Synthesis and Upconversion Luminescence of NaLuF4：Yb3+, Er3+ Microcrystals

YAO Xiu-wei; WANG Guo-feng; LI Ying; ZHANG Ji-sen

doi:10.3788/fgxb20133410.1319

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Synthesis and Upconversion Luminescence of NaLuF₄：Yb³⁺, Er³⁺ Microcrystals

更新时间：2020-08-12

- Synthesis and Upconversion Luminescence of NaLuF₄：Yb³⁺, Er³⁺ Microcrystals
- Chinese Journal of Luminescence Vol. 34, Issue 10, Pages: 1319-1323(2013)
- 作者机构：
  
  1. 中国科学院长春光学精密机械与物理研究所,吉林长春,中国,130033
  2. 黑龙江大学功能无机材料化学教育部重点实验室化学化工与材料学院,黑龙江哈尔滨,150080
  3. 哈尔滨师范大学光电带隙材料省部共建教育部重点实验室物理与电子工程学院, 黑龙江哈尔滨 150025
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20133410.1319
  CLC： O482.31
- Received：20 May 2013，
  
  Revised：09 August 2013，
  
  Published：10 October 2013
- 稿件说明：
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姚秀伟, 王国凤, 李莹, 张继森. NaLuF4：Yb3+, Er3+微米晶的制备及上转换发光[J]. 发光学报, 2013,34(10): 1319-1323

YAO Xiu-wei, WANG Guo-feng, LI Ying, ZHANG Ji-sen. Synthesis and Upconversion Luminescence of NaLuF4：Yb3+, Er3+ Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(10): 1319-1323
姚秀伟, 王国凤, 李莹, 张继森. NaLuF4：Yb3+, Er3+微米晶的制备及上转换发光[J]. 发光学报, 2013,34(10): 1319-1323 DOI： 10.3788/fgxb20133410.1319.

YAO Xiu-wei, WANG Guo-feng, LI Ying, ZHANG Ji-sen. Synthesis and Upconversion Luminescence of NaLuF4：Yb3+, Er3+ Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(10): 1319-1323 DOI： 10.3788/fgxb20133410.1319.

摘要

采用EDTA辅助法合成了NaLuF

:Yb

微米晶

用X射线粉末衍射(XRD)对样品的结构进行了表征。XRD分析表明样品NaLuF

为六角相。研究了初始反应溶液的pH值对NaLuF

:Yb

微米晶的组分、形貌和荧光性质的影响。在980 nm光激发下

观察到了

11/2

15/2

、

9/2

15/2

、

11/2

15/2

、

3/2

15/2

和

9/2

15/2

发射

荧光强度比

(

11/2

3/2

15/2

(

9/2

15/2

)和

(

11/2

9/2

15/2

(

11/2

3/2

15/2

)随着pH值的变化而变化。研究了样品的上转换发光机制。

Abstract

Hexagonal phase NaLuF

:Yb

microcrystals were synthesized by a EDTA-assisted hydrothermal method. The effects of pH value of the reaction solutions on the phase compositions

morphologies

and luminescence properties of NaLuF

:Yb

microcrystals were investigated in detail. Under 980 nm excitation

the

11/2

15/2

9/2

15/2

11/2

15/2

3/2

15/2

and

9/2

15/2

emissions were observed. The relative intensity of

11/2

9/2

15/2

11/2

3/2

15/2

as well as

11/2

3/2

15/2

9/2

15/2

changed with increasing pH values. The upconversion luminescence mechanism of NaLuF

:Yb

was investigated in detail.

关键词

Keywords

references

Wang G, Peng Q, Li Y. Luminescence tuning of upconversion nanocrystals [J]. Chem. Eur. J., 2006, 16(16):4923-4931.[2] Ehlert O, Thomann R, Darbandi M, et al. A four-color colloidal multiplexing nanoparticle system [J]. ACS Nano, 2008, 2(1):120-124.[3] Wang M, Huang Q, Zhang H, et al. Formation of YF3 nanocrystals and their self-assembly into hollow peanut-like structures [J]. Cryst. Growth Des., 2007, 7(10):2106-2111.[4] Li S, Zhang X, Hou Z, et al. Enhanced emission of ultra-small-sized LaF3:RE3+ (RE=Eu, Tb) nanoparticles through 1,2,4,5-benzenetetracarboxylic acid sensitization [J]. Nanoscale, 2012, 4(18):5619-5626.[5] Li H, Yang K S, Qi N, et al. Preparation and luminescence properties of Yb3+,Er3+-codoped oxyfluoride glass ceramics [J]. Chin. Opt.(中国光学), 2011, 4(6):672-677 (in Chinese)[6] Wang F, Liu X. Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals [J]. Chem. Soc. Rev., 2009, 38(4):976-984.[7] Wang G, Li Y, Jiang B, et al. In situ synthesis and photoluminescence of Eu3+ doped Y(OH)3@-NaYF4 core-shell nanotubes [J]. Chem. Commun., 2011, 47(28):8019-8021.[8] Yan R, Li Y. Down/up conversion in Ln3+-doped YF3 nanocrystals [J]. Adv. Funct. Mater., 2005, 15(5):763-770.[9] Zhang M, Fan H, Xi B, et al. Synthesis, characterization, and luminescence properties of uniform Ln3+-doped YF3 nanospindles [J]. J. Phys, Chem. C, 2007, 111(1):6652-6657.[10] Lenyre J, Ritcey A. Synthesis of lanthanide fluoride nanoparticles of varying shape and size [J]. Chem. Mater., 2005, 17(11):3040-3043.[11] Wang G, Qin W, Zhang J, et al. Synthesis, growth mechanism, and tunable upconversion luminescence of Yb3+/Tm3+-codoped YF3 nanobundles [J]. J. Phys. Chem. C, 2008, 112(32):12161-12167.[12] Pan G, Song H, Bai X, et al. Highly luminescent YVO4-Eu3+ nanocrystals coating on wirelike Y(OH)3-Eu3+ and Y2O3-Eu3+ microcrystals by chemical corrosion [J]. J. Phys. Chem. C, 2007, 111(33):12472-12477.[13] Chen D, Wang Y, Yu Y, et al. Intense ultraviolet upconversion luminescence from Tm3+/Yb3+:-YF3 nanocrystals embedded glass ceramic [J]. Appl. Phys. Lett., 2007, 91(5):051920-1-3.[14] Qin G, Qin W, Huang S, et al. Infrared-to-violet upconversion from Yb3+ and Er3+ codoped amorphous fluoride film prepared by pulsed laser deposition [J]. J. Appl. Phys., 2002, 92(11):6936-6938.[15] Dong B, Liu D, Wang X, et al. Optical thermometry through infrared excited green upconversion emissions in Er3+-Yb3+ codoped Al2O3 [J]. Appl. Phys. Lett., 2007, 90(18):181117-1-3.[16] Wang Y, Ohwaki J. New transparent vitroceramics codoped with Er3+ and Yb3+ for efficient frequency upconversion [J]. Appl. Phys. Lett., 1993, 63(24):3268-3270.[17] Lehmann O, Kmpe K, Haase M. Synthesis of Eu3+-doped core and core/shell nanoparticles and direct spectroscopic identification of dopant sites at the surface and in the interior of the particles [J]. J. Am. Chem. Soc., 2004, 126(45):14935-14942.[18] Wang G, Peng Q, Li Y. Upconversion luminescence of monodisperse CaF2:Yb3+,Er3+ nanocrystals [J]. J. Am. Chem. Soc., 2009, 131(40):14200-14201.[19] Bai X, Song H, Pan G, et al. Size-dependent upconversion luminescence in Er3+/Yb3+-codoped nanocrystalline yttria:Saturation and thermal effects [J]. J. Phys. Chem. C, 2007, 111(36):13611-13617.[20] Bhargava R, Gallaghar D, Hong X, et al. Optical properties of manganese doped nanocrystals of ZnS [J]. Phys. Rev. Lett., 1994, 72(3):416-419.[21] Krmer K, Biner D, Frei G, et al. Hexagonal sodium yttrium fluori de based green and blue emitting upconversi on phosphors [J]. Chem. Mater., 2004, 16(7):1244-1251.[22] Wang L, Li Y. Na(Y1.5Na0.5)F6 single-crystal nanorods as multicolor luminescent materials [J]. Nano Lett., 2006, 6(8):1645-1649.[23] Shi F, Wang J, Zhai X, et al. Facile synthesis of -NaLuF4:Yb/Tm hexagonal nanoplates with intense ultraviolet upconversion luminescence [J]. Cryst. Eng. Comm., 2011, 13:3782-3787.[24] Pollnau M, Gamelin D, Ldel S. Power dependence of upconversion luminescence in lanthanide and transition-meta-lion systems [J]. Phys. Rev. B, 2000, 61(5):3337-3346.[25] Wang G, Qin W, Wang L, et al. Intense ultraviolet upconversion luminescence from hexagonal NaYF4:Yb3+/Tm3+ microcrystals [J]. Opt. Exp., 2008, 16(16):11907-11914.[26] Wang G, Qin W, Zhang J, et al. Enhancement of violet and ultraviolet upconversion emissions in Yb3+,Er3+-codoped YF3 nanocrystals [J]. Opt. Mater., 2008, 31(2):296-299.

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