Synthesis and Properties of A New 4-Aminoantipyrine Schiff-base for Selective Recognition of Cu2+

HUANG Qiang; ZHU Wei-ju; YANG Lian-lian; LI Cun; NING Dian-hua; YU Yang

doi:10.3788/fgxb20133409.1144

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Synthesis and Properties of A New 4-Aminoantipyrine Schiff-base for Selective Recognition of Cu²⁺

更新时间：2020-08-12

- Synthesis and Properties of A New 4-Aminoantipyrine Schiff-base for Selective Recognition of Cu²⁺
- Chinese Journal of Luminescence Vol. 34, Issue 9, Pages: 1144-1148(2013)
- 作者机构：
  
  安徽大学化学化工学院绿色高分子材料安徽省重点实验室,安徽合肥,230601
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20133409.1144
  CLC： O625
- Received：09 May 2013，
  
  Revised：11 July 2013，
  
  Published：10 September 2013
- 稿件说明：
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黄强, 朱维菊, 杨莲莲, 李村, 宁殿华, 余洋. 新型4-氨基安替比林席夫碱的合成及对Cu2+的选择性识别[J]. 发光学报, 2013,34(9): 1144-1148

HUANG Qiang, ZHU Wei-ju, YANG Lian-lian, LI Cun, NING Dian-hua, YU Yang. Synthesis and Properties of A New 4-Aminoantipyrine Schiff-base for Selective Recognition of Cu2+[J]. Chinese Journal of Luminescence, 2013,34(9): 1144-1148
黄强, 朱维菊, 杨莲莲, 李村, 宁殿华, 余洋. 新型4-氨基安替比林席夫碱的合成及对Cu2+的选择性识别[J]. 发光学报, 2013,34(9): 1144-1148 DOI： 10.3788/fgxb20133409.1144.

HUANG Qiang, ZHU Wei-ju, YANG Lian-lian, LI Cun, NING Dian-hua, YU Yang. Synthesis and Properties of A New 4-Aminoantipyrine Schiff-base for Selective Recognition of Cu2+[J]. Chinese Journal of Luminescence, 2013,34(9): 1144-1148 DOI： 10.3788/fgxb20133409.1144.

摘要

设计合成了一种新型安替比林-席夫碱衍生物M(4-氨基安替比林缩5-硝基水杨醛席夫碱)

用IR、

H NMR及元素分析对其结构进行了表征。通过紫外光谱和荧光光谱研究了M对Cu

的选择性识别作用。结果表明:M 与Cu

能够以1:1的化学计量比形成配合物

结合常数为6.5 10

Lmol

-1

;M和Cu

的结合导致M在 496 nm 处的荧光猝灭

紫外可见吸收光谱红移

且M 对Cu

有较高的选择性

受常见离子的干扰较小。

Abstract

A new 4-aminoantipyrine-based Schiff-base (M) was synthesized. Its structure was characterized by using IR

H NMR and elemental analysis. The influences of a number of different metal ions on its UV-Vis absorption and fluorescence spectral were studied in acetonitrile. Spectroscopic studies revealed that compound M could detect Cu

by UV-Vis absorption and fluorescence spectrophotometry. The stoichiometry ratio of M-Cu

was 1:1

respectively. Moreover

the detection limit was calculated to be 1.41 mol/L for Cu

ion. The analysis suggested that M could beh ave as a fluorescent sensor for the selective detection of Cu

and the binding constant was 6.510

L/mol. Thus a new kind of chemosensor for Cu

with high sensitivity and selectivity was introduced.

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Keywords

references

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