted white light emitting diode [J]. Phys. Stat. Sol., 2005, 202(9):1727-1732.
Wang L, Rong J L, Cao J, et al. Influence of agglomeration in CdSe/ZnS quantum dot on the performances of light emitting diode [J]. Chin. J. Lumin.(发光学报), 2012, 33(12):1351-1355 (in Chinese).
Wu H, Zhang X, Guo C, et al. Three-band white light from InGaN-based blue LED chip precoated with green/red phosphors [J]. IEEE Photon. Technol. Lett., 2005, 17(6):1160-1162.
Historical Evolution and Current Status of Key Materials and Technologies in Inkjet-printed Quantum Dot Electroluminescent Displays
Research Progresses on Infrared Superluminescent Diodes
Progress on Modulation Bandwidth of Quantum-dot LED in Visible Light Communication
Synthesis and Conversion Efficiency Optimization of Quantum Dots Layer for Full-color Micro-LED Display
Design and Performance of Quantum Dot Light-emitting Diode Based on TiO2 Modified Layer
Related Author
LUO Xin
SUN Zhiguo
XU Bo
LIU Chen
WEI Changting
ZENG Haibo
YANG Jinghang
YAN Changling
Related Institution
School of Chemistry and Chemical Engineering, Anshun University
MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, Institute of Optoelectronics & Nanomaterials, School of Materials Science and Engineering, Nanjing University of Science and Technology
State Key Laboratory on High-power Semiconductor Lasers, Changchun University of Science and Technology
School of Electronic and Information Engineering, Guangdong Ocean University
Technology Development Centre, Shenzhen Research Institute of Guangdong Ocean University