Preparation of Mn<sup>2+</sup> Doping Water-soluble NaBiF<sub>4</sub>: Yb/Er Microcrystals and Their Upconversion Luminescence Properties

Peng ZHANG; Wan-ying XIE; Rui-liang ZUO; Zong-ru XIE; Guo-cui QI; Li-li WANG; Xiu-ju YIN

doi:10.37188/fgxb20204109.1122

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Preparation of Mn²⁺ Doping Water-soluble NaBiF₄: Yb/Er Microcrystals and Their Upconversion Luminescence Properties

Synthesis and Properties of Materials | 更新时间：2020-09-10

- Preparation of Mn²⁺ Doping Water-soluble NaBiF₄: Yb/Er Microcrystals and Their Upconversion Luminescence Properties
- Chinese Journal of Luminescence Vol. 41, Issue 9, Pages: 1122-1127(2020)
- 作者机构：
  
  1.河池学院化学与生物工程学院, 广西河池 546300
  2.长春工业大学材料科学与工程学院, 吉林长春 130012
- 作者简介：
- 基金信息：
  
  Guangxi Colleges and Universities Young and Middle-aged Teachers Basic Ability Impro
- DOI：10.37188/fgxb20204109.1122
  CLC： O482.31
- Received：01 July 2020，
  
  Accepted：12 July 2020，
  
  Published：2020-09
- 稿件说明：
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Peng ZHANG, Wan-ying XIE, Rui-liang ZUO, et al. Preparation of Mn²⁺ Doping Water-soluble NaBiF₄: Yb/Er Microcrystals and Their Upconversion Luminescence Properties[J]. Chinese journal of luminescence, 2020, 41(9): 1122-1127.
DOI：

Peng ZHANG, Wan-ying XIE, Rui-liang ZUO, et al. Preparation of Mn²⁺ Doping Water-soluble NaBiF₄: Yb/Er Microcrystals and Their Upconversion Luminescence Properties[J]. Chinese journal of luminescence, 2020, 41(9): 1122-1127. DOI： 10.37188/fgxb20204109.1122.

摘要

NaBiF

作为一种新型的上转换发光基质材料，具有优异的发光性能。本文以聚乙烯吡咯烷酮（PVP）作为表面活性剂，通过溶剂热法成功制备出水溶性NaBiF

:Yb

/Er

/Mn

上转换微米晶，并对其晶相、形貌及发光性能进行了表征。在980 nm激发光条件下，NaBiF

:Yb

/Er

/Mn

可发射出强烈的绿色发光，且发光强度随Mn

掺杂浓度的提高呈现先增强后减弱的趋势，表现出优异的上转换发光性能。同时，NaBiF

:Er

/Yb

/Mn

上转换发光对温度具有良好的依赖性，有望成为潜在的温度传感器材料。

Abstract

As a new type of upconversion matrix

NaBiF

has been found with excellent luminescence properties. In this paper

polyvinyl pyrrolidone(PVP) was used as the surfactant

and the water-soluble NaBiF

:Er

/Yb

/Mn

particles were successfully prepared by a solvothermal synthesis. The crystal phase

morphology and luminescence properties of the microcrystals were studied. Under the excitation of 980 nm laser

NaBiF

:Er

/Yb

/Mn

microcrystals show excellent upconversion luminescence(UCL). The upconversion emission intensity increased at first and then decreased with the increase of the dopant concentrations of Mn

ions. Moreover

the temperature-dependent UCL properties of NaBiF

:Yb

/Er

/Mn

were investigated systematically under 980 nm excitation. The microcrystals could be a potential candidate for sensitive temperature sensor.

关键词

Keywords

references

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Preparation of Mn2+ Doping Water-soluble NaBiF4: Yb/Er Microcrystals and Their Upconversion Luminescence Properties

DOI：10.37188/fgxb20204109.1122

摘要

Abstract

关键词

Keywords

references

Preparation of Mn²⁺ Doping Water-soluble NaBiF₄: Yb/Er Microcrystals and Their Upconversion Luminescence Properties