Effect of Solvent Dilution on Preparation of PEDOT：PSS Transparent Conductive Films and Device Performance of Organic Solar Cells

HU Xue-hua; LI Fu-shan; XU Sheng; GUO Tai-liang

doi:10.3788/fgxb20143503.0322

您当前的位置：

首页 >

文章列表页 >

Effect of Solvent Dilution on Preparation of PEDOT：PSS Transparent Conductive Films and Device Performance of Organic Solar Cells

更新时间：2020-08-12

- Effect of Solvent Dilution on Preparation of PEDOT：PSS Transparent Conductive Films and Device Performance of Organic Solar Cells
- Chinese Journal of Luminescence Vol. 35, Issue 3, Pages: 322-326(2014)
- 作者机构：
  
  福州大学光电显示技术研究所, 福建福州 350002
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20143503.0322
  CLC： O631.2+3
- Received：03 November 2013，
  
  Revised：06 December 2013，
  
  Published：03 March 2014
- 稿件说明：
移动端阅览
胡雪花, 李福山, 徐胜等. 稀释溶剂对PEDOT：PSS薄膜和有机太阳能电池性能的影响[J]. 发光学报, 2014,35(3): 322-326

HU Xue-hua, LI Fu-shan, XU Sheng etc. Effect of Solvent Dilution on Preparation of PEDOT：PSS Transparent Conductive Films and Device Performance of Organic Solar Cells[J]. Chinese Journal of Luminescence, 2014,35(3): 322-326
胡雪花, 李福山, 徐胜等. 稀释溶剂对PEDOT：PSS薄膜和有机太阳能电池性能的影响[J]. 发光学报, 2014,35(3): 322-326 DOI： 10.3788/fgxb20143503.0322.

HU Xue-hua, LI Fu-shan, XU Sheng etc. Effect of Solvent Dilution on Preparation of PEDOT：PSS Transparent Conductive Films and Device Performance of Organic Solar Cells[J]. Chinese Journal of Luminescence, 2014,35(3): 322-326 DOI： 10.3788/fgxb20143503.0322.

摘要

采用喷涂技术制备聚3，4-乙撑二氧噻吩：聚苯乙烯磺酸盐（PEDOT：PSS）有机层薄膜，系统研究了乙醇、去离子水、甲醇、异丙醇和乙二醇等稀释溶剂对PEDOT：PSS薄膜形貌、透过率及导电性能的影响。将PEDOT：PSS薄膜应用于有机太阳能电池器件的制备，研究了不同溶剂对器件性能的影响。实验结果表明：采用乙醇稀释PEDOT：PSS溶液，能有效抑制PEDOT：PSS颗粒团聚，降低薄膜粗糙度，提高薄膜的透过率和导电性。以其制备的太阳能电池器件的能量转换效率明显高于其他溶剂稀释，转换效率为2.66%。

Abstract

Poly(3

4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) films were prepared by using spray coating technique. The morphology

transmittance and conductivity of the film were studied by using ethanol

deionized water

methanol and isopropanol to dilute the origin PEDOT:PSS

respectively. The solvent-diluted PEDOT:PSS films were employed to fabricated organic solar cells. The effect of solvents dilution on the solar cells performance was studied. The results indicate that the introduction of ethanol can effectively inhibit the agglomeration of PEDOT:PSS particles

reduce the film roughness

and improve the transmittance and conductivity of the PEDOT:PSS film. The organic solar cell based on the PEDOT:PSS film diluted with ethanol exhibits a power conversion efficiency of 2.66%

which is higher than those with other diluting solvents.

关键词

Keywords

references

Li J, Kim S, Edington S, et al. A study of stabilization of P3HT/PCBM organic solar cells by photochemical active TiOx layer[J]. Sol. Energy Mater. Sol. Cells, 2011, 95(4):1123-1130. [2] Shaheen S E, Brabec C J, Sariciftci N S, et al. 2.5% efficient organic plastic solar cells[J]. Appl. Phys. Lett., 2001, 78(6):841-843. [3] Jeon S O, Lee J Y. Improved high temperature stability of organic solar cells using a phosphine oxide type cathode modification layer[J]. Sol. Energy Mater. Sol. Cells, 2011, 95(4):1102-1106. [4] Sun K, Xia Y, Ouyang J. Improvement in the photovoltaic efficiency of polymer solar cells by treating the poly (3, 4-ethylenedioxythiophene):Poly (styrenesulfonate) buffer layer with co-solvents of hydrophilic organic solvents and hydrophobic 1, 2-dichlorobenzene[J]. Sol. Energy Mater. Sol. Cells, 2012, 97(1):89-96. [5] Sefanc M A, Okyay A K, Demir H V. Plasmonic backcontact grating for P3HT/PCBM organic solar cells enabling strong optical absorption increased in all polarizations[J]. Opt. Exp., 2011, 19(15):14200-14209. [6] Wang L J, Zhang W, Qin H T, et al. Influence of solution-processed conditions on polymer bulk heterojunction solar cell performance[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2013, 28(4):521-526 (in Chinese). [7] Vak D, Kim S S, Jo J, et al. Fabrication of organic bulk heterojunction solar cells by a spray deposition method for low-cost power generation[J]. Appl. Phys. Lett., 2007, 91(8):081102-1-3. [8] Zhou Y, Cheun H, Choi S, et al. Optimization of a polymer top electrode for inverted semitransparent organic solar cells[J]. Org. Electron., 2011, 12(5):827-831. [9] Weickert J, Sun H, Palumbiny C, et al. Spray-deposited PEDOT:PSS for inverted organic solar cells[J]. Sol. Energy Mater. Sol. Cells, 2010, 94(12):2371-2374. [10] Kopola P, Zimmermann B, Filipovic A, et al. Aerosol jet printed grid for ITO-free inverted organic solar cells[J]. Sol. Energy Mater. Sol. Cells, 2012, 107:252-258. [11] Kim K J, Kim Y S, Kang W S, et al. Inspection of substrate-heated modified PEDOT:PSS morphology for all spray deposited organic photovoltaics[J]. Sol. Energy Mater. Sol. Cells, 2010, 94(7):1303-1306. [12] Kim Y, Lee J, Kang H, et al. Controlled electro-spray deposition of highly conductive PEDOT:PSS films[J]. Sol. Energy Mater. Sol. Cells, 2012, 98:39-45. [13] Hoth C N, Steim R, Schilinsky P, et al. Topographical and morphological aspects of spray coated organic photovoltaics[J]. Org. Electron., 2009, 10(4):587-593. [14] Kim Y, Kim G, Lee J, et al. Morphology controlled bulk-heterojunction layers of fully electro-spray coated organic solar cells[J]. Sol. Energy Mater. Sol. Cells, 2012, 105:272-279. [15] Steirer K X, Berry J J, Reese M O, et al. Ultrasonically sprayed and inkjet printed thin film electrodes for organic solar cells[J]. Thin Solid Films, 2009, 517(8):2781-2786. [16] Girotto C, Moia D, Rand B P, et al. High-performance organic solar cells with spray-coated hole-transport and active layers[J]. Adv. Funct. Mater., 2011, 21(1):64-72. [17] Zhang F L, Gadisa A, Inganas O, et al. Influence of buffer layers on the performance of polymer solar cells[J]. Acta Phys.Sinica (物理学报), 2004, 84(19):3906-3908 (in Chinese). [18] Xia Y, Zhang H, Ouyang J. Highly conductive PEDOT:PSS films prepared through a treatment with zwitterions and their application in polymer photovoltaic cells[J]. J. Mater. Chem., 2010, 20(43):9740-9747. [19] Peng B, Guo X, Cui C, et al. Performance improvement of polymer solar cells by using a solvent-treated poly (3, 4-ethylenedioxythiophene):poly (styrenesulfonate) buffer layer[J]. Appl. Phys. Lett., 2011, 98(24):243308-1-3. [20] Crispin X, Marciniak S, Osikowicz W, et al. Conductivity, morphology, interfacial chemistry, and stability of poly (3, 4-ethylene dioxythiophene)-poly (styrene sulfonate): A photoelectron spectroscopy study[J]. J. Polym. Sci. Part B:Polym. Phys., 2003, 41(21):2561-2583. [21] Wang H T, Zhang W F, Chen B X, et al. Enhancing power conversion efficiency of polymer solar cells via treatment of PEDOT:PSS anode buffer layer using DMF solvent[J]. J. Univ. Sci. Technol. Chin.(中国科学技术大学学报), 2012, 42(10):775-784 (in Chinese). [22] Yang C H, Tang A W, Teng F, et al. Preparation of highly conductive polymer PEDOT:PSS by post-treatment[J]. Chin. J. Liq. Cryst. Disp.(液晶与显示), 2013, 28(3):323-329 (in Chinese).

Views

257

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Surface Plasmon Resonance-enhanced Organic Solar Cells Based on Au Nanorods@SiO₂ Core-shell Structures

Flexible Organic Light Emitting Diodes Based on Double-layered Graphene/PEDOT：PSS Conductive Film

Effect of Substrate Temperature on Preparation of Large Area Organic Solar Cell Array by Spraying

Preparation and Characteristics of Organic Solar Cells Based on Novel Transparent Conducting Oxides

Analysis of Optical Performance for Organic Solar Cell on Si Substrate

Related Author

CHEN Shu-fen

XIONG Jian-qiao

YUAN Xin-fang

ZHANG Ran

LI Xue

GUO Tai-liang

WU Wei

LI Fu-shan

Related Institution

南京工程学院机械工程学院

南京邮电大学信息材料与纳米技术研究院

Institute of Optoelectronic Display, College of Physics and Information Engineering, Fuzhou University

Institute of Optoelectronic Display Technology, Physics and Information Engineering, Fuzhou University

College of Physics, Changchun Normal University, Changchun 130022, China

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰