Hydrothermal Synthesis and Characterization of Mercaptopropionic Acid Modified Water-soluble CdTe Quantum Dots

您当前的位置：

首页 >

文章列表页 >

Hydrothermal Synthesis and Characterization of Mercaptopropionic Acid Modified Water-soluble CdTe Quantum Dots

更新时间：2020-08-12

- Hydrothermal Synthesis and Characterization of Mercaptopropionic Acid Modified Water-soluble CdTe Quantum Dots
- Chinese Journal of Luminescence Vol. 33, Issue 12, Pages: 1309-1314(2012)
- 作者机构：
  
  中国科学院安徽光学精密机械研究所环境光学与技术重点实验室,安徽合肥,230031
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123312.1309
  CLC： O613.5
- Received：25 August 2012，
  
  Revised：13 October 2012，
  
  Published：10 December 2012
- 稿件说明：
移动端阅览
甘婷婷, 张玉钧, 肖雪, 殷高方, 段静波, 石朝毅. 以巯基丙酸为稳定剂的水溶性CdTe量子点的水热合成及表征[J]. 发光学报, 2012,33(12): 1309-1314

GAN Ting-ting, ZHANG Yu-jun, XIAO Xue, YIN Gao-fang, DUAN Jing-bo, SHI Chao-yi. Hydrothermal Synthesis and Characterization of Mercaptopropionic Acid Modified Water-soluble CdTe Quantum Dots[J]. Chinese Journal of Luminescence, 2012,33(12): 1309-1314
甘婷婷, 张玉钧, 肖雪, 殷高方, 段静波, 石朝毅. 以巯基丙酸为稳定剂的水溶性CdTe量子点的水热合成及表征[J]. 发光学报, 2012,33(12): 1309-1314 DOI： 10.3788/fgxb20123312.1309.

GAN Ting-ting, ZHANG Yu-jun, XIAO Xue, YIN Gao-fang, DUAN Jing-bo, SHI Chao-yi. Hydrothermal Synthesis and Characterization of Mercaptopropionic Acid Modified Water-soluble CdTe Quantum Dots[J]. Chinese Journal of Luminescence, 2012,33(12): 1309-1314 DOI： 10.3788/fgxb20123312.1309.

摘要

以巯基丙酸(MPA)为稳定剂

采用水热合成方法在160 ℃下合成水溶性CdTe量子点。研究了不同反应时间及反应前驱体溶液的不同pH值对合成的CdTe量子点光学性质的影响。结果表明:所制得的CdTe量子点的荧光发射波长在510~661 nm范围内连续可调

并且CdTe量子点的光学性质强烈地依赖于反应前驱体溶液的pH值

最佳pH值为9。透射电子显微镜和X射线衍射分析表明所制备的CdTe量子点的形状接近于球形

粒径分布较均匀。与回流方法制备的水溶性量子点相比

高温条件下的水热合成方法简单

反应时间短

CdTe量子点生长速度快

100 min就可生长到3.5 nm

并且所制得的CdTe量子点荧光强度高

稳定性好

荧光量子产率也较高

最高可达44.6%。

Abstract

Mercaptopropionic acid (MPA) modified high quality CdTe quantum dots (QDs) were prepared by hydrothermal synthesis method in a high temperature. The influences of different reaction time and different pH value of the reactive precursor solution on the optical properties of CdTe QDs were studied. The results indicate that the fluorescence emission wavelength of the as-prepared CdTe QDs can be adjusted continuously at a range of 510~661 nm

and the optical properties of CdTe QDs strongly depend on the pH value of the reactive precursor solution(the optimum pH value is 9). The samples were characterized by transmission electron microscopy and X-ray diffraction. The results show that the shape of the as-prepared CdTe QDs is closed to sphere

and the particle size distribution is uniform. Comparing with the reflux method for preparing water-soluble QDs

the hydrothermal synthesis method at a high temperature is relatively simple

and the reaction time is shorter

the growth of CdTe QDs is faster

the particle size can be grown to 3.5 nm within 100 min. The as-prepared CdTe QDs possess higher fluorescence intensity

good stability and higher fluorescence quantum yield (up to 44.6%).

关键词

Keywords

references

Li Z, Wang Y X, Zhang G X, et al. Luminescent properties and cytotoxicity of CdTe quantum dots with different stabilizing agents [J]. J. Inorg. Mater.(无机材料学报), 2010, 25(5):495-499 (in Chinese).

Tomczak N, Janczewski D, Han M Y, et al. Designer polymer-quantum dot architectures [J]. Prog. Polym. Sci., 2009, 34(5):393-430.

Tian X, Cao L X, Liu W, et al. Synthesis and photoluminescent properties of core/shell structure ZnS∶Cu/ZnS quantum dots [J]. Chin. J. Lumin.(发光学报), 2012, 33(7):736-741 (in Chinese).

Liu J J, Shi Z X, Yu Y C, et al. Water-soluble multicolored fluorescent CdTe quantum dots: Synthesis and application for fingerprint developing [J]. Colloid Interf. Sci., 2010, 342(2):278-282.

Guo C, Gao G Y, Ding X J, et al. Determination of diethylstilbestrol in milk with the enhanced chemiluminescence system of luminol-K3Fe(CN)6 by using of ZnSe quantum dots [J]. Chin. J. Lumin.(发光学报), 2012, 33(7):796-801 (in Chinese).

Yu Y, Lai Y, Zheng X L, et al. Synthesis of functionalized CdTe/CdS QDs for spectrofluorimetric detection of BSA [J]. Spectrochim. Acta, Part A, 2007, 68(5):1356-1361.

Wu Y Y, Zhang X S, Xu J P, et al. Memory effect and charge-transport mechanisms of write-once-read-many-times bistable devices based on ZnS quantum dots embedded in poly-4-vinyl-phenol layer [J]. Chin. J. Lumin.(发光学报), 2012, 33(4):428-432 (in Chinese).

Zhang X. Fluorescence properties of Ⅱ-Ⅵ group quantum dot and its applications in analytical chemistry [J]. Anhui Chemical Industry (安徽化工), 2011, 37(4):4-6 (in Chinese).

Wang X Y, Liu X Y, Zhao J L. Synthesis and luminescence properties of CuInS2 nanocrystals [J]. Chin. J. Lumin.(发光学报), 2012, 33(1):7-11 (in Chinese).

Li M Y, Zhou H M, Zhang H Y, et al. Preparation and purification of L-cysteine capped CdTe quantum dots and its self-recovery of degenerate fluorescence [J]. J. Lumin., 2010, 130(10):1935-1940.

Ma H. Preparation of CdTe Quantum Dots and Its Preliminary Application . Tianjin: Tianjin University, 2010 (in Chinese).

Li H, He T, Dai L G, et al. Photoluminescence of GeSi self-assembled quantum dots grown by gas source MBE [J]. Chin. J. Lumin.(发光学报), 2011, 32(8):789-792 (in Chinese).

Na J, Hou M. Synthesis and spectral application of functionalized CdTe quantum dots as fluorescence probe [J]. J. Guilin Univ. Technol.(桂林理工大学学报), 2010, 30(1):133-136 (in Chinese).

Xu L H, Qiang Y H, Jiang L. Photoluminescent properties of CdS quantum dots doped in silica xerogel [J]. Chin. J. Lumin.(发光学报), 2011, 32(3):227-231 (in Chinese).

Abhijit M, Naoto T. Influence of acid on luminescence properties of thioglycolic acid-capped CdTe quantum dots [J]. J. Phys. Chem. C, 2008, 112(22):8244-8250.

Peng H, Zhang L J, Soeller C, et al. Preparation of water-soluble CdTe/CdS core/shell quantum dots with enhanced photostability [J]. J. Lumin., 2007, 127(2):721-726.

Xu R H, Wang Y X, Xu W B, et al. Study on synthesis and fluorescent property of CdS nanocrystals [J]. J. Synth. Cryst.(人工晶体学报), 2006, 35(5):1007-1011 (in Chinese).

Chen Q F, Wang W X, Ge Y X, et al. study on hydrothermal synthesis CdTe quantum dots and their conjugation to protein as luminescence probe [J]. Chin. J. Anal. Lab.(分析试验室), 2007, 26(3):1-5 (in Chinese).

Yang W H, Li W W, Sun K. Hydrothermal synthesis of cysteamine-stabilized CdTe quantum dots [J]. Chem. J. Chin. Univ.(高等学校化学学报), 2008, 29(4):681-685 (in Chinese).

Zhang H, Zhou Z, Bai Y. The influence of carboxyl groups on the photoluminescence of mercaptocarboxylic acid-stabilized CdTe nanoparticles [J]. J. Phys. Chem. B, 2003, 107(1):8-13.

Shao C, Liu X Y, Zhao J L. Effect of mercaptopropionic acid molecules on electron transfer from CdSe core/shell quantum dots to ZnO nanocrystal films [J]. Chin. J. Lumin.(发光学报), 2012, 33(1):26-31 (in Chinese).

Wang Y L, Tong Z F, Lu J P, et al. Synthesis and characterization of water-soluble CdHgTe alloyed quantum dots [J]. J. Inorg. Mater.(无机材料学报), 2011, 26(7):735-738 (in Chinese).

Wang Y F, Zhang J H, Jia H Y, et al. Mercaptopyridine surface-functionalized CaTe quantum dots with enhanced Raman scattering properties [J]. J. Phys. Chem. C, 2008, 112(4):996-1000.

Hasselbarth A, Eychmuller A, Eichburger R, et al. Chemistry and photophysics of mixed cadmium sulfide/mercury sulfide colloids [J]. J. Phys. Chem., 1993, 97(20):5333-5340.

Shi P. Synthesis and luminescent properties of water-soluble CdTe nanocrystals [J]. Chin. J. Spectrosc. Lab.(光谱实验室), 2008, 25(3):390-393 (in Chinese).

Qin Y B, Yang X, Yu J S. Synthesis and characterization of CdTe nanoparticles stabilized by cysteamine [J]. Chi. J. Inorg. Chem.(无机化学学报), 2006, 22(5):851-855 (in Chinese).

Liang J R, Zhong W Y, Yu J S. Rapid aqueous synthsis of high-quality CdTe colloidal quantum dots [J]. Chem. J. Chin. Univ.(高等学校化学学报), 2009, 30(1):14-18 (in Chinese).

0

Views

117

下载量

3

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Related Articles

Fluorescence Interaction Between Folate Molecules and CdTe and CdTe/CdS Quantum Dots

Research Progress of Circulating Tumor Cell Detection Based on Fluorescence Method

Crosslinking Agents Enhancing Fluorescence Performance of Carboxylate Graphene Quantum Dots

Preparation of Copper/Silver Bimetallic Nanoclusters Stabilized by Penicillamine and Their Application in Silver Ion Detection

Related Author

Guang-min LI

Hao-yang LIU

Yang YANG

Hong-fei LIU

Xue-ning FEI

Wei LIU

Guangmin LI

Haoyang LIU

Related Institution

School of Science, Tianjin Chengjian University

Zhongqi Zhongxin(Tianjin) Industrial Design Co., Ltd.

School of Science， Tianjin Chengjian University

Zhongqi Zhongxin （Tianjin） Industrial Design Co.， Ltd

State Key Laboratory of Integrated Optoelectronics， College of Electronic Science and Engineering， Jilin University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰