Spectroscopic Properties of Two Kinds of Zn Porphyrin-functionalized Polymer and Their Coordination Products with Terbuthylazine

YU Long; WANG Rui-xin; GAO Bao-jiao; GENG Tian-qi; CHEN Mei-jun; LEI Cai-ping; LIU Shao-we

doi:10.3788/fgxb20123312.1373

您当前的位置：

首页 >

文章列表页 >

Spectroscopic Properties of Two Kinds of Zn Porphyrin-functionalized Polymer and Their Coordination Products with Terbuthylazine

更新时间：2020-08-12

- Spectroscopic Properties of Two Kinds of Zn Porphyrin-functionalized Polymer and Their Coordination Products with Terbuthylazine
- Chinese Journal of Luminescence Vol. 33, Issue 12, Pages: 1373-1380(2012)
- 作者机构：
  
  1. 中北大学化学工程系,山西太原,030051
  2. 甘肃银光化学工业集团有限公司,甘肃白银,730900
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123312.1373
  CLC： O482.3
- Received：15 September 2012，
  
  Revised：14 October 2012，
  
  Published：10 December 2012
- 稿件说明：
移动端阅览
喻龙, 王蕊欣, 高保娇, 耿天奇, 陈玫君, 雷彩萍, 刘少伟, 黄小利, 雷鸣. 两种高分子化锌卟啉络合物与特丁津相互作用的光谱性能研究[J]. 发光学报, 2012,33(12): 1373-1380

YU Long, WANG Rui-xin, GAO Bao-jiao, GENG Tian-qi, CHEN Mei-jun, LEI Cai-ping, LIU Shao-wei, HUANG Xiao-li, LEI Ming. Spectroscopic Properties of Two Kinds of Zn Porphyrin-functionalized Polymer and Their Coordination Products with Terbuthylazine[J]. Chinese Journal of Luminescence, 2012,33(12): 1373-1380
喻龙, 王蕊欣, 高保娇, 耿天奇, 陈玫君, 雷彩萍, 刘少伟, 黄小利, 雷鸣. 两种高分子化锌卟啉络合物与特丁津相互作用的光谱性能研究[J]. 发光学报, 2012,33(12): 1373-1380 DOI： 10.3788/fgxb20123312.1373.

YU Long, WANG Rui-xin, GAO Bao-jiao, GENG Tian-qi, CHEN Mei-jun, LEI Cai-ping, LIU Shao-wei, HUANG Xiao-li, LEI Ming. Spectroscopic Properties of Two Kinds of Zn Porphyrin-functionalized Polymer and Their Coordination Products with Terbuthylazine[J]. Chinese Journal of Luminescence, 2012,33(12): 1373-1380 DOI： 10.3788/fgxb20123312.1373.

摘要

将苯基卟啉(PP)功能化的聚甲基丙烯酸缩水甘油酯(PGMA)即PP-PGMA和羟基苯基卟啉(HPP) 功能化的PGMA(HPP-PGMA)分别与锌离子发生络合反应

制得高分子化的苯基锌卟啉ZnPP-PGMA或羟苯基锌卟啉ZnHPP-PGMA。采用

H-NMR对ZnPP-PGMA和ZnHPP-PGMA的化学结构进行了表征

用紫外-可见光谱法、荧光光谱法研究了其光谱性能。将ZnPP-PGMA或ZnHPP-PGMA与特丁津作用

研究特丁津对其光谱性能的影响。研究结果表明:高分子化的金属卟啉ZnPP-PGMA和ZnHPP-PGMA都具有强的光谱性能

相对于PP-PGMA和HPP-PGMA

其电子吸收光谱Soret吸收带红移

荧光发射峰蓝移。ZnPP-PGMA和ZnHPP-PGMA分别与特丁津作用后

ZnPP-PGMA的紫外光谱发生一定程度的红移

且ZnPP-PGMA和ZnHPP-PGMA发生明显的荧光猝灭现象。随着特丁津浓度的增大

ZnHPP-PGMA发生荧光猝灭的程度增大。

Abstract

The benzylporphyrin (PP)-functionalized polyglyceryl methacrylate (PGMA) and the hydroxylbenzylporphyrin (HPP)-functionalized PGMA

i.e.

PP-PGMA and HPP-PGMA

were coordinated with Zn

ion respectively

resulting in the Zn porphyrin-functionalized PGMA

i.e.

ZnPP-PGMA and ZnHPP-PGMA. The chemical structures of ZnPP-PGMA and ZnHPP-PGMA were characterized by nuclear magnetic resonance (

H-NMR) spectroscopy. The spectroscopic properties of ZnPP-PGMA and ZnHPP-PGMA were studied by means of UV-Vis spectroscopy and fluorescence spectroscopy. The axial coordination reaction between two kinds of Zn porphyrin-functionalized PGMA and terbuthylazines was studied by using the fluorescence spectrum titration method. The affective factors for fluorescence character of axial coordination reaction were investigated. The results show that both ZnPP-PGMA and ZnHPP-PGMA have possessed strong spectral characteristics. Comparing with PP-PGMA and HPP-PGMA

the Soret absorption bands of ZnPP-PGMA and ZnHPP-PGMA exhibited obvious red shift

and the blue shift occurred for Q emission bands of them. In addition

both the Soret and Q absorption bands of ZnPP-PGMA exhibited red shift in the electronic absorption spectra. The fluorescence quenching occurred in the product of terbuthylazine. The fluorescence quenching for ZnHPP-PGMA was a little less than ZnPP-PGMA. It is because the hydrogen bonding between ZnHPP-PGMA and terbuthylazine led to the weaker axial coordination. Moreover

the fluorescence quenching of ZnHPP-PGMA was strengthed with the increasing concentration of terbuthylazine.

关键词

Keywords

references

Liu Q, Zhang X, Shi S K, et al. Intercalation assembly and optical properties of metalloporphyrin into an inorganic lamellar framework [J]. Chin. J. Lumin.(发光学报), 2011, 32(6):617-621 (in Chinese).

Lu X Q, Quan Y L, Xue Z H, et al. Determination of explosives based on novel type of sensor using porphyrin functionalized carbon nanotubes [J]. Colloids Surf., B, 2011, 88(1):396-401.

Lvova L, Mastroianni M, Pomarico G, et al. Carbon nanotubes modified with porphyrin units for gaseous phase chemical sensing [J]. Sens. Actuators B, 2012, 170:163-171.

Li B, Zuo Q H. Preparation and oxygen-sensing properties of ruthenium(Ⅱ) complex as optical oxygen-sensing material [J]. Chin. J. Lumin.(发光学报), 2011, 32(3):211-215 (in Chinese).

Kim J, Lim S H, Yoon Y, et al. A fluorescent ammonia sensor based on a porphyrin cobalt(Ⅱ)-dansyl complex [J]. Tetrahedron Lett., 2011, 52(21):2645-2648.

Bozkurt S S, Ayata S, Kaynak I. Fluorescence-based sensor for Pb(Ⅱ) using tetra-(3-bromo-4-hydroxyphenyl) porphyrin in liquid and immobilized medium [J]. Spectrochim. Acta, Part A, 2009, 72(4):880-883.

Manisankar M, Brook R D, Ronald P S. Photophysics of soret-excited tetrapyrroles in solution. Ⅳ. Radiationless decay and triplet-triplet annihilation investigated using tetraphenylporphinato Sn(Ⅳ) [J]. J. Phys. Chem. A, 2009, 113(42):11318-11326.

Wang S J, Peng Y L, Zhou X W. Synthesis of porphyrin modified with nicotinic acid and studies on the fluorescence properties of axial coordination reaction [J]. Chin. J. Inorg. Chem.(无机化学学报), 2010, 26(5):793-800 (in Chinese).

Fang Z H, Zhou J L, Wan Q Z, et al. Tetra(p-amino-phenyl) porphyrin based optical fiber chemical sensor for measurement of pH with wide range [J]. Chem. Sensors (化学传感器), 2008, 28(1):49-53 (in Chinese).

Muthukumar P, Abraham J S. Highly sensitive detection of HCl gas using a thin film of meso-tetra(4-pyridyl)porphyrin coated glass slide by optochemical method [J]. Sens. Actuators B, 2011, 159(1):238-244.

Borisov S M, Lehner P, Klimant I. Novel optical trace oxygen sensors based on platinum(Ⅱ) and palladium(Ⅱ) complexes with 5,10,15,20-meso-tetrakis-(2,3,4,5,6-pentafluorphenyl)- porphyrin covalently immobilized on silica-gel particles [J]. Anal. Chim. Acta, 2011, 690(1):108-115.

Zhou X F, Su F Y, Tian Y Q, et al. Platinum (Ⅱ) porphyrin-containing thermoresponsive poly(N- isopropylacrylamide) copolymer as fluorescence dual oxygen and temperature sensor [J]. Sens. Actuators B, 2011, 159(1):135-141.

Zhang Y, Wang R X, Gao B J, et al. Preparation and spectroscopic properties of l ine-type poly(glyceryl methacrylate) bondingmanganoporphyrin on side chain [J]. Chem. J. Chin. Univ.(高等学校化学学报), 2008, 29(3):634-639 (in Chinese).

Wang F Y, Gao B J, Wang R X. Realization of synchronistically synthesizing and bonding of porphyrin on side chain of copolymer P(GMA-co-MMA) [J]. Acta Phys. Chim. Sinica (物理化学学报), 2009, 25(2):341-346 (in Chinese).

Zhang P Y, Zhang J B, Yu X C, et al. Synthesis, characterization and photochemical characteristic of magnesium tetraphenyl porphyrin [J]. Acta Phys. Chim. Sinica (物理化学学报), 2008, 24(1):143-146 (in Chinese).

Guo X N, Shi Y H, Zhang Y H, et al. Synthesis of p-hydroxylphenylporphyrin arrays and their fluorescence spectrum study [J]. Chin. J. Org. Chem.(有机化学), 2006, 26(2):247-251 (in Chinese).

Wang L Z, Yu Y B. Spectroscopic analysis of substituted tetraphenylporphyrin iron, manganese, cobalt, copper and zinc complexes [J]. Spectrosc. Spectral. Anal.(光谱学与光谱分析), 2008, 28(10):2312-2317 (in Chinese).

Peng Y L, Wang S J. Study on the spectroscopic properties of coordination reaction between Zn porphyrin and imidazoles derivatives [J]. Chem. Res. Appl.(化学研究与应用), 2012, 24(2):181-186 (in Chinese).

Gentemann S, Medforth C J, Forsyth T P, et al. Photophysical properties of conformationally distorted metal-free porphyrins. Investigation into the deactivation mechanisms of the lowest excited singlet state [J]. J. Am. Chem. Soc., 1994, 116:7363-7368.

Chi Y X, Niu S Y, Jin J. Crystal structures and luminescence property of d10 transition metal complexes [J]. Spectrosc. Spectral. Anal.(光谱学与光谱分析), 2008, 28(10):2258-2262 (in Chinese).

Views

146

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Detection of Hydrogen Peroxide and Cholest-erol Based on Zinc Doped Quantum Dots and Fenton-like Reaction Fluorescent Probe Preparation

Research Progress of Optical Fiber Sensors Based on Fluorescence Quenching Effect

Synthesis and Upconversion Luminescence Properties of White Phosphor CaF₂: Yb³⁺/Eu³⁺/La³⁺

β-cyclodextrin Functionalized Mn-ZnS Quantum Dots as Sensors for Determination of Acetaminophen in The Blood

Preparation of Carbon Quantum Dots from Cigarette Filters for Detection of Dopamine

Related Author

Xue-hua SUN

Yu QIANG

Du-ting HAO

Rui TIAN

Jing CHEN

Zhao YANG

Yu-hao HUANG

Ming-hui ZHOU

Related Institution

Yan'an Key Laboratory of Green Synthetic Materials and Chemical Safety Testing, College of Chemistry and Chemical Engineering, Yan'an University

School of Optics and Electronic Information, Huazhong University of Science and Technology

State Key Laboratory on Integrated Optoelectronics, Jilin University

School of Chemistry and Chemical Engineering, Yangtze Normal University

School of Environment and Civil Engineering, Dongguan University of Technology

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰