ZHAO Jun-wei, SHAN Han, SHI Dong-mei, ZHAO Ying-gang, KONG Xiang-gui. Solvothermal Synthesis of Water Soluble B-PEI/NaYF<sub>4</sub>∶Yb<sup>3+</sup>, Er<sup>3+</sup> Nanoparticles with Upconversion Luminescence[J]. Chinese Journal of Luminescence, 2012,33(3): 253-257
ZHAO Jun-wei, SHAN Han, SHI Dong-mei, ZHAO Ying-gang, KONG Xiang-gui. Solvothermal Synthesis of Water Soluble B-PEI/NaYF<sub>4</sub>∶Yb<sup>3+</sup>, Er<sup>3+</sup> Nanoparticles with Upconversion Luminescence[J]. Chinese Journal of Luminescence, 2012,33(3): 253-257 DOI: 10.3788/fgxb20123303.0253.
Solvothermal Synthesis of Water Soluble B-PEI/NaYF4∶Yb3+, Er3+ Nanoparticles with Upconversion Luminescence
nanoparticles with size about 45 nm were successfully prepared via a solvothermal method in water and diethylene glycol using B-PEI as surfactant. The strong upconversion luminescence from the sample can be observed under excitation of 980 nm diode laser at room temperature. The amino groups of B-PEI existing on the nanoparticles can be used for attachment of biomolecules. The cell viability experiments show that the samples have lower cell toxicity. The results presented in this study provide a new insight for the upconversion luminescence nanoparticles in the biomedical applications.
关键词
Keywords
references
Haase M, Schfer H. Upconverting nanoparticles [J]. Angew. Chem. Int. Ed., 2011, 50(26):5808-5829.[2] Lu Zhihua, Chen Huan, He Chunfeng, et al. Synthesis of water soluble upconversion NaYF4∶Yb3+,Er3+ nanoparticals using polyvinylpyrrolidone as surfactant and their biological compatibility [J]. Chin. J. Lumin. (发光学报), 2011, 32(10):993-997 (in Chinese).[3] Wang F, Liu X G. Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals [J]. Chem. Soc. Rev., 2009, 38(4):976-989.[4] Shen J, Sun L D, Yan C H. Luminescent rare earth nanomaterials for bioprobe applications [J]. Dalton Trans., 2008,42:5687-5697.[5] Wang F, Banerjee D, Liu Y S, et al. Upconversion nanoparticles in biological labeling, imaging, and therapy [J]. Analyst, 2010, 135(8):1839-1854.[6] Li C X, Lin J. Rare earth fluoride nano-/microcrystals: Synthesis, surface modification and application [J]. J. Mater. Chem., 2010, 20(33):6831-6847.[7] Wang M, Abbineni G, Clevenger A, et al. Upconversion nanoparticles: Synthesis, surface modification and biological applications [J]. Nanomedicine: Nanotechnology, Biology and Medicine, 2011, 7(6):710-729.[8] Auzel F. Upconversion and anti-stokes processes with f and d ions in solids [J]. Chem. Rev., 2004, 104(1):139-173.[9] Suyver J F, Grimm J, Van Veen M K, et al. Upconversion spectroscopy and properties of NaYF4 doped with Er3+ , Tm3+ and/or Yb3+ [J]. J. Lumin., 2006, 117(1):1-12.[10] Mai H X, Zhang Y W, Si R, et al. High-quality sodium rare-earth fluoride nanocrystals: Controlled synthesis and optical properties [J]. J. Am. Chem. Soc., 2006, 128(19):6426-6436.[11] Chen Zhe, Liu Zhenyu, Zhao Dan, et al. Effect of reactants concentration on NaYF4∶Yb3+,Tm3+ crystalline phase [J]. Chin. J. Lumin. (发光学报), 2011, 32(9):853-857 (in Chinese).[12] Zhao Junwei, Shan Han, Jia Tiekun, et al. Effect of high temperature annealing in nitrogen on the upconversion luminescence of NaYF4∶Yb3+, Er3+ nanoparticles [J]. Chin. J. Lumin. (发光学报), 2011, 32(12):1227-1232 (in Chinese).[13] Zhao Junwei, Kong Xianggui. AEP-assisted hydrothermal synthesis and upconversion luminescence of NaYF4∶Yb3+, Er3+ nanocrystals [J]. Chin. J. Lumin. (发光学报), 2011, 32(7):675-679 (in Chinese).[14] Wang F, Chatterjee D K, Li Z Q, et al. Synthesis of polyethylenimine/NaYF4 nanoparticles with upconversion fluorescence [J]. Nanotechnology, 2006, 17(23):5786-5791.[15] Lin-Vien D, Colthup N B, Fateley W G, et al. The Handbook of IR and Raman Characteristic Frequencies of Organic Molecules [M]. New York, USA: Academic Press, 1991:45-59.[16] Socrates G. Infrared Characteristic Group Frequencies [M]. Chichester, UK: Wiley, 2001:50-81.[17] Babacan S, Pivamik P, Leteher S, et al. Evaluation of antibody immobilization methods for piezoelectric biosensor application [J]. Biosens. Bioelectron., 2000, 15(11-12):615- 621.[18] Ballulekar R, Ayyangar N R, Ponrathnam S. Polyethyleneimine in immobilization of bioeatalysts [J]. Enzyme. Microb. Technol., 1991, 13(11):858-868.[19] Bakef A, Saltik M, Lehrmann H, et al. Polyethylenimine(PEI) is a simple, inexpensive and effective reagent for condensing and linking plasmid DNA to adenovirus for gene delivery [J]. Gene. Ther., 1997, 4(8):773-782.[20] Kircheis R, Wightman L, Wagner E. Design and gene delivery activity of modified polyethylenimines [J]. Adv. Drug. Deliv. Rev., 2001, 53(3):341-358.[21] Lvov Y, Ariga K, Ichinose I, et al. Assembly of multicomponent protein films by means of electrostatic layer-by-layer adsorption [J]. J. Am. Chem. Soc., 1995, 117(22):6117-6123.[22] Boussif O, Lezoualeh F, Zanta M A, et al. A versatile vector for gene and oligonucleotide transfer into cells in culture and in-vivo-Polyethylenimine [J]. Proc. Natl. Acad. Sci. USA, 1995, 92(16):7297-7301.