Synthesis of(E)-5-(dimethylamino)-N-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion

WU Hong-mei; GUO Yu

doi:10.3788/fgxb20123307.0790

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Synthesis of(E)-5-(dimethylamino)-N-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion

更新时间：2020-08-12

- Synthesis of(E)-5-(dimethylamino)-N-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion
- Chinese Journal of Luminescence Vol. 33, Issue 7, Pages: 790-795(2012)
- 作者机构：
  
  辽宁工业大学化学与环境工程学院, 辽宁锦州 121001
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123307.0790
  CLC： O482.31
- Received：12 April 2012，
  
  Revised：26 April 2012，
  
  Published Online：10 July 2012，
  
  Published：10 July 2012
- 稿件说明：
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吴红梅, 郭宇. 新型锌离子荧光探针(5-(二甲基氨基)-N-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)的研究[J]. 发光学报, 2012,33(7): 790-795

WU Hong-mei, GUO Yu. Synthesis of(E)-5-(dimethylamino)-N-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion[J]. Chinese Journal of Luminescence, 2012,33(7): 790-795
吴红梅, 郭宇. 新型锌离子荧光探针(5-(二甲基氨基)-N-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)的研究[J]. 发光学报, 2012,33(7): 790-795 DOI： 10.3788/fgxb20123307.0790.

WU Hong-mei, GUO Yu. Synthesis of(E)-5-(dimethylamino)-N-(4-(2-(quinolin-2-ylmethylene)- hydrazinecarbonyl)phenyl) naphthalene-1-sulfonamide for Detection of Zinc Ion[J]. Chinese Journal of Luminescence, 2012,33(7): 790-795 DOI： 10.3788/fgxb20123307.0790.

摘要

以丹磺酰胺为荧光基团设计合成了新型Zn

荧光探针DW1(5-(二甲基氨基)-

-(4-(2-(2-喹啉亚甲基)甲酰肼基)苯基)萘-1-磺酰胺)。通过紫外光谱、荧光光谱及电喷雾质谱研究了DW1对Zn

的选择性识别作用。结果表明

DW1与Zn

结合后荧光显著增强

荧光发射光谱由545 nm蓝移至515 nm

量子产率达到0.32

且对Zn

具有较高的选择性

受常见离子的干扰较小。光谱滴定和ESI-MS谱表明DW1与Zn

以1∶1的化学计量数形成配合物

平衡常数

=1.75×10

(mol/L)

-1

。

Abstract

A novel dansyl sulfonamide-based fluorescence probe

(E)-5-(dimethylamino)-

-(4-(2-(quinolin-2-ylmethylene)hydrazinecarbonyl)phenyl)naphthalene-1-sulfonamide (DW1) was synthesized for detection of Zn

. UV-Vis

fluorescence and ESI-MS spectra of DW1 were measured to investigate the selective recognition. The results show that the fluorescence intensity increase significantly with high quantum yield (

=0.32) and blue-shift emission from 545 nm to 515 nm after the coordination of DW1 with Zn

manifesting DW1 could detect Zn

sensitively. Moreover

the selective and competitive fluorescent experiments show that DW1 is highly selective for recognition of Zn

over other common metal ions. Spectrophotometric titration and ESI-MS spectrum indicate the formation of a 1∶1 DW1-Zn

complex and the association constant

was calculated as 1.75×10

(mol/L)

-1

关键词

Keywords

references

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Related Institution

School of Chemical and Environmental Engineering, Liaoning University of Technology

College of Mechanical Engineering and Automation, Liaoning University of Technology

College of Chemical Engineering， University of Science and Technology Liaoning

Beijing Key Laboratory of Work Safety Intelligent Monitoring， School of Electronic Engineering， Beijing University of Posts and Telecommunications

Department of Radiology， the Third Medical Centre， Chinese PLA General Hospital

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