Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN<sub>3</sub>∶Eu Composite Phosphor Ceramics

Xing-lin PENG; Shu-xing LI; Ao-chen DU; Zi-qiu CHENG; Xiu-min YAO; Zheng-ren HUANG; Rong-jun XIE; Xue-jian LIU

doi:10.37188/CJL.20210146

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Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics

Invited Paper | 更新时间：2021-10-17

- Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 10, Pages: 1502-1509(2021)
- 作者机构：
  
  1.中国科学院　上海硅酸盐研究所，上海　 200050
  2.中国科学院大学　材料科学与光电技术学院，北京　 100049
  3.厦门大学　材料学院，福建　厦门　 361005
- 作者简介：
- 基金信息：
  
  National Key R&D Program of China(2018YFB0406700)
- DOI：10.37188/CJL.20210146
  CLC： TQ174
- Received：22 April 2021，
  
  Revised：2021-05-11，
  
  Published：01 October 2021
- 稿件说明：
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Xing-lin PENG, Shu-xing LI, Ao-chen DU, et al. Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics[J]. Chinese Journal of Luminescence, 2021, 42(10): 1502-1509.
DOI：

Xing-lin PENG, Shu-xing LI, Ao-chen DU, et al. Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics[J]. Chinese Journal of Luminescence, 2021, 42(10): 1502-1509. DOI： 10.37188/CJL.20210146.

摘要

目前报道的高热导AlN-CaAlSiN

∶Eu红色复相荧光陶瓷由于放电等离子体烧结(SPS)产生的碳污染问题导致发光性能难以提高。本研究工作提出了一种减少氮化物荧光陶瓷碳污染的有效方法，即采用热等静压(HIP)在N

气氛中处理SPS烧结的样品。实验表明，经过HIP处理后样品的发光强度和量子效率最高均提高了一倍左右，光通量提高了51%，发光饱和阈值提高了15%以上。其中，性能最佳的样品在入射激光功率高达15 W时依然保持完好且未发生发光饱和，光通量高达197 lm。本研究工作利用HIP处理制备出具有优异发光性能和极高发光饱和阈值的红色荧光陶瓷，促进了大功率激光照明领域的发展。

Abstract

The previously reported highly thermal conductive red-emitting AlN-CaAlSiN

∶Eu composite phosphor ceramic is difficult to improve the luminescence performance due to the carbon contamination problem caused by spark plasma sintering(SPS). In this paper

hot isostatic pressing(HIP) post-treatment is used to prepare red-emitting phosphor ceramics with excellent luminescence performance and extremely high saturation threshold

which promotes the development of high-power laser lighting. The SPS sintered samples were treated by HIP in N

atmosphere. The experimental results show that the luminescence intensity and quantum efficiency of the samples are doubled after HIP post-treatment

the luminous flux is increased by 51%

and the saturation threshold is increased by more than 15%. The sample with the best performance remains intact without luminance saturation when the incident laser power is as high as 15 W

and the luminous flux is up to 197 lm.

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references

JR WIERER J J , TSAO J Y , SIZOV D S . Comparison between blue lasers and light-emitting diodes for future solid-state lighting [J]. Laser Photon. Rev. , 2013 , 7 ( 6 ): 963 - 993 .

LI S X , WANG L , HIROSAKI N , et al . Color conversion materials for high-brightness laser-driven solid-state lighting [J]. Laser Photon. Rev. , 2018 , 12 ( 12 ): 1800173-1-29 .

KIM Y H , VISWANATH N S M , UNITHRATTIL S , et al . Review-phosphor plates for high-power LED applications: challenges and opportunities toward perfect lighting [J]. ECS J. Solid State Sci. Technol. , 2018 , 7 ( 1 ): R3134 - R3147 .

彭星淋 , 李淑星 , 刘泽华 , 等 . 大功率固态照明用荧光陶瓷研究进展 [J]. 无机材料学报 , 2021 , 36 ( 8 ): 807 - 819 .

PENG X L , LI S X , LIU Z H , et al . Phosphor ceramics for high-power solid-state lighting [J]. J. Inorg. Mater. , 2021 , 36 ( 8 ): 807 - 819 . (in Chinese)

胡盼 , 丁慧 , 刘永福 , 等 . YAG∶Ce3+在激光照明应用中的研究进展 [J]. 发光学报 , 2020 , 41 ( 12 ): 1504 - 1528 .

HU P , DING H , LIU Y F , et al . Recent progress of YAG∶Ce3+ for white laser diode lighting application [J]. Chin. J. Lumin. , 2020 , 41 ( 12 ): 1504 - 1528 . (in Chinese)

李江 , 李万圆 , 刘欣 , 等 . 固态照明/显示用荧光陶瓷研究进展 [J]. 发光学报 , 2021 , 42 ( 5 ): 580 - 604 .

LI J , LI W Y , LIU X , et al . Research progress on phosphor ceramics for solid-state lighting/display [J]. Chin. J. Lumin. , 2021 , 42 ( 5 ): 580 - 604 . (in Chinese)

YAO Q , HU P , SUN P , et al . YAG∶Ce3+ transparent ceramic phosphors brighten the next-generation laser-driven lighting [J]. Adv. Mater. , 2020 , 32 ( 19 ): 1907888-1-7 .

ZHENG P , LI S X , WEI R , et al . Unique design strategy for laser-driven color converters enabling superhigh-luminance and high-directionality white light [J]. Laser Photon. Rev. , 2019 , 13 ( 10 ): 1900147-1-10 .

ZHU Q Q , WANG X J , WANG L , et al . β-Sialon∶Eu phosphor-in-glass: a robust green color converter for high power blue laser lighting [J]. J. Mater. Chem. C , 2015 , 3 ( 41 ): 10761 - 10766 .

YU J B , SI S C , LIU Y , et al . High-power laser-driven phosphor-in-glass for excellently high conversion efficiency white light generation for special illumination or display backlighting [J]. J. Mater. Chem. C , 2018 , 6 ( 30 ): 8212 - 8218 .

ZHENG P , LI S X , WANG L , et al . Unique color converter architecture enabling phosphor-in-glass(PiG) films suitable for high-power and high-luminance laser-driven white lighting [J]. ACS Appl. Mater. Interfaces , 2018 , 10 ( 17 ): 14930 - 14940 .

YOU S H , LI S X , ZHENG P , et al . A thermally robust La3Si6N11∶Ce-in-glass film for high-brightness blue-laser-driven solid state lighting [J]. Laser Photon. Rev. , 2019 , 13 ( 2 ): 1800216-1-10 .

XU J , THORSETH A , XU C , et al . Investigation of laser-induced luminescence saturation in a single-crystal YAG∶Ce phosphor: towards unique architecture, high saturation threshold, and high-brightness laser-driven white lighting [J]. J. Lumin. , 2019 , 212 : 279 - 285 .

CANTORE M , PFAFF N , FARRELL R M , et al . High luminous flux from single crystal phosphor-converted laser-based white lighting system [J]. Opt. Express , 2016 , 24 ( 2 ): A215 - A221 .

SUN Y , ZHOU K , FENG M X , et al . Room-temperature continuous-wave electrically pumped InGaN/GaN quantum well blue laser diode directly grown on Si [J]. Light Sci. Appl. , 2018 , 7 ( 1 ): 13-1-7 .

YANG J , ZHAO D G , JIANG D S , et al . Suppression the formation of V-pits in InGaN/GaN multi-quantum well growth and its effect on the performance of GaN based laser diodes [J]. J. Alloys Compd. , 2020 , 822 : 153571 .

LIU X , QIAN X L , HU Z W , et al . Al2O3-Ce∶Gd YAG composite ceramic phosphors for high-power white light-emitting-diode applications [J]. J. Eur. Ceram. Soc. , 2019 , 39 ( 6 ): 2149 - 2154 .

LIU S , SUN P , LIU Y F , et al . Warm white light with a high color-rendering index from a single Gd3Al4GaO12∶Ce3+ transparent ceramic for high-power LEDs and LDs [J]. ACS Appl. Mater. Interfaces , 2019 , 11 ( 2 ): 2130 - 2139 .

LING J R , ZHOU Y F , XU W T , et al . Red-emitting YAG∶Ce, Mn transparent ceramics for warm WLEDs application [J]. J. Adv. Ceram. , 2020 , 9 ( 1 ): 45 - 54 .

WANG J C , TANG X Y , ZHENG P , et al . Thermally self-managing YAG∶Ce-Al2O3 color converters enabling high-brightness laser-driven solid state lighting in a transmissive configuration [J]. J. Mater. Chem. C , 2019 , 7 ( 13 ): 3901 - 3908 .

XU Y R , LI S X , ZHENG P , et al . A search for extra-high brightness laser-driven color converters by investigating thermally-induced luminance saturation [J]. J. Mater. Chem. C , 2019 , 7 ( 37 ): 11449 - 11456 .

PENG X L , LI S X , LIU Z H , et al . Highly thermal conductive red-emitting AlN-CaAlSiN3∶Eu2+ composite phosphor ceramics for high-power laser-driven lighting [J]. J. Eur. Ceram. Soc. , 2021 , 41 ( 11 ): 5650 - 5657 .

ZHANG Y L , HU S , WANG Z J , et al . Pore-existing Lu3Al5O12∶Ce ceramic phosphor: an efficient green color converter for laser light source [J]. J. Lumin. , 2018 , 197 : 331 - 334 .

LI S X , ZHU Q Q , WANG L , et al . CaAlSiN3∶Eu2+ translucent ceramic: a promising robust and efficient red color converter for solid state laser displays and lighting [J]. J. Mater. Chm. C , 2016 , 4 ( 35 ): 8197 - 8205 .

MORITA K , KIM B N , YOSHIDA H , et al . Distribution of carbon contamination in oxide ceramics occurring during spark-plasma-sintering(SPS) processing: Ⅱ-effect of SPS and loading temperatures [J]. J. Eur. Ceram. Soc. , 2018 , 38 ( 6 ): 2596 - 2604 .

MORITA K , KIM B N , YOSHIDA H , et al . Distribution of carbon contamination in MgAl2O4 spinel occurring during spark-plasma-sintering(SPS) processing: Ⅰ-effect of heating rate and post-annealing [J]. J. Eur. Ceram. Soc. , 2018 , 38 ( 6 ): 2588 - 2595 .

ZHU Q Q , YANG P F , WANG Z Y , et al . Additive-free Y2O3∶Eu3+ red-emitting transparent ceramic with superior thermal conductivity for high-power UV LEDs and UV LDs [J]. J. Eur. Ceram. Soc. , 2020 , 40 ( 6 ): 2426 - 2431 .

LI S X , TANG D M , TIAN Z F , et al . New insights into the microstructure of translucent CaAlSiN3∶Eu2+ phosphor ceramics for solid-state laser lighting [J]. J. Mater. Chem. C , 2017 , 5 ( 5 ): 1042 - 1051 .

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Related Author

Xing-lin PENG

Shu-Xing LI

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Zi-qiu Cheng

Xiu-min YAO

Zheng-ren HUANG

Rong-Jun XIE

Xue-jian LIU

Related Institution

College of Materials， Xiamen University

College of Materials Science and Opto-Electronic Technology， University of Chinese Academy of Sciences

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Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN3∶Eu Composite Phosphor Ceramics

DOI：10.37188/CJL.20210146

摘要

Abstract

关键词

Keywords

references

Hot Isostatic Pressing Post-treatment and Performance of Red-emitting AlN-CaAlSiN₃∶Eu Composite Phosphor Ceramics