Effect of Optical Basicity on Luminescence Properties of Tb3+ Doped Bi2O3-B2O3 Glasses

LIU Pan; YIN Hai-rong; GUO Hong-wei; DONG Ji-xian

doi:10.3788/fgxb20143504.0413

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Effect of Optical Basicity on Luminescence Properties of Tb³⁺ Doped Bi₂O₃-B₂O₃ Glasses

更新时间：2020-08-12

- Effect of Optical Basicity on Luminescence Properties of Tb³⁺ Doped Bi₂O₃-B₂O₃ Glasses
- Chinese Journal of Luminescence Vol. 35, Issue 4, Pages: 413-419(2014)
- 作者机构：
  
  1. 陕西科技大学材料科学与工程学院,陕西西安,710021
  2. 陕西科技大学机电工程学院,陕西西安,710021
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143504.0413
  CLC： O482.31
- Received：22 November 2013，
  
  Revised：11 December 2013，
  
  Published Online：24 January 2014，
  
  Published：03 April 2014
- 稿件说明：
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刘盼, 殷海荣, 郭宏伟等. 光学碱度对Tb3+掺杂Bi2O3-B2O3玻璃发光性能的影响[J]. 发光学报, 2014,35(4): 413-419

LIU Pan, YIN Hai-rong, GUO Hong-wei etc. Effect of Optical Basicity on Luminescence Properties of Tb3+ Doped Bi2O3-B2O3 Glasses[J]. Chinese Journal of Luminescence, 2014,35(4): 413-419
刘盼, 殷海荣, 郭宏伟等. 光学碱度对Tb3+掺杂Bi2O3-B2O3玻璃发光性能的影响[J]. 发光学报, 2014,35(4): 413-419 DOI： 10.3788/fgxb20143504.0413.

LIU Pan, YIN Hai-rong, GUO Hong-wei etc. Effect of Optical Basicity on Luminescence Properties of Tb3+ Doped Bi2O3-B2O3 Glasses[J]. Chinese Journal of Luminescence, 2014,35(4): 413-419 DOI： 10.3788/fgxb20143504.0413.

摘要

采用熔融法制备了Tb

掺杂的Bi

-B

系统玻璃，使用激发、发射及拉曼光谱分析了光学碱度与玻璃结构及发光性能的关系，同时绘制了Tb

、Bi

和Bi

的能级图。研究结果表明：Tb

掺杂的Bi

-B

玻璃由[BO

]、[BiO

]、[BO

]及[BiO

]共同组成，且随着光学碱度由0.63增加到0.93，玻璃的结构逐渐疏松。高的光学碱度使部分Bi

变为Bi

，发出571 nm（

3/2（2）

1/2

）的光，Bi

的能量降低。在光学碱度及Tb

、Bi

和Bi

离子的共同作用下，随着光学碱度的提高，玻璃的发光颜色由黄绿色变为白色。

Abstract

doped Bi

-B

glasses were prepared by melting technique

and the relationship of optical basicity

luminescence properties and structure were investigated by excitation

emission and Raman spectra. Energy level structures of Tb

and Bi

ions were plotted for the excitation and energy transfer routes. The results show that Tb

doped Bi

-B

glasses consist of [BO

]

[BiO

]

[BO

]

and [BiO

] together as basic structural groups

and its structure turn looses as the optical basicity increasing from 0.63 to 0.93. Based on energy matching condition

571 nm emission ascribed to

3/2(2)

1/2

transition of Bi

reduces from Bi

ions at high optical basicity of glasses

which decreases the transition of Bi

. The luminescent properties of Tb

doped Bi

-B

glasses are quite sensitive to optical basicity

the luminescence color turns to white from yellow-green with the optical basicity increasing.

关键词

Keywords

references

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