Luminescent Properties of Er3+/Yb3+ Codoped Tellurite Glass Ceramics

ZHANG Ming; YU Hua; HU Nan; ZHAO Li-juan

doi:10.3788/fgxb20113208.0761

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Luminescent Properties of Er³⁺/Yb³⁺ Codoped Tellurite Glass Ceramics

paper | 更新时间：2020-08-12

- Luminescent Properties of Er³⁺/Yb³⁺ Codoped Tellurite Glass Ceramics
- Chinese Journal of Luminescence Vol. 32, Issue 8, Pages: 761-765(2011)
- 作者机构：
  
  1. 南开大学物理科学学院天津,300071
  2. 南开大学弱光非线性光子学教育部重点实验室天津,300457
  3. 南开大学泰达应用物理学院天津,300457
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20113208.0761
  CLC： O482.31
- Received：01 March 2011，
  
  Revised：17 June 2011，
  
  Published Online：22 August 2011，
  
  Published：22 August 2011
- 稿件说明：
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张铭, 余华, 胡男, 赵丽娟. Er3+/Yb3+ 共掺碲酸盐玻璃陶瓷的光谱性质[J]. 发光学报, 2011,32(8): 761-765

ZHANG Ming, YU Hua, HU Nan, ZHAO Li-juan. Luminescent Properties of Er3+/Yb3+ Codoped Tellurite Glass Ceramics[J]. Chinese Journal of Luminescence, 2011,32(8): 761-765
张铭, 余华, 胡男, 赵丽娟. Er3+/Yb3+ 共掺碲酸盐玻璃陶瓷的光谱性质[J]. 发光学报, 2011,32(8): 761-765 DOI： 10.3788/fgxb20113208.0761.

ZHANG Ming, YU Hua, HU Nan, ZHAO Li-juan. Luminescent Properties of Er3+/Yb3+ Codoped Tellurite Glass Ceramics[J]. Chinese Journal of Luminescence, 2011,32(8): 761-765 DOI： 10.3788/fgxb20113208.0761.

摘要

利用熔融淬火法在900 ℃下成功制备出原料比为60TeO

-10CaF

-25H

-1Er

-4Yb

的Er

/Yb

共掺杂透明玻璃陶瓷。利用XRD和TEM验证了玻璃陶瓷中存在Er

纳米微晶

并由Raman测试得知其声子能量为886 cm

-1

。分别测量了其上转换和下转换发射谱

发现不同激发光源下的发光过程中红、绿光发射强度有明显不同

并分别对其能量传递过程进行了讨论。

Abstract

Optically transparent Er

/Yb

codoped glass ceramics based on the system 60TeO

-10CaF

-25H

-1Er

-4Yb

have been successfully prepared by melt-quenching method at 900 ℃.The Er

nanocrystals

whose phonon energy was 886 cm

-1

by Raman measurement

were characterized by XRD and TEM in the tellurite glass ceramics. Both up-conversion and down-conversion emission spectra were measured. The red and green emissions have different luminescent processes under different excitation sources. The energy transfer processes were discussed individually.

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Keywords

references

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