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1. 北京交通大学光电子技术研究所 教育部发光与光信息技术重点实验室 北京,100044
2. 国家电光源质量监督检验中心(北京) 北京,100022
Received:13 July 2012,
Revised:20 August 2012,
Published:10 October 2012
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孟腾飞, 何志群, 刘姝, 刘淑洁, 梁春军, 张娇. 三波段白光有机电致发光器件及其色稳定性的控制[J]. 发光学报, 2012,(10): 1095-1100
MENG Teng-fei, HE Zhi-qun, LIU Shu, LIU Shu-jie, LIANG Chun-jun, ZHANG Jiao. Towards Color Stable Three-band White Organic Light-emitting Diodes[J]. Chinese Journal of Luminescence, 2012,(10): 1095-1100
孟腾飞, 何志群, 刘姝, 刘淑洁, 梁春军, 张娇. 三波段白光有机电致发光器件及其色稳定性的控制[J]. 发光学报, 2012,(10): 1095-1100 DOI: 10.3788/fgxb20123310.1095.
MENG Teng-fei, HE Zhi-qun, LIU Shu, LIU Shu-jie, LIANG Chun-jun, ZHANG Jiao. Towards Color Stable Three-band White Organic Light-emitting Diodes[J]. Chinese Journal of Luminescence, 2012,(10): 1095-1100 DOI: 10.3788/fgxb20123310.1095.
制备并研究了基于3种小分子荧光材料的白光有机电致发光器件。发光层采用红色发光材料DCJTB掺杂绿光材料Alq
3
构成混合发光层
与OXD-7构成的蓝色发光层形成异质结的结构
并以NPB为空穴注入层。通过改变结构参数详细研究了发射光谱及其色坐标的电场依赖性。通过分析载流子注入/传输特性
控制激子的复合区域等措施得到了色坐标稳定性好、光谱丰富的高性能白光电致发光器件。经过优化的器件结构可以覆盖更大的可见光区域
当电压从9V增加到13V时
色坐标仅从CIE(
x
y
)=(0.364
0.314)偏移到CIE
(x
y)
=(0.332
0.291)
具有较好的色稳定性。
White organic light-emitting diodes based on three small molecular fluorescence materials were designed and prepared.The emitting layers consisted of a red dye
4-(dicyanomethylene)-2-tert-butyl-6-(1
1
7
7-tetra-methyljulolidin-4-yl-vinyl)-4H-pyran (DCJTB)
doped in a green layer of 8-hydroxyquinoline aluminum salt (Alq
3
)
which further formed a heterojunction with a blue layer of 2
2'-(1
3-phenylene)-bis (OXD-7).N
N'-bis-(naphthalene-1-yl)-N
N'-bis(phenyl)-benzidine (NPB) was used as a hole transport layer.Voltage dependent emission spectra and their colorimetric characteristics were manipulated using different device structures.After adjusting the carrier injection/transporting properties
the exciton recombination region was confined and the color stability was improved against the driving voltages.An improved white light-emitting device has a wide spectrum in visible range and a good color stability
its color coordinates change slightly from CIE(
x
y
)=(0.364
0.314) to CIE(
x
y
)=(0.332
0.291) when the driven voltage changes from 9.1 V to 12.9 V.
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Yu L Z,Jiang X Y,Zhang Z L,et al. Investigation of Frster-type energy transfer in organic light-emitting devices with 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethy ljulolidin-4-yl-vinyl)-4H-pyran doped cohost emitting layer [J]. J.Appl.Phys.,2009,105(1):013105-1-4.
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Wang Y M,Teng F,Xu Z,et al. Trap effect of an ultrathin DCJTB layer in organic light-emitting diodes [J]. Materials Chemistry and Physics,2005,92(2-3):291-294.
Park Y S,Kang J W,Kang D M,et al. Efficient,color stable white organic light-emitting diode based on high energy level yellowish-green dopants [J]. Advanced Materials, 2008,20(10):1957-1961.
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