Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane

XIE An; LUO Geng-geng

doi:10.3788/fgxb20123311.1192

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Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane

更新时间：2020-08-12

- Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane
- Chinese Journal of Luminescence Vol. 33, Issue 11, Pages: 1192-1197(2012)
- 作者机构：
  
  1. 厦门理工学院材料科学与工程系,福建厦门,361024
  2. 华侨大学材料科学与工程学院,福建厦门,361021
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123311.1192
  CLC： O469;O756;O613.42
- Received：05 July 2012，
  
  Revised：07 September 2012，
  
  Published：10 November 2012
- 稿件说明：
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谢安, 骆耿耿. 以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质[J]. 发光学报, 2012,(11): 1192-1197

XIE An, LUO Geng-geng. Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane[J]. Chinese Journal of Luminescence, 2012,(11): 1192-1197
谢安, 骆耿耿. 以AgCl和1,2-二(4-吡啶)乙烷为原料合成的二维无机-有机杂化聚合物的晶体结构及荧光性质[J]. 发光学报, 2012,(11): 1192-1197 DOI： 10.3788/fgxb20123311.1192.

XIE An, LUO Geng-geng. Crystal Structure and Luminescent Property of 2D Hybrid Silver Chloride with 1,2-Bis(4-pyridyl)Ethane[J]. Chinese Journal of Luminescence, 2012,(11): 1192-1197 DOI： 10.3788/fgxb20123311.1192.

摘要

以AgCl与柔性配体1

2-二(4-吡啶)乙烷(bpe)为原料

在1:1的甲醇-水混合溶剂中超声反应合成了一个新的无机-有机杂化聚合物[Ag

(BPE)

]

(

)

并对该配合物进行了元素分析、红外光谱分析、热重分析、发光测试以及晶体结构研究。配合物属于三斜晶系

空间群

a=0.998 8(2) nm

b=1.115 1(2) nm

c=1.269 5(3) nm

α=64.27(3)°

β=85.71(3)°

γ=86.70(3)°

V=1.269 7(5) nm

Z=2。单晶结构分析表明

该化合物

含有一维的(Ag

)

链

双氮配体BPE进一步连接该一维链形成了二维双层结构。固体发光性能测试表明

该化合物在385 nm光激发下能发出峰值为525 nm的黄光。此外

热分析表明

该化合物热稳定性可达到170℃。

Abstract

Using the flexible dipyridyl ligand 1

2-bis(4-pyridyl)ethane (bpe)

a hybrid silver chloride [Ag

-(bpe)

]

(1) has been synthesized by ultrasonic method. The experimental results indicate that it belongs to triclinic system with space group P1. The structure of complex

features 1D (Ag

)

chains

which are further linked by bipodal spacers bpe to form a 2D bilayer structure. In addition

the complex 1 shows a strong yellow emission band that peaks at 525 nm (λ

=385 nm) in the solid state at room temperature

and it is thermally stable below 170℃.

关键词

Keywords

references

Ding B, Chuang R N, Wu X X, et al. Synthesis and characterization of one novel 1D double-chain copper(Ⅱ) complex with 1,2-bis(1,2,4-triazole-1-yl)ethane [J]. Chin. J. Inorg. Chem.(无机化学学报), 2011, 27(1):189-192 (in English).

Gu L Y, Tu H, Zhu L, et al. Synthesis and luminescent properties of novel metal-organic coordination polymers based on bisphenol A [J]. Chin. J. Lumin.(发光学报), 2011, 32(2):127-133 (in Chinese).

Wang C C, Song Y X, Wang Y L, et al. Syntheses, crystal structure and optical property of two bis-ligand silver(Ⅰ) complexes containing diphenic acid and bidentate N-donor ligands [J]. Chin. J. Inorg. Chem.(无机化学学报), 2011,27(2):361-366 (in English).

Luo G G, Wu D L, Liu L, et al. A novel 1D T5(0)A(2) water tape incorporated in the channel of the first 3D silver-suberate framework [J]. J. Mol. Struct., 2012, 1014(1):92-96.

Luo G G, Li D X, Wu D L, et al. Characterization of a well-resolved acyclic methanol(water)5 heterohexamer in the solid state [J]. Inorg. Chem. Commun., 2012, 17(1):108-112.

Engelhardt L M, Gotsis S, Healy P C, et al. Lewis-base adducts of group 11 metal(Ⅰ) compounds.XLV. conformational systematics of [(N-base)1(AgX)1]N complexes [J]. Aust. J. Chem., 1989, 42(1):149-176.

Zhang L, Zhang J, Li Z J, et al. New coordination motifs of melamine directed by N-H center dot center dot center dot X(X=Cl or Br) hydrogen bonds [J]. Inorg. Chem., 2007, 46(15):5838-5840.

Graham P M, Pike R D, Sabat M, et al. Coordination polymers of copper(Ⅰ) halides [J]. Inorg. Chem., 2000, 39(22):5121-5132.

Place H, Scott B, Willett R D. A new one-dimensional copper(Ⅰ) halide lattice: (paraquat)Cu4Cl6 [J]. Inorg. Chim. Acta, 2001, 319(1):43-48.

Xu X X, Ma Y, Wang E B. Synthesis, structure, and luminescent property of the first mixed-valence Cu-halide complex constructed from novel D6R Cu6Cl6 cores [J]. Inorg. Chem. Commun., 2007, 10(9):1113-1116.

Bowmaker G A, Effendy, Skelton B W, et al. Syntheses, structures and vibrational spectroscopy of some unusual silver(I) (pseudo-) halide/unidentate nitrogen base polymers [J]. Inorg. Chim. Acta, 2005, 358(14):4307-4326.

Zartilas S, Kourkoumelis N, Hadjikakou S K, et al. A new silver(Ⅰ) aggregate having an octagonal Ag4S4 Core where μ3-S bonding interactions lead to a nanotube assembly that exhibits quasiaromaticity [J]. Eur. J. Inorg. Chem., 2007, (9):1219-1224.

Zhang L, Li Z J, Qin Y Y, et al. Homochiral moganite-type metal-organic framework based on unusual (Ag2Cl)/em>n skeletons [J]. Cryst. Eng. Comm., 2008, 10(6):655-657.

Luo G G, Xiong H B, Sun D, et al. A discrete spirocyclic (H2O)9 cluster and 1D novel water chain with tetrameric and octameric clusters in cationic hosts [J]. Cryst. Growth & Des., 2011, 11(5):1948-1956.

Luo G G, Sun D, Xu Q J, et al. Photoluminescent metal-organic coordination polymer incorporating one-dimensional silver chains [J]. Inorg. Chem. Commun., 2009, 12(5):436-439.

Luo G G, Wu D L, Liu L, et al. A discrete water hexamer with a new planar tetrameric water moiety trapped in the crystal host of [Ag(azelate)(4,4'-bipyridine)]·(H2O)3 [J]. J. Mol. Struct., 2011, 1005(1):172-177.

Luo K J, Jiang S P, Wang X, et al. Efficient green phosphorescent polymer light-emitting diodes based on cyclometalated iridium complex [J]. Chin. J. Lumin.(发光学报), 2011, 32(4):368-373 (in English).

Sheldrick G M, Phase annealing in SHELX-90: Direct methods for larger structures [J]. Acta Crystallogr., 1990, A46(6):467-473.

Sheldrick G M. A short history of SHELX [J]. Acta Crystallogr., 2008, A64(1):112-122.

Spek A L. Implemented as The PLATON Procedure, A Multi-purpose Crystallographic Tool [M]. Ultrecht, Netherlands: Utrecht University, 1998.

Yang L, Powell D R, Houser R P. Structural variation in copper(Ⅰ) complexes with pyridylmethylamide ligands: Structural analysis with a new four-coordinate geometry index, τ4 [J]. Dalton Trans., 2007, (9):955-964.

Addison A W, Rao T N, Reedijk J, et al. Synthesis, structure, and spectroscopic properties of copper(Ⅱ) compounds containing nitrogen-sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2'-yl)-2,6-dithiaheptane]copper(Ⅱ) perchlorate [J]. J. Chem. Soc., Dalton Trans., 1984, (7):1349-1356.

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