Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative

ZHU Yan-long; XU Mao-liang; JIANG Han-yu; LIU Ya-dong; ZHANG Yi-guang; MENG Qing-hua

doi:10.3788/fgxb20143503.0354

您当前的位置：

首页 >

文章列表页 >

Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative

更新时间：2020-08-12

- Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative
- Chinese Journal of Luminescence Vol. 35, Issue 3, Pages: 354-359(2014)
- 作者机构：
  
  1. 西安近代化学研究所, 陕西西安 710065
  2. 长春工程职业技术学院,吉林长春,130017
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143503.0354
  CLC： TN383+.1
- Received：07 November 2013，
  
  Revised：25 December 2013，
  
  Published：03 March 2014
- 稿件说明：
移动端阅览
祝艳龙, 徐茂梁, 姜菡雨等. 新型蒽衍生物蓝光材料的合成及光电性能研究[J]. 发光学报, 2014,35(3): 354-359

ZHU Yan-long, XU Mao-liang, JIANG Han-yu etc. Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative[J]. Chinese Journal of Luminescence, 2014,35(3): 354-359
祝艳龙, 徐茂梁, 姜菡雨等. 新型蒽衍生物蓝光材料的合成及光电性能研究[J]. 发光学报, 2014,35(3): 354-359 DOI： 10.3788/fgxb20143503.0354.

ZHU Yan-long, XU Mao-liang, JIANG Han-yu etc. Synthesis and Optical Properties of A Novel Blue-emitting Anthracene-based Derivative[J]. Chinese Journal of Luminescence, 2014,35(3): 354-359 DOI： 10.3788/fgxb20143503.0354.

摘要

通过引入具有电子传输性能的噁二唑衍生物支链，采用Suzuki偶联反应，设计并合成了一种新型的蒽衍生物蓝光材料，同时研究了它的光学性能、热学性能、电化学性能以及成膜性。研究结果表明，该化合物在四氢呋喃溶液中发射蓝色荧光，最大发射波长为433 nm，其荧光量子效率为0.94，是9，10-二（-萘基）蒽（ADN）的1.17倍。该化合物薄膜经过100 ℃高温烘烤3 h，依然保持连续、均一、平整的无定型结构，是制备长寿命、高效率OLED的很有潜力的材料。

Abstract

Using Suzuki coupling reaction

a novel blue-emitting anthracene-based derivatives was designed and synthesized by introducing the electron transport branch of oxadiazole derivatives. The optical properties

thermal properties

electrochemical properties

and surface morphology of the compound were characterized. The maximum emission wavelength of this compound is 433 nm in tetrahydrofuran

and the fluorescence quantum yields is 0.94 which is 1.17 times than that of 9

10-di(2-naphthyl)anthracene. The film of this compound is continuous

compact

and smooth after annealing at 100 ℃ for 3 h

which is suitable to prepare long life and high efficiency OLED devices.

关键词

Keywords

references

Tang C W, VanSlyke S A. Organic electroluminescent devices[J]. Appl. Phys. Lett., 1987, 51(12):913-915. [2] Wu M F, Yeh S J, Chen C T, et al. The quest for high-performance host materials for electrophosphorescence blue dopants[J]. Adv. Funct. Mater., 2007, 17(12):1887-1895. [3] Xiong Z Y, Li H J, Wang J X, et al. Optical characteristics of flexible microcavity organic light-emitting diodes[J]. Chin. J. Lumin.(发光学报), 2009, 30(3):337-343 (in Chinese). [4] Adachi C, Kwong R C, Djurovich P, et al. Endothermic energy transfer: A mechanism for generating very efficient high-energy phosphorescent emission in organic materials[J]. Appl. Phys. Lett., 2001, 79(13):2082-2084. [5] Wang Q, Yu J, Zhao J, et al. High-efficiency and heavily doped organic light-emitting devices based on quench-resistant red iridium complex[J]. J. Lumin., 2013, 134:870-873. [6] Zhang G, Chou H H, Jiang X, et al. Highly efficient organic light-emitting diodes (OLEDs) based on an iridium complex with rigid cyclometalated ligand[J]. Org. Electron., 2010, 11(4):632-640. [7] Fukagawa H, Shimizu T, Ohbe N, et al. Anthracene derivatives as efficient emitting hosts for blue organic light-emitting diodes utilizing triplet-triplet annihilation[J]. Org. Electron., 2012, 13(7):1197-1203. [8] Lee M T, Liao C H, Tsai C H, et al. Highly efficient deep-blue doped organic light-emitting devices[J]. Adv. Mater., 2005, 17(20):2493-2497. [9] Kim Y H, Jung H C, Kim S H, et al. High-purity-blue and high efficiency electroluminescence devices based on anthracene[J]. Adv. Funct. Mater., 2005, 15(11):1799-1805. [10] An Y, Xu M L, Wang Z J, et al. Synthesis of novel blue light emitting 9, 9'-bianthracene derivatives and their optoelectronic properties[J]. Chin. J. Lumin.(发光学报), 2011, 32(9):890-895 (in Chinese). [11] Shih H T, Lin C H, Shih H H, et al. High-performance blue electroluminescent devices based on a biaryl[J]. Adv. Mater., 2002, 14(19):1409-1412. [12] Shi J, Tang C W. Anthracene derivatives for stable blue-emitting organic electroluminescence devices[J]. Appl. Phys. Lett., 2002, 80(17):3201-3203. [13] Howell J O, Wightman R M. Ultrafast voltammetry of anthracene and 9, 10-diphenylanthracene[J]. J. Phys. Chem., 1984, 88(18):3915-3918. [14] Wee K R, Han W S, Kim J E, et al. Asymmetric anthracene-based blue host materials: synthesis and electroluminescence properties of 9-(2-naphthyl)-10-arylanthracenes[J]. J. Mater. Chem., 2011, 21:1115-1123. [15] Jiang H Y, Xu M L, Song X C, et al. Synthesis and properties of novel blue-light-emitting bianthracene-based derivatives[J]. Opt. Mater., 2012, 35:89-92. [16] Shen J. Study on The Synthesis and Properties of 1, 3, 4-Oxadiazole Derivative Electron Transport Functional Materials[D]. Hefei: Anhui University, 2006 (in Chinese). [17] Danel K, Huang T H, Lin J T, et al. Blue-emitting anthracenes with end-capping diarylamines[J]. Chem. Mater., 2002, 14(9):3860-3865. [18] Xing X, Zhang M X, Chung Y S, et al. Organic electroluminescent materials and devices[J]. Sci. Sin-Phys. Mech. Astron.(中国科学: 物理学力学天文学), 2013, 43(10):1135-1143 (in Chinese). [19] Ho M H, Chang C M, Chu T Y, et al. Iminodibenzyl-substituted distyrylarylenes as dopants for blue and white organic light-emitting devices[J]. Org. Electron., 2008, 9(1):101-110. [20] Bie G J, Cai S Y, Liu B, et al. Synthesis and spectral analysis of blue emitting material 9, 10-di(2-naphthyl)anthracene[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2007, 22(3):301-305 (in Chinese).

Views

192

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

A Y-type Delayed Fluorescence Emitter for Blue and Green OLEDs

Fabrication of Al₂O₃/PMMA Laminates and Its Barrier Performance in OLED Encapsulation

Design, Synthesis and Properties of D-π-A-π-D Type Organic Red Light Luminogens

Relationship Between π-conjugated Bridge and Photophysical Properties of Blue Light-emitting Fluorescent Materials with Twisting A-π-D-π-A Configuration

Photophysical and Excited State Properties of Blue Fluorescent Material with High Exciton Utilizing Efficiency

Related Author

SUN Jing

FAN Zhijie

DU Jikuan

DONG Hailiang

WANG Hua

Xiong-tu ZHOU

Gui-xiong CHEN

Fan SUN

Related Institution

Zheda Institute of Advanced Materials and Chemical Engineering

Key Laboratory of Interface Science and Engineering in Advanced Materials， Ministry of Education， Taiyuan University of Technology

Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

College of Physics and Information Engineering, Fuzhou University

南京邮电大学有机电子与信息显示国家重点实验室培育基地信息材料与纳米技术研究院

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰