Synthesis and Photoluminescence Properties of Cr3+ Doped Aluminium Nitride

YANG Yan-min; LI Zi-qiang; JIAO Fu-yun; LIU Yun-feng; LI Zhi-qiang; SU Hong-xin; YANG Zhi-

doi:10.3788/fgxb20123305.0504

您当前的位置：

首页 >

文章列表页 >

Synthesis and Photoluminescence Properties of Cr³⁺ Doped Aluminium Nitride

paper | 更新时间：2020-08-12

- Synthesis and Photoluminescence Properties of Cr³⁺ Doped Aluminium Nitride
- Chinese Journal of Luminescence Vol. 33, Issue 5, Pages: 504-508(2012)
- 作者机构：
  
  1. 河北大学物理科学与技术学院, 河北保定 071002
  2. 河北大学工商学院, 河北保定 071002
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123305.0504
  CLC： O482.31
- Received：22 February 2012，
  
  Revised：19 March 2012，
  
  Published Online：10 May 2012，
  
  Published：10 May 2012
- 稿件说明：
移动端阅览
杨艳民, 李自强, 焦福运, 刘云峰, 李志强, 苏红新, 杨志平. 氮化铝铬的制备及其光学性质[J]. 发光学报, 2012,(5): 504-508

YANG Yan-min, LI Zi-qiang, JIAO Fu-yun, LIU Yun-feng, LI Zhi-qiang, SU Hong-xin, YANG Zhi-ping. Synthesis and Photoluminescence Properties of Cr3+ Doped Aluminium Nitride[J]. Chinese Journal of Luminescence, 2012,(5): 504-508
杨艳民, 李自强, 焦福运, 刘云峰, 李志强, 苏红新, 杨志平. 氮化铝铬的制备及其光学性质[J]. 发光学报, 2012,(5): 504-508 DOI： 10.3788/fgxb20123305.0504.

YANG Yan-min, LI Zi-qiang, JIAO Fu-yun, LIU Yun-feng, LI Zhi-qiang, SU Hong-xin, YANG Zhi-ping. Synthesis and Photoluminescence Properties of Cr3+ Doped Aluminium Nitride[J]. Chinese Journal of Luminescence, 2012,(5): 504-508 DOI： 10.3788/fgxb20123305.0504.

摘要

利用直接氮化法得到了氮化铝和氮化铬

并用两种途径得到Cr

掺杂的氮化铝样品。用X射线衍射仪分析了样品晶相并测试了两种样品的激发和发射光谱

计算了晶体场劈裂参数

和Racah参数

B及D

分别为1 800

693.69和2.59。光谱数据表明

在氮化铝中属于强场环境

光发射来自于最低激发态

E能级

与在氧化铝中的环境相似。根据光谱数据给出了Cr

在氮化铝晶体场中的能级。

Abstract

Aluminium nitride and chromium nitride were synthesized by high temperature solid state method with aluminium

chromium and high purity nitrogen. Two types of methods were used to obtain Cr

-doped AlN: one is to nitride mixtures of aluminium and chromium

the other is to heat aluminium nitride and chromium nitride at 1 400 ℃ for 3 h under nitrogen. X-ray diffraction analyzer was used to measure the crystal structure of obtained samples. The excitation and emission spectra of the samples were measured by spectrometer. The obtained data showed that the excitation and emission spectra of Cr

∶AlN obtained by two methods are similar

two broad excited bands

peak at 400 nm and 500 nm

and the emission peak at 696 nm

while the intensity of the latter was higher than that of the former due to higher annealing temperature. According to the excitation and emission spectra of Cr

∶AlN

and the energy levels of Cr

ion in AlN were given. The obtained data showed that the emission of Cr

at 696 nm came from the first excited state

which is similar to that of Cr

in Al

host.

关键词

Keywords

references

Kwak J H, Park Y J, Sohn K S. Photoluminescent and decay behaviors of Mn2+ and Ce3+coactivated MgSiN2 phosphors for use light-emitting-diode applications [J]. Optics Letters, 2009, 34(6):794-796.[2] Suehiro T, Hirosaki N, Xie R J, et al. One-step preparation of Ca-α-SiAlON:Eu2+ fine powder phosphorsfor white light-emitting diodes [J]. Appl. Phys. Lett., 2008, 92(19):191904-1-3.[3] Takahashi K, Hirosaki N, Xie R J, et al. Luminescence properties of blue La1-xCexAl(Si6-zAlz)(N10-zOz) (z~1) oxynitride phosphors and their application in white light-emitting diode [J]. Appl. Phys. Lett., 2007, 91(9):091923-1-3.[4] Kim J S, Jeon P E, Choi J C, et al. Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor [J]. Appl. Phys. Lett., 2004, 84(15):2931-2933[5] Zhang Mei, He Xin, Ding Weijia, et al. Oxynitride and nitride phosphors for white LEDs [J]. Progress in Chemistry (化学进展), 2010, 22(2-3):0376-0384 (in Chinese).[6] Ni Haiyong. Recent progress in nitride and oxy-nitride phosphor of power white LED [J]. Materials Research and Application (材料研究与应用), 2008, 2(4):486-489 (in Chinese).[7] Lia Y Q, van Steena J E J, van Krevela J W H, et al. Luminescence properties of red-emitting M2Si5N8:Eu2+(M=Ca, Sr, Ba) LED conversion phosphors [J]. Journal of Alloys and Compounds, 2006, 417(1-2):273-279[8] Ryu J H, Park Y G, Won H S, et al. luminescent properties of Ca-α-SiAlON:Eu phosphors synthesized by gas-pressured sintering [J]. Journal of The Electrochemical Society, 2008, 155(4):J99-J104.[9] Li Panlai, Liu Haiyan, Wang Zhijun, et al. Luminescence and energy transfer between Ce3+ and Tb3+in SrZnP2O7 Phosphor [J]. Chin. J. Lumin.(发光学报), 2010, 31(5):719-723 (in Chinese).[10] Song X F, Fu R L, Hong S, et al. Photoluminescence properties of Eu2+-activated CaSi2O2N2:Redshift and concentration quenching [J]. J. Appl. Phys., 2009, 106(3):033103-1-5.[11] Wang Renqing. Effects of excitation wavelength and the Eu2+ doped content on phosphorescence of Sr4Al14O25 Eu2+, Dy3+ [J]. Chin. J. Lumin.(发光学报), 2010, 31(5):682-685 (in Chinese).[12] Atakan B, Eckert C, Pflitsch C. Light emitting diode excitation of Cr3+:Al2O3 as thermographic phosphor: Experiments and measurement strategy [J]. Measurement Science and Technology, 2009, 20(7):075304-1-10.[13] Mi Xiaoyun, Zhang Xiyan, Ba Xuewei, et al. Preparation and luminescent properties of Cr3+:Al2O3 nano-powders by low-temperature combustion synthesis [J]. Advanced Powder Technology, 2009, 20(7):164-168.[14] Ha L H, Lanh P T, Long N N, et al. Some physical properties of ZnAl2O4:Cr3+ (Co2+) powders prepared by hydrothermal method [J]. Journal of Physics: Conference Series, 2009, 187(1):012053-1-7.[15] Zhong Ruixia, Zhang Jiahua, Zhang Xia, et al. Red phosphorescence in Sr4Al14O25:Cr3+,Eu2+,Dy3+ through persistent energy transfer [J]. Appl. Phys. Lett., 2006, 88(20):201916-1-3.[16] Nie Z G, Lim K S, Zhang J H, et al. Pr3+ 1S0→Cr3+ energy transfer and ESR investigation in Pr3+ and Cr3+ activated SrAl12O19 quantum cutting phosphor [J]. J. Lumin., 2009, 129(8):844-849.[17] Li Guanghuan, Long Tao, Song Yanhua, et al. Preparation and luminescent properties of CaAl2O4:Eu3+,R+ (R=Li, Na, K) phosphors [J]. Journal of Rare Earths, 2010, 28(1):22-25.[18] Ryu H, Bartwa K S. Cr3+ doping optimization in CaAl2O4:Eu2+ blue phosphor [J]. Journal of Alloys and Compounds, 2008, 22(1-2):317-321.[19] Maqbool M, Wilson E, Clark J, et al. Luminescence from Cr+3-doped AlN films deposited on optical fiber and silicon substrates for use as waveguides and laser cavities [J]. Applied Optics, 2010, 49(4):653-657.[20] Caldwell M L, Martin A L, Dimitrova V I, et al. Emission properties of an amorphous AlN:Cr3+ thin-film phosphor [J]. Appl. Phys. Lett., 2001, 78(9):1246-1249.[21] Aldabergenov S B, Frank G, Strunk H P, et al. Structure changes of AlN:Ho films with annealing and enhancement of the Ho3+ emission [J]. Journal of Non-Crystalline Solids, 2006, 352(9-20):1290-1293.[22] Tu Chaoyang, Yang Fugui, Li Jianfu, et al. Co-transition absorption property of K2ZnCl4:Co2+ crystal [J]. Optics Letters, 2006, 331(15):2299-2301.[23] Sugano S, Tanabe Y, Kamimura H. Multiplets of Transition Metal Ions in Crystals [M]. New York: Academic Press, 1970:121-165.

Views

434

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress on Blue LED Excited Cr³⁺Doped Phosphors with Broad-band Near-infrared Luminescence

Influence of Thickness of Electron Transport Layer and Block Layer on The Properties of Quantum Dot Light Emitting Diodes

Optical Properties of Eu³⁺ ,Dy³⁺ ,Sm³⁺ Doped Ca(Sr,Ba)WO₄

Investigation of Spectroscopic Properties in Eu²⁺ Activated Ba_5-xSr_x(PO₄)₃Cl

First-principles Calculation of AlN Electronic Structure by Doping with Zn and Cd

Related Author

FAN Xian-ping

QIAO Xu-sheng

WANG Chang-jian

YE Ji-xing

CHEN Wen-bai

LI Deng-hua

MA Hang

LIU Yun-feng

Related Institution

School of Materials Science and Engineering， Zhejiang University

北京交通大学电子信息工程学院

北京信息科技大学自动化学院

河北大学物理科学与技术学院

河北大学研究生学院

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰