Temperature Characteristic of Blue Up-conversion Emission in Tm3+,Yb3+ Codoped Oxyfluoride Glass Ceramic

ZHENG Long-jiang; GAO Xiao-yang; XU Wei; ZHANG Zhi-guo

doi:10.3788/fgxb20123309.0944

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Temperature Characteristic of Blue Up-conversion Emission in Tm³⁺,Yb³⁺ Codoped Oxyfluoride Glass Ceramic

更新时间：2020-08-12

- Temperature Characteristic of Blue Up-conversion Emission in Tm³⁺,Yb³⁺ Codoped Oxyfluoride Glass Ceramic
- Chinese Journal of Luminescence Vol. 33, Issue 9, Pages: 944-948(2012)
- 作者机构：
  
  1. 燕山大学河北省测试计量技术及仪器重点实验室,河北秦皇岛,066004
  2. 哈尔滨工业大学凝聚态科学与技术研究所,黑龙江哈尔滨,150001
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123309.0944
  CLC： O433
- Received：17 May 2012，
  
  Revised：12 July 2012，
  
  Published：10 September 2012
- 稿件说明：
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郑龙江, 高晓阳, 徐伟, 张治国. Tm3+ ,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性[J]. 发光学报, 2012,33(9): 944-948

ZHENG Long-jiang, GAO Xiao-yang, XU Wei, ZHANG Zhi-guo. Temperature Characteristic of Blue Up-conversion Emission in Tm3+,Yb3+ Codoped Oxyfluoride Glass Ceramic[J]. Chinese Journal of Luminescence, 2012,33(9): 944-948
郑龙江, 高晓阳, 徐伟, 张治国. Tm3+ ,Yb3+共掺微晶玻璃蓝色上转换荧光的温度特性[J]. 发光学报, 2012,33(9): 944-948 DOI： 10.3788/fgxb20123309.0944.

ZHENG Long-jiang, GAO Xiao-yang, XU Wei, ZHANG Zhi-guo. Temperature Characteristic of Blue Up-conversion Emission in Tm3+,Yb3+ Codoped Oxyfluoride Glass Ceramic[J]. Chinese Journal of Luminescence, 2012,33(9): 944-948 DOI： 10.3788/fgxb20123309.0944.

摘要

制备了Tm

共掺氟氧化物微晶玻璃

在980 nm二极管激光器泵浦下研究了其上转换发光。发现将前驱玻璃进行热处理后

源于Tm

的

能级到基态

跃迁所产生的蓝色上转换荧光在463 nm和476 nm出现明显劈裂。在此基础上分析了该劈裂蓝色上转换荧光在303~623 K范围内的温度特性。结果表明:Tm

共掺氟氧化物微晶玻璃蓝色上转换荧光可应用于光学测温

其测温最大灵敏度为4.2×10

-4

-1

相应温度为352 K。

Abstract

codoped oxyfluoride ceramic glass was prepared and their up-conversion luminescence property was studied under the pump of 980 nm diode laser. In the luminescence spectra of annealed samples

stark splits of luminescence were observed at 463 nm and 476 nm. Temperature property of this split was studied between 303 K and 623 K. The results indicate that Tm

codoped oxyfluoride ceramic glass could be used for temperature measurement according to luminescence intensity ratio. The best sensitivity is 4.2?10

-4

-1

at 352 K.

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references

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