Luminescent Properties of Sr3-xSi1-xAlxO5∶xCe3+ Phosphors Prepared by Heterogeneous Precipitation Method

PENG Jie; ZENG Ren-jie; LI Lang-kai

doi:10.3788/fgxb20123309.0966

您当前的位置：

首页 >

文章列表页 >

Luminescent Properties of Sr_3-xSi_1-xAl_xO₅∶xCe³⁺ Phosphors Prepared by Heterogeneous Precipitation Method

更新时间：2020-08-12

- Luminescent Properties of Sr_3-xSi_1-xAl_xO₅∶xCe³⁺ Phosphors Prepared by Heterogeneous Precipitation Method
- Chinese Journal of Luminescence Vol. 33, Issue 9, Pages: 966-972(2012)
- 作者机构：
  
  1. 厦门大学材料学院,福建厦门,361005
  2. 福建省特种先进材料重点实验室,福建厦门,361005
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123309.0966
  CLC： O482.31
- Received：17 June 2012，
  
  Revised：12 July 2012，
  
  Published：10 September 2012
- 稿件说明：
移动端阅览
彭杰, 曾人杰, 李郎楷. 非均相沉淀法制备的Sr3-xSi1-xAlxO5∶xCe3+ 荧光粉及其发光性能[J]. 发光学报, 2012,33(9): 966-972

PENG Jie, ZENG Ren-jie, LI Lang-kai. Luminescent Properties of Sr3-xSi1-xAlxO5∶xCe3+ Phosphors Prepared by Heterogeneous Precipitation Method[J]. Chinese Journal of Luminescence, 2012,33(9): 966-972
彭杰, 曾人杰, 李郎楷. 非均相沉淀法制备的Sr3-xSi1-xAlxO5∶xCe3+ 荧光粉及其发光性能[J]. 发光学报, 2012,33(9): 966-972 DOI： 10.3788/fgxb20123309.0966.

PENG Jie, ZENG Ren-jie, LI Lang-kai. Luminescent Properties of Sr3-xSi1-xAlxO5∶xCe3+ Phosphors Prepared by Heterogeneous Precipitation Method[J]. Chinese Journal of Luminescence, 2012,33(9): 966-972 DOI： 10.3788/fgxb20123309.0966.

摘要

采用非均相沉淀法制备了Sr

∶

荧光粉

并与高温固相法制备的该荧光粉进行了对比。以XRD、SEM和荧光光谱分析来表征所制备的荧光粉。结果表明

非均相沉淀法比高温固相反应法制备的荧光粉相纯度更高

颗粒分布更窄

晶面清晰

团聚程度小

相对发光强度也更高。荧光粉的激发光谱为270~500 nm的双峰宽带

最强激发峰位于417 nm处。发射光谱为450~700 nm的单峰宽带

峰值位于525 nm处。电荷补偿剂对荧光粉相对发光强度影响较大

外加Al

置换Si

作为电荷补偿剂比外加Li

置换Sr

的效果更好。

Abstract

Phosphors of nominal composition Sr

∶

were prepared by heterogeneous precipitation method and high temperature solid state reaction method

respectively. The phosphors were characterized by XRD

SEM and fluorescence spectrum analysis. The results show that phosphors synthesized by heterogeneous precipitation method have higher phase purity

narrower particle size distribution

clearer crystal surface and lighter aggregation

also yield higher relative luminous intensity

than those by high temperature solid state reaction method. The excitation spectra of the phosphors range from 270 nm to 500 nm with the bimodal broadband

while the strongest excitation peak at 417 nm. The emission spectra range from 450 nm to 700 nm with single-peak broadband

with peak at 525 nm. Charge compensation has a great influence on the relative luminous intensity of phosphors. It could be conclude that adding Al

to substitute Si

as charge compensation might be better than adding Li

to substitute Sr

关键词

Keywords

references

Liu X R. Phosphors for white LED solid state lighting [J]. Chin. J. Lumin.(发光学报), 2007, 28(3):291-301 (in Chinese).

Lin C C, Liu R S. Advances in phosphors for light-emitting diodes [J]. J. Phys. Chem. Lett., 2011, 2(11):1268-1277.

Shimizu Y, Sakano K, Noguchi Y, et al. Light emitting device having a nitride compound semiconductor and a phosphor containing a garnet fluorescent material: US, 5998925 . 1999-12-07.

Setlur A. Phosphors for LED-based solid-state lighting [J]. Electrochem. Soc. Interface, 2009, 18(4):32-36.

Xu J, Xia W, Xiao Z G, et al. Preparation and luminescent properties of high quality Sr2-xBaxSiO4∶Eu2+ phosphors [J]. Chin. J. Lumin.(发光学报), 2009, 30(5):617-396 (in Chinese).

Park J K, Kim C H, Park S H, et al. Application of strontium silicate yellow phosphor for white light-emitting diodes [J]. Appl. Phys. Lett., 2004, 84(10):1647-1649.

Kang E H, Choi S W, Chung S E, et al. Photoluminescence characteristics of Sr3SiO5∶Eu2+ yellow phosphors synthesized by solid-state method and pechini process [J]. J. Electrochem. Soc., 2011, 158(11):J330-J333.

Jang H S, Jeon D Y. Yellow-emitting Sr3SiO5∶Ce3+, Li+ phosphor for white-light-emitting diodes and yellow-light-emitting diodes [J]. Appl. Phys. Lett., 2007, 90(4):041906-1-3.

Yang Y, Jin S Z, Shen C Y, et al. Spectral properties of alkaline earth composite silicate phosphors for white LED [J]. Chin. J. Lumin.(发光学报), 2008, 29(5):800-804 (in Chinese).

Xu X R, Su M Z.Luminescence and Luminescent Materials [M]. 1th Edition, Beijing: Chemical Industry Press, 2004:55, 599, 611 (in Chinese).

Zhao A P, Deng H, Liu F. Characterization of YAG∶Ce3+phosphor synthesized via ultrasonic co-precipitation by different techniques [J]. Chin. J. Lumin.(发光学报), 2011, 32(11):1104-1108 (in Chinese).

Chen W C. Eu2+ activated Sr2-xBaxSiO4 and Sr3-xBaxSiO5 phosphors .Taiwan:National Cheng Kung University, 2008.

Gao S X, Chen Y B, Zeng R J. Preparation and characterization of agglomerate free YAG∶Ce3+ phosphor by co precipitating and spray drying [J]. Chin. J. Lumin.(发光学报), 2010, 31(6):806-811 (in Chinese).

Matsubara I, Paranthaman M, Allison S W, et al. Preparation of Cr-doped Y3Al5O12 phosphors by heterogeneous preci-pitation methods and their luminescent properties [J]. Mater. Res. Bull., 2000, 35(2):217-224.

Yuan F, Ryu H. Ce-doped YAG phosphor powders prepared by co-precipitation and heterogeneous precipitation [J]. Mater. Sci. Eng. B, 2004, 107(1):14-18.

Zeng R J, Chen Y B. Rare earth ions doped yttrium aluminum garnet phosphors synthesized by oxalic acid heterogeneous precipitation method: China, 200710009678.6 . 2009-09-23.

Liu X L, Chen Y B, Zeng R J. Preparation of Eu2+and Mn2+ co doped Ba3MgSi2O8 phosphor through heterogeneous precipitation [J]. J. Ceram.(陶瓷学报), 2011, 32 (4):534-539 (in Chinese).

Zeng R J. The Chemistry of Inorganic Materials [M]. Xiamen: Xiamen University Press, 2001:200 (in Chinese).

Im W B, Fellows N N, Seshadri R, et al. La1-x-0.025Ce0.025Sr2+xAl1-xSixO5 solid solutions as tunable yellow phosphors for solid state white lighting [J]. J. Mater. Chem., 2009, 19(9):1325-1330.

Dean J A. Lange's Handbook of Chemistry [M]. 13th Edition, New York: McGraw Hill Book Company, 1985:384.

Fields J M, Dear P S, Brown J J. Phase equilibria in the system BaO-SrO-SiO2 [J]. J. Am. Ceram. Soc., 1972, 55(12):585-588.

Nakamura Y, Watari T, Torikai T, et al. Synthesis and luminescence properties of Eu2+ activated Sr3SiO5 phosphors [J]. IOP Conf. Series.: Mater. Sci. Eng., 2011, 18:1-4.

Kingery W D, Bowen H K, Uhlmann D R. Introduction to Ceramics [M]. New York: John Wiley and Sons, 1976:422, 451.

Ye R L, Fan Y H, Lu P W. Physical Chemistry of Inorganic Materials [M]. Beijing: China Building Industry Press, 1986:328,355 (in Chinese).

Mah T I, Petry M D. Eutectic composition in the pseudo binary of Y4Al2O9 and Y2O3 [J]. J. Am. Ceram. Soc., 1992, 75(7):2006-2009.

Blasse G, Grabmaier B C. Luminescent Materials [M]. Berlin: Springer-Verlag, 1994:45.

Glasser L S D, Glasser F P. Silicates M3SiO5 I. Sr3SiO5 [J]. Acta Cryst., 1965, 18(3):453-454.

Shannon R D. Revised effective ionic radii and systematic studies of interatomie distances in halides and chaleogenides [J]. Acta Cryst. A, 1976, 32(5):751-767.

Pu Y, Zhu D C, Han T. Preparation and characterization of Ca1-x-yWO4∶xPr3+, yLi+ deep red phosphors for white LEDs excited by blue light [J]. Chin. J. Lumin.(发光学报), 2012, 33(1):12-16 (in Chinese).

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Crystal Structure and Luminescence Properties of (Ca_2.94-xLu_xCe_0.06)(ScMg)Si₃O₁₂ Phosphors for White LEDs

Luminescence Properties and Application of Ce³⁺ Doped Ba₃Y₂(BO₃)₄ Phosphor

Synthesis and Luminescence Properties of Abnormal Thermal Quenching Red Phosphor Sr₂Ga₂SiO₇∶Sm³⁺

Advance in Mn⁴⁺-doped Oxyfluoride Red-emitting Phosphors for WLED

Improving Moisture Resistance of K₂SiF₆∶Mn⁴⁺ via Passivation Effect of Lactobionic Acid

Related Author

LIU Yong-fu

ZHANG Xia

HAO Zhen-dong

WANG Xiao-jun

ZHANG Jia-hua

SUN Xiaoyuan

LIU Chunmiao

LI Min

Related Institution

Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences

Graduate School of Chinese Academy of Sciences

Department of Physics, Georgia Southern University, Statesboro

Department of Physics， Changchun Normal University

Key Laboratory of Luminescence Science and Technology， Chinese Academy of Sciences & State Key Laboratory of Luminescence and Applications， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰