Downconversion Materials Preparation and The Research of Conversion Efficiency in Pr3+, Yb3+ Co-doped YPO4

LI Kai-yu; WANG Ru-zhi; QU Ming-hao; ZHANG Ying; YAN Hui

doi:10.3788/fgxb20123305.0486

您当前的位置：

首页 >

文章列表页 >

Downconversion Materials Preparation and The Research of Conversion Efficiency in Pr³⁺, Yb³⁺ Co-doped YPO₄

paper | 更新时间：2020-08-12

- Downconversion Materials Preparation and The Research of Conversion Efficiency in Pr³⁺, Yb³⁺ Co-doped YPO₄
- Chinese Journal of Luminescence Vol. 33, Issue 5, Pages: 486-491(2012)
- 作者机构：
  
  北京工业大学材料科学与工程学院北京,100124
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20123305.0486
  CLC： O482.31
- Received：20 January 2012，
  
  Revised：15 March 2012，
  
  Published Online：10 May 2012，
  
  Published：10 May 2012
- 稿件说明：
移动端阅览
李开宇, 王如志, 曲铭浩, 张影, 严辉. Pr3+,Yb3+共掺YPO4下转换材料的制备及其转光效率[J]. 发光学报, 2012,(5): 486-491

LI Kai-yu, WANG Ru-zhi, QU Ming-hao, ZHANG Ying, YAN Hui. Downconversion Materials Preparation and The Research of Conversion Efficiency in Pr3+, Yb3+ Co-doped YPO4[J]. Chinese Journal of Luminescence, 2012,(5): 486-491
李开宇, 王如志, 曲铭浩, 张影, 严辉. Pr3+,Yb3+共掺YPO4下转换材料的制备及其转光效率[J]. 发光学报, 2012,(5): 486-491 DOI： 10.3788/fgxb20123305.0486.

LI Kai-yu, WANG Ru-zhi, QU Ming-hao, ZHANG Ying, YAN Hui. Downconversion Materials Preparation and The Research of Conversion Efficiency in Pr3+, Yb3+ Co-doped YPO4[J]. Chinese Journal of Luminescence, 2012,(5): 486-491 DOI： 10.3788/fgxb20123305.0486.

摘要

采用固相反应法制备了Pr

共掺杂的YPO

下转换发光粉体

并在450 nm光激发条件下

研究了Yb

不同摩尔分数(0%

20%

30%)对转光效率的影响。结果表明:不同Yb

浓度的样品

其荧光峰强度不同

这可能是由于Pr

-Yb

之间Yb

浓度不同存在能量传递效率差异的原因。研究也发现了样品的下转换发光

其能量传递过程为:Pr

5/2

。荧光光谱测试结果表明

的最佳掺杂摩尔分数为2%。Pr

共掺杂的YPO

材料在提高太阳能电池光电转换效率方面具有潜在的应用。

Abstract

co-doped YPO

downconversion phosphor powders were prepared by solid state reaction. When excitation at 450 nm

the effects of different Yb

mole fractions (0%

20%

30%) on the conversion efficiency are studied. Results shows that because of the difference of energy transfer efficiency between Pr

and Yb

the samples with various Yb

doping concentrations have different fluorescence intensity. It is also found that the energy transfer process of the downconversion luminescence in samples is Pr

5/2

. From photoluminescence spectra measurement

the optimal doping mole fraction of Yb

is 2%. The results indicate that Pr

co-doped YPO

downconversion phosphor is a kind of potential material which may be used to improve the solar cell efficency.

关键词

Keywords

references

Tuerxun Aidilibike, Deng Kaimo, Chen Yonghu, et al. Highly efficient near-infrared quantum cutting in LaF3:Ho3+, Yb3+ for solar cells [J]. Chin. J. Lumin.(发光学报), 2011, 32(11):1133-1138 (in Chinese).[2] Trupke T, Green M A, Wurfel P. Improving solar cell efficiencies by down-conversion of high-energy photons [J]. J. Appl. Phys., 2002, 92(3):1668-1674.[3] Serrano D, Braud A, Doualan J L, et al. Ytterbium sensitization in KY3F10:Pr3+, Yb3+ for silicon solar cells efficiency enhancement [J]. Optical Materials, 2011, 33(7):1028-1031.[4] Richards B S. Luminescent layers for enhanced silicon solar cell performance:Down-conversion [J]. Solar Energy Materials and Solar Cells, 2006, 90(9):1189-1207.[5] van Wijngaarden J T, Scheidelaar S, Vlugt T J H, et al. Energy transfer mechanism for downconversion in the (Pr3+, Yb3+) couple [J]. Physical Review B, 2010, 81(15):155112-1-6.[6] Liu Chunxu, Wang Pengcheng, Luo Yongshi, et al. Tb3+-Er3+ couples as spectral converters in NaYF4 for GaAs solar cells [J]. Chin. J. Lumin.(发光学报), 2011, 32(11):1120-1125 (in Chinese).[7] Aarts L, van der Ende B, Reid M F, et al. Downconversion for solar cells in YF3:Pr3+, Yb3+ [J]. Spectroscopy Letters, 2010, 43(5):373-381.[8] Chen X B, Yang J G, Zhang C L, et al. Infrared quantum-cutting analysis of Er0.3Gd0.7VO4 crystal for solar cell application [J]. Acta Physica Sinica (物理学报), 2010, 59(11):8191-8199 (in Chinese).[9] Chen X P, Huang X Y, Zhang Q Y. Concentration-dependent near-infrared quantum cutting in NaYF4:Pr3+,Yb3+ phosphor [J]. J. Appl. Phys., 2009, 106(6):063518-1-3.[10] Yang G M, Zhou S M, Lin H, et al. Down-conversion near infrared emission in Pr3+,Yb3+ co-doped Y2O3 transparent ceramics [J]. Physica B: Condensed Matter, 2011, 406(19):3588-3591.[11] Vergeer P, Vlugt T J H, Kox M H F, et al. Quantum cutting by cooperative energy transfer in YbxY1-xPO4:Tb3+ [J]. Physical Review B, 2005, 71(1):014119-1-11.[12] Zhang Q Y, Yang C H, Pan Y X. Cooperative quantum cutting in one-dimensional (YbxGd1-x)Al3(BO3)4:Tb3+ nanorods [J]. Appl. Phys. Lett., 2007, 90(2):021107-1-3.[13] Zhang Q Y, Yang C H, Jiang Z H, et al. Concentration-dependent near-infrared quantum cutting in GdBO3:Tb3+, Yb3+ nanophosphors [J]. Appl. Phys. Lett., 2007, 90(6):061914-1-3.[14] Zhang Q Y, Yang C H, Jiang Z H. Cooperative downconversion in GdAl3(BO3)4:RE3+, Yb3+(RE=Pr, Tb, and Tm) [J]. Applied Physics Letters, 2007, 91(5):051903-1-3.[15] Xie L C, Wang Y H, Zhang H J. Near-infrared quantum cutting in YPO4:Yb3+, Tm3+ via cooperative energy transfer [J]. Appl. Phys. Lett., 2009, 94(6):061905-1-3.[16] Chen D Q, Wang Y S, Yu Y L, et al. Quantum cutting downconversion by cooperative energy transfer from Ce3+ to Yb3+ in borate glasses [J]. J. Appl. Phys., 2008, 104(11):8989-8994.[17] Liu X F, Qiao Y B, Dong G P, et al. Cooperative downconversion in Yb3+-RE3+(RE=Tm or Pr) codoped lanthanum borogermanate glasses [J]. Optics Letters, 2008, 33(23):2858-2860.[18] Ye S, Zhu B, Luo J, et al. Enhanced cooperative quantum cutting in Tm3+-Yb3+ codoped glass ceramics containing LaF3 nanocrystals [J]. Optics Express, 2008, 16(12):8989-8994.[19] Ye S, Zhu B, Chen J X, et al. Infrared quantum cutting in Tb3+, Yb3+ codoped transparent glass ceramics containing CaF2 nanocrystals [J]. Appl. Phys. Lett., 2008, 92(14):141112-1-3.[20] Wang Y S, Chen D Q, Yu Y L, et al. Near-infrared quantum cutting in transparent nanostructured glass ceramics [J]. Optics Letters, 2008, 33(16):1884-1886.[21] Chen D Q, Yu Y L, Wang Y S, et al. Cooperative energy transfer up-conversion and quantum cutting down-conversion in Yb3+:TbF3 nanocrystals embedded glass ceramics [J]. J. Phys. Chem. C, 2009, 113(16):6406-6410.[22] Lin H, Chen D Q, Yu Y L, et al. Near-infrared quantum cutting in Ho3+/Yb3+ codoped nanostructured glass ceramic [J]. Optics Letters, 2011, 36(6):876-878.[23] Chen D Q, Yu Y L, Lin H, et al. Ultraviolet-blue to near-infrared downconversion of Nd3+-Yb3+ couple [J]. Optics Letters, 2010, 35(2):220-222.[24] Lin H, Zhou S M, Teng H, et al. Near infrared quantum cutting in heavy Yb doped Ce0.03Yb3xY(2.97-3x)Al5O12 transparent ceramics for crystalline silicon solar cells [J]. J. Appl. Phys., 2010, 107(4):876-878.[25] Lin H, Zhou S M, Hou X R, et al. Down-conversion from blue to near infrared in Tm3+-Yb3+ codoped Y2O3 transparent ceramics [J]. IEEE Photonics Technology Letters, 2010, 22(12):866-868.[26] Huang X Y, Zhang Q Y. Efficient near-infrared down conversion in Zn2SiO4:Tb3+, Yb3+ thin-films [J]. J. Appl. Phys., 2009, 105(5):053521-1-4.[27] de Sousa P C, Serra O A. Reverse microemulsion synthesis, structure, and luminescence of nanosized REPO4:Ln3+(RE=La, Y, Gd, or Yb, and Ln=Eu, Tm, or Er) [J]. J. Phys. Chem. C, 2011, 115(3):636-646.[28] Capelletti R, Baraldi A, Buffagni E, et al. Optical spectroscopy of YPO4 single crystals doped with Ho3+ [J]. Spectroscopy Letters, 2010, 43(5):382-388.[29] de Sousa P C, Serra O A. Red, green, and blue lanthanum phosphate phosphors obtained via surfactant-control led hydrothermal synthesis [J]. J. Lumin., 2009, 129(12):1664-1668.[30] Moine B, Hachani S, Ferid M. Energy transfer between Sm3+ and Er3+ in orthophosphate YPO4 [J]. J. Lumin., 2011, 131(10):2110-2115.[31] Lian R, Yin M, Zhang W P, et al. Chemical preparation, structure analysis and spectrum characteristics of YPO4:Pr3+ nanocrystal [J]. Chin. J. Lumin.(发光学报), 1999, 20(2):102-105 (in Chinese).[32] Lecointre A, Bessiere A, Bos A J J, et al. Designing a red persistent luminescence phosphor:The example of YPO4:Pr3+, Ln3+ (Ln=Nd, Er, Ho, Dy) [J]. J. Phys. Chem. C, 2011, 115(10):4217-4227.[33] Yuan J L, Zeng X Y, Zhao J T, et al. Energy transfer mechanisms in Tb3+, Yb3+ codoped Y2O3 downconversion phosphor [J]. J. Phys. D: Appl. Phys., 2008, 41(10):105406-1-6.[34] Chen H T, Yin M, Lian R, et al. Luminescence dependence upon concentration and temperature in YPO4:Pr3+ [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2001, 21(2):151-154 (in Chinese).

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Review of Advances in Large-area Perovskite Solar Cell Thin-film Fabrication Techniques

Near Infrared Optical Thermometry Along with Photothermal Conversion Ability Realized in BaY₂O₄∶Nd³⁺

Passivation of Perovskite Buried-interface Using Phenethylamine for Enhanced Solar Cell Performance

Advances in Rare Earth Doped Lead Halide Perovskite Luminescence, Optoelectronic Materials and Devices

Temperature Sensing Properties in NaScF₄∶Yb³⁺/Er³⁺ Nanoparticles

Related Author

XU Zhentong

LIN Jie

HUANG Jingsong

JIANG Chengming

XIANG Guotao

DING Yongxi

ZHANG Yu

LIU Tao

Related Institution

Oxford Suzhou Centre for Advanced Research （OSCAR）， University of Oxford

College of Mechanical Engineering， Dalian University of Technology

Department of Mathematics and Physics， Chongqing University of Posts and Telecommunications

State Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials （IAM）， Nanjing University of Posts & Telecommunications

College of Electronic Science and Engineering， Jilin University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰