Effect of Different Glasses on Solubility and Luminescent Properties of &beta;-NaYF4:Yb3+,Er3+/Tm3+ Microcrystals

DING Ming-ye; LU Chun-hua; CAO Lin-hai; HUANG Wen-juan; JIANG Chen-fei; NI Ya-ru; XU Zhong

doi:10.3788/fgxb20133403.0282

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Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF₄:Yb³⁺,Er³⁺/Tm³⁺ Microcrystals

更新时间：2020-08-12

- Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF₄:Yb³⁺,Er³⁺/Tm³⁺ Microcrystals
- Chinese Journal of Luminescence Vol. 34, Issue 3, Pages: 282-291(2013)
- 作者机构：
  
  材料化学工程国家重点实验室南京工业大学材料科学与工程学院,江苏南京,210009
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20133403.0282
  CLC： O482.31
- Received：12 November 2012，
  
  Revised：09 January 2013，
  
  Published：10 March 2013
- 稿件说明：
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丁明烨, 陆春华, 操林海, 黄文娟, 蒋晨飞, 倪亚茹, 许仲梓. 不同玻璃组分对β-NaYF4:Yb3+,Er3+/Tm3+粉体的侵蚀性研究及对发光性能的影响[J]. 发光学报, 2013,34(3): 282-291

DING Ming-ye, LU Chun-hua, CAO Lin-hai, HUANG Wen-juan, JIANG Chen-fei, NI Ya-ru, XU Zhong-zi. Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF4:Yb3+,Er3+/Tm3+ Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(3): 282-291
丁明烨, 陆春华, 操林海, 黄文娟, 蒋晨飞, 倪亚茹, 许仲梓. 不同玻璃组分对β-NaYF4:Yb3+,Er3+/Tm3+粉体的侵蚀性研究及对发光性能的影响[J]. 发光学报, 2013,34(3): 282-291 DOI： 10.3788/fgxb20133403.0282.

DING Ming-ye, LU Chun-hua, CAO Lin-hai, HUANG Wen-juan, JIANG Chen-fei, NI Ya-ru, XU Zhong-zi. Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF4:Yb3+,Er3+/Tm3+ Microcrystals[J]. Chinese Journal of Luminescence, 2013,34(3): 282-291 DOI： 10.3788/fgxb20133403.0282.

摘要

选用硅酸盐、硼酸盐以及磷酸盐3种常用的玻璃体系

与-NaYF

:Yb

/Tm

粉体均匀混合压片后在不同的温度(400～700 ℃)下进行热处理。采用X射线衍射技术和荧光光谱技术等测试手段研究不同玻璃形成体以及碱金属离子对-NaYF

:Yb

/Tm

粉体的侵蚀情况以及对发光性能的影响。研究结果表明

在硼酸盐玻璃体系与-NaYF

:Yb

/Tm

粉体复合热处理过程中

和K

离子会取代-NaYF

晶体中Na原子的位置。在相同热处理温度下

不同玻璃体系与-NaYF

晶体反应剧烈程度:磷酸盐

硼酸盐

硅酸盐。

Abstract

The composites of -NaYF

:Yb

/Tm

incorporated in silicate glasses

borate glasses and phosphate glasses were formed into pellets under pressure and annealed under different temperature (400～700 ℃). The effect of different glasses formers and alkali metal ions on solubility and luminescent properties of -NaYF

:Yb

/Tm

microcrystals were characterized by X-ray diffraction (XRD)

photoluminescence (PL) spectra. The results show that Li

ions and K

ions can replace Na

ions in -NaYF

microcrystals at low heat treatment temperature. The solubility of -NaYF

:Yb

/Tm

microcrystals in different glasses systems is investigated as follows: phosphate glasses

borate glasses

silicate glasses.

关键词

Keywords

references

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Related Institution

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School of Chemistry and Life Sciences, Changchun University of Technology

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State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

Department of Materials Science and Engineering, Luoyang Institute of Science and Technology

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⁰

Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF4:Yb3+,Er3+/Tm3+ Microcrystals

DOI：10.3788/fgxb20133403.0282

摘要

Abstract

关键词

Keywords

references

Effect of Different Glasses on Solubility and Luminescent Properties of β-NaYF₄:Yb³⁺,Er³⁺/Tm³⁺ Microcrystals