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Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing
增强出版- Chinese Journal of Luminescence Vol. 43, Issue 2, Pages: 182-191(2022)
- 作者机构：
. 山东大学 晶体材料国家重点实验室，山东 济南 250100
- 作者简介：
- 基金信息：National Natural Science Foundation of China(62105181);Postdoctoral Applied Research in Qingdao
DOI：10.37188/CJL.20210345
CLC： O482.31Received：04 November 2021，
Revised：2021-11-22，
Published：2022-02
- 稿件说明：
移动端阅览
Na ZHANG, Yang LI, Yan-ru YIN, et al. Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing[J]. Chinese Journal of Luminescence, 2022, 43(2): 182-191.
Na ZHANG, Yang LI, Yan-ru YIN, et al. Down-conversion Luminescence Performance of Dy3+ Doped Lu2O3 and Y2O3 Single Crystal Fibers for Temperature Sensing[J]. Chinese Journal of Luminescence, 2022, 43(2): 182-191. DOI： 10.37188/CJL.20210345.
摘要
稀土倍半氧化物单晶光纤材料凭借超高的熔点(~2 400 ℃)、稳定的物化性能以及灵活的结构被认为是极具潜力的高温传感介质。本文采用激光加热基座(LHPG)法，成功生长了透明无开裂Dy
3+
离子掺杂的倍半氧化物单晶光纤Lu
2
O
3
和Y
2
O
3
。依据Dy
3+
离子的
4
I
15/2
和
4
F
9/2
能级为一对热耦合能级对(TCLs)，测试得到了430~520 nm波长范围内的下转换荧光光谱。荧光强度比(FIR)结果显示，晶体在298~673 K温度范围内的荧光强度具有良好的温度相关性。其中Dy∶Lu
2
O
3
在该范围内的最大相对灵敏度和绝对灵敏度分别为0.97%·K
-1
(315 K)和1.62×10
-4
K
-1
(673 K)，展现出更为优异的温度传感性能。
Abstract
Rare earth sesquioxide single crystal fibers(SCFs) are considered to be potential high-temperature sensing media due to their ultra-high melting point(~2 400 ℃)
stable physical and chemical properties and flexible structure. The transparent and crack-free Dy
3+
doped Lu
2
O
3
and Y
2
O
3
single crystal fibers(SCFs) were successfully grown by laser heated pedestal growth(LHPG) method. According to the
4
I
15/2
and
4
F
9/2
energy levels of Dy
3+
ion as a pair of thermally coupled energy levels(TCLs)
the down-conversion luminescence in the wavelength range of 430-520 nm was obtained. The fluorescence intensity ratio(FIR) measurement technique shows that the Dy
3+
doped Lu
2
O
3
and Y
2
O
3
crystals have a good temperature dependence in the temperature range of 298-673 K. The maximum relative sensitivity and absolute sensitivity of Dy∶Lu
2
O
3
in this range are 0.97%·K
-1
(315 K) and 1.62×10
-4
K
-1
(673 K)
respectively
showing more excellent temperature sensing performance.
关键词
Keywords
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