WU Xiao-xiao, LI Fu-shan, WU Wei etc. Flexible Organic Light Emitting Diodes Based on Double-layered Graphene/PEDOT:PSS Conductive Film[J]. Chinese Journal of Luminescence, 2014,35(4): 486-490
WU Xiao-xiao, LI Fu-shan, WU Wei etc. Flexible Organic Light Emitting Diodes Based on Double-layered Graphene/PEDOT:PSS Conductive Film[J]. Chinese Journal of Luminescence, 2014,35(4): 486-490 DOI: 10.3788/fgxb20143504.0486.
Flexible Organic Light Emitting Diodes Based on Double-layered Graphene/PEDOT:PSS Conductive Film
Graphene is an ideal material for the preparation of high performance conductive film because of its unique electrical properties
excellent mechanical ductility and good chemical stability. This paper presents the preparation of a double-layered graphene/poly(3
4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) conductive film
in which the PEDOT:PSS film was fabricated by using spray-coating technique. The surface morphology
optical and electrical properties of the double-layered conductive films were investigated. PEDOT:PSS can not only reduce the surface resistance of the graphene films
but also smooth the film surface. Flexible organic light-emitting diodes based on the double-layered film were fabricated
and the current efficiency increased with the voltage and reached its maximum of 0.9 cd/A when the voltage was 12 V. The device luminance did not show obvious degradation after 100 times bending with a radius of curvature of 10 mm. The hybrid films hold promise for the practical application of FOLEDs.
关键词
Keywords
references
Li J F, Marks T J. Air-stable, cross-linkable, hole-injecting/transporting interlayers for improved charge injection in organic light-emitting diodes[J]. Chem. Mater., 2008, 20(15):4873-4882. [2] Choi M C, Kim Y, Ha C S. Polymers for flexible displays: From material selection to device applications[J]. Prog. Polym. Sci., 2008, 33(6):581-630. [3] Veiont J G C, Marks T J. Toward the ideal organic light-emitting diode: The versatility and utility of interfacial tailoring by cross-linked siloxane interlayers[J]. Acc. Chem. Res., 2005, 38(8):632-643. [4] Chiang C J, Winscm C. Mechanical modeling of flexible OLED devices[J]. Org. Electron., 2009, 10(7):1268-1274. [5] Sutthana S, Hongsith N, Choopun S. AZO/Ag/AZO multilayer films prepared by DC magnetron sputtering for dye-sensitized solar cell application[J]. Curr. Appl. Phys., 2010, 10(3):813-816. [6] Han H, Theodore N D, Alford T L. Improved conductivity and mechanism of carrier transport in zinc oxide with embedded silver layer[J]. J. Appl. Phys., 2008, 103(1):013708-1-8. [7] Chen M, Pei Z L, Wang X, et al. Properties of ZnO:Al films on polyester produced by dc magnetron reactive sputtering[J]. Mater. Lett., 2001, 48(3):137-143. [8] Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696):666-669. [9] Geim A K. Graphene: Status and prospects[J]. Science, 2009, 324(5934):1530-1534. [10] Bolotin K I, Sikes K J, Jiang Z, et al. Ultrahigh electron mobility in suspended grapheme[J]. Solid State Commun., 2008, 146(9):351-355. [11] Zhang Y, Tan Y W, Stormer H L, et al. Experimental observation of the quantum Hall effect and Berry's phase in grapheme[J]. Nature, 2005, 438(7065):201-204. [12] Pang Y Y. Application of graphene in semiconductor optoelectronic devices[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2011, 26(3):296-300 (in Chinese). [13] Nasibulin A G, Ollikainen A, Anisimov A S, et al. Integration of single-walled carbon nanotubes into polymer films by thermo-compression[J]. Chem. Eng. J., 2008, 136(2):409-413. [14] Tsai Y S, Juang F S, Yang T H, et al. Effects of different buffer layers in flexible organic light-emitting diodes[J]. J. Phys. Chem. Solids., 2008, 69(2):764-768. [15] Yang C H, Tang A W, Teng F. Preparation of highly conductive polymer PEDOT:PSS by post-treatment[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2013, 28(3):323-329 (in Chinese). [16] Hong W J, Xu Y X, Lu G W, et al. Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells[J]. Electrochem. Commun., 2008, 10(10):1555-1558. [17] Kim G H, Hwang D H, Woo S I, et al. Thermoelectric properties of nanocomposite thin films prepared with poly (3, 4-ethylenedioxythiophene) poly (styrenesulfonate) and graphene[J]. Phys. Chem. Chem. Phys., 2012, 14(10):3530-3536. [18] Vlassiouk I, Regmi M, Fulvio P. Role of hydrogen in chemical vapor deposition growth of large single-crystal grapheme[J]. ACS Nano, 2011, 5(7):6069-6076. [19] Han T H, Lee Y, Choi M R, et al. Extremely efficient flexible organic light-emitting diodes with modified graphene anode[J]. Nat. Photon., 2012, 6(2):105-110. [20] Zou H. Application of Poly(3, 4-ethylenedioxythiophene) in Organic Light-emitting Diode. Beijing: Beijing Jiaotong University, 2010 (in Chinese).