Influence of Particle's Deformation on The Optical Properties of Silica Opal Photonic Crystals

CUI Nai-di; LIANG Jing-qiu; LIANG Zhong-zhu; ZHOU Jian-wei; WANG Wei-biao

doi:10.3788/fgxb20113206.0542

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Influence of Particle's Deformation on The Optical Properties of Silica Opal Photonic Crystals

paper | 更新时间：2020-08-12

- Influence of Particle's Deformation on The Optical Properties of Silica Opal Photonic Crystals
- Chinese Journal of Luminescence Vol. 32, Issue 6, Pages: 542-549(2011)
- 作者机构：
  
  1. 中国科学院研究生院北京,100049
  2. 中国科学院长春光学精密机械与物理研究所应用光学国家重点实验室,吉林长春,130022
- 作者简介：
- 基金信息：
- DOI：10.3788/fgxb20113206.0542
  CLC： O431.1
- Received：25 April 2011，
  
  Revised：15 May 2011，
  
  Published Online：22 June 2011，
  
  Published：22 June 2011
- 稿件说明：
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崔乃迪, 梁静秋, 梁中翥, 周建伟, 王维彪. 二氧化硅蛋白石光子晶体中粒子重构对光学性质的影响[J]. 发光学报, 2011,32(6): 542-549

CUI Nai-di, LIANG Jing-qiu, LIANG Zhong-zhu, ZHOU Jian-wei, WANG Wei-biao. Influence of Particle's Deformation on The Optical Properties of Silica Opal Photonic Crystals[J]. Chinese Journal of Luminescence, 2011,32(6): 542-549
崔乃迪, 梁静秋, 梁中翥, 周建伟, 王维彪. 二氧化硅蛋白石光子晶体中粒子重构对光学性质的影响[J]. 发光学报, 2011,32(6): 542-549 DOI： 10.3788/fgxb20113206.0542.

CUI Nai-di, LIANG Jing-qiu, LIANG Zhong-zhu, ZHOU Jian-wei, WANG Wei-biao. Influence of Particle's Deformation on The Optical Properties of Silica Opal Photonic Crystals[J]. Chinese Journal of Luminescence, 2011,32(6): 542-549 DOI： 10.3788/fgxb20113206.0542.

摘要

使用自组装法制备了蛋白石结构二氧化硅纳米球三维光子晶体

并对样品在150

300

450 ℃温度下进行了热处理。随热处理温度的升高

光子晶体禁带中心波长出现22.5 nm的蓝移

且禁带宽度变窄。对于在450 ℃热处理的样品

其测量的禁带中心波长为572.5 nm

与理论计算结果有较大差异。引起样品光学特性变化的原因是热处理后二氧化硅球体形变和重构。进一步分析了小球形变对样品光学特性的影响

根据实验结果

修正了计算模型。利用修正后的模型计算样品禁带中心波长为558nm

和实验结果符合良好。

Abstract

The opal photonic crystals were fabricated with silica colloidal particles. These opal photonic crystal samples were annealed at 150

300

450 ℃ separately. For the photonic crystals annealed at 450 ℃

the central wavelength of photonic band gap(PBG) was measured at 572.5 nm

which was greatly different from the calculated result at 605 nm. In addition

the samples showed a blue shift for 22.5 nm and a reduction of the photonic band gap width upon increasing the annealing temperature. The shrink and deformation of silica colloidal particles were observed by SEM. The influence mechanism of the deformation was analyzed quantitatively

and the theoretical model was amended. The central wavelength of PBG re-calculated with the amended dodecahedron model was 558 nm

which fit the measured result much better than that calculated with the old sphere model. The new dodecahedron model provides a way to analyze the optical properties of the deformed opal PCs in theory

and shall be of significant value on the fabrication and application of photonic crystals devices.

关键词

Keywords

references

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