Structural and Optical Properties of Ca0.88TiO3：0.12Eu3+ Red Phosphors

WU Yi-bing; SUN Zhuo; RUAN Kai-bin; LIU Yin-chun; ZHANG Hong

doi:10.3788/fgxb20143508.0932

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Structural and Optical Properties of Ca_0.88TiO₃：0.12Eu³⁺ Red Phosphors

更新时间：2020-08-12

- Structural and Optical Properties of Ca_0.88TiO₃：0.12Eu³⁺ Red Phosphors
- Chinese Journal of Luminescence Vol. 35, Issue 8, Pages: 932-938(2014)
- 作者机构：
  
  1. 福建农林大学机电工程学院,福建福州,350002
  2. 华东师范大学物理系纳光电集成与先进装备教育部工程研究中心上海,200062
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143508.0932
  CLC： O482.31
- Received：09 April 2014，
  
  Revised：24 April 2014，
  
  Published Online：30 April 2014，
  
  Published：03 August 2014
- 稿件说明：
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吴义炳, 孙卓, 阮凯斌等. Ca0.88TiO3：0.12Eu3+红色荧光粉的结构与发光性能[J]. 发光学报, 2014,35(8): 932-938

WU Yi-bing, SUN Zhuo, RUAN Kai-bin etc. Structural and Optical Properties of Ca0.88TiO3：0.12Eu3+ Red Phosphors[J]. Chinese Journal of Luminescence, 2014,35(8): 932-938
吴义炳, 孙卓, 阮凯斌等. Ca0.88TiO3：0.12Eu3+红色荧光粉的结构与发光性能[J]. 发光学报, 2014,35(8): 932-938 DOI： 10.3788/fgxb20143508.0932.

WU Yi-bing, SUN Zhuo, RUAN Kai-bin etc. Structural and Optical Properties of Ca0.88TiO3：0.12Eu3+ Red Phosphors[J]. Chinese Journal of Luminescence, 2014,35(8): 932-938 DOI： 10.3788/fgxb20143508.0932.

摘要

采用固相反应法制备Ca

0.88

TiO

：0.12Eu

（CTE）红色荧光粉，研究了CTE荧光粉的结构与发光性能。XRD结果表明，不同退火温度下的CTE荧光粉皆为钙钛矿结构，其晶粒尺寸随退火温度的升高而增大，1 300℃退火时晶相最佳，与SEM观察的结果相一致。CTE荧光粉的激发光谱由350~500 nm范围内的一系列窄带吸收峰组成，其中的最强峰位于398 nm 附近;发射谱主要包含595 nm和616 nm两个峰，属于Eu

离子跃迁发光。616 nm发射峰明显强于595 nm发射峰，说明Eu

是处在无反演对称中心的格位。CTE 荧光粉的发光随着退火温度的升高而增强，1 300℃时达到最大值，这可归因于其结晶状况的改善。另外，CTE荧光粉还具有色纯度高与热稳定性好等优点，这些将使CTE成为一种潜在的用于近紫外激发的白光LED红色荧光粉材料。

Abstract

Red phosphors of Ca

0.88

TiO

:0.12Eu

(CTE) were synthesized by solid-state method

and their structure and morphology were studied. XRD results show that CTE phosphors sintered at different temperature exhibit orthorhombic structure. The average grain size increases with the increase of sintering temperature

and their crystallization sintered at 1 300℃ is the best

which is consistent with the SEM results. CTE phosphors can be efficiently excited by near-ultraviolet light of 398 nm

and emit intensive red light with peaks around 594 nm and 616 nm corresponding to the transition

and

of Eu

. The peak around 616 nm is stronger than that of 594 nm

showing that Eu

ions site at lattice without the center of inversion symmetry. The emission intensity of CTE phosphor increases with the sintering temperature

and is the highest when the sintering temperature is 1 300℃ due to higher crystallinity. Furthermore

CTE phosphors have very good thermal stability and high color purity

implying the potential to be a promising red phosphor in white light emitting diodes.

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Keywords

references

Sunitha D V, Nagabhushana H, Sharma S C, et al. Luminescent characteristics of Eu3+ doped di-calcium silicate nano-powders for white LEDS [J]. J. Alloys Compd., 2013, 575:434-443.

Yamada S, Emoto H, Ibukiyama M, et al. Properties of SiAlON powder phosphors for white LEDs [J]. J. Eur. Ceram. Soc., 2012, 32(7):1355-1359.

Hou J S, Yin X, Fang Y Z, et al. Novel red-emitting perovskite-type phosphor CaLa1-xMgM'O6:xEu3+ (M'=Nb, Ta) for white LED application [J]. Opt. Mater., 2012, 34(8):1394-1398.

Hou J S, Yin X, Huang F Q, et al. Synthesis and photoluminescence properties of NaLaMgWO6:RE3+ (RE=Eu, Sm, Tb) phosphor for white LED application [J]. Mater. Res. Bull., 2012, 47(6):1295-1299.

Huang C F, Lu C F, Yang T Y, et al. Phosphor-free white-light light-emitting diode of weakly carrier-density-dependent spectrum with prestrained growth of InGaN/GaN quantum wells [J]. Appl. Phys. Lett., 2007, 90(15):151122-1-3.

Kim T G, Lee H S, Lin C C, et al. Effects of additional Ce3+ doping on the luminescence of Li2SrSiO4:Eu2+ yellow phosphor [J]. Appl. Phys. Lett., 2010, 96(6):061904-1-3.

Lu Z, Zhang L, Xu N C, et al. Luminescent properties of Eu3+ doped layered perovskite structure M2TiO4(M=Ca, Sr, Ba) red-emitting phosphors [J]. Spectrosc. Spect. Anal.(光谱学与光谱分析), 2012, 32(10):2632-2636 (in Chinese).

Li X P, Zhong H Y, Cheng L H, et al. Synthesis and photoluminescence of NaGdTiO4:Eu3+ red phosphors for white LEDs [J]. Chin. J. Lumin.(发光学报), 2011, 32(2):138-143 (in Chinese).

Ye S, Xiao F, Pan Y X, et al. Phosphors in phosphor-converted white light-emitting diodes: Recent advances in materials, techniques and properties [J]. Mater. Sci. Eng., 2010, 71:1-34.

Zhang J, Yin J, Liu P P, et al. Preparation and luminescent properties of MgTiO3:Eu3+ phosphor for white LEDs [J]. J. Rare Earths (稀土学报), 2012, 30(10):1009-1012 (in Chinese).

Sun W T, Gu Y X, Zhang Q H, et al. CaTiO3:Eu3+ layer coated SiO2 particles: Core-shell structured red phosphors for near-UV white LEDs [J]. J. Alloys Compd., 2010, 493:561-564.

Sun Z, Zhang Q H, Li Y G, et al. Thermal stable La2Ti2O7:Eu3+ phosphors for blue-chip white high color rendering index [J]. J. Alloys Compd., 2010, 506:338-342.

Huang Y L, Cao Y G, Jiang C F, et al. Vacuum ultraviolet and ultraviolet spectroscopy of Tb3+-and Eu3+-doped Na(Sr,Ba)PO4 phosphate [J]. Jpn. J. Appl. Phys., 2008, 47:6364-6368.

Piao X Q, Machida K I, Horikawa T, et al. Acetate reduction synthesis of Sr2Si5N8:Eu2+ phosphor and its luminescence properties [J]. J. Lumin., 2010, 130(1):8-13.

Chen R, Song F L, Chen D H, et al. Improvement of the luminescence properties of CaTiO3:Pr obtained by modified solid-state reaction [J]. Powder Technol., 2009, 194:252-257.

Noto L L, Pitale S S, Gusowki M A, et al. Afterglow enhancement with In3+ codoping in CaTiO3:Pr3+ red phosphor [J]. Powder Technol., 2013, 237:141-146.

Yang H K, Chung J W, Moon B K, et al. Synthesis and enhanced luminescence properties of Li-doped CaTiO3:Pr3+ ceramic phosphors [J]. Solid State Sci., 2011, 13:1420-1423.

Tang W J, Chen D H. Enhanced red emission in CaTiO3:Pr3+,Bi3+,B3+ phosphors [J]. Phys. Stat. Sol. (a), 2009, 206(2):229-232.

Ruan K B, Wu G H, Zhou H, et al. Optical properties of Bi3.45Eu0.55Ti3O12 ferroelectric thin films [J]. Chin. J. Lumin. (发光学报), 2012, 33(7):754-758 (in Chinese).

Fu J P, Zhang Q H, Li Y G, et al. Highly luminescent red light phosphor CaTiO3:Eu3+ under near-ultraviolet excitation [J]. J. Lumin., 2010, 130:231-235.

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