Enhanced Luminescence of BaSi2O2N2∶Eu2+ By Co-doping Er3+

Xue-qing LIU; Shuai HE; Liang-liang ZHANG; Guo-hui PAN; Hua-jun WU; Hao WU; Jia-hua ZHANG

doi:10.37188/CJL.20210145

您当前的位置：

首页 >

文章列表页 >

Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺

Cover Story | 更新时间：2021-09-13

- Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺
  增强出版
- Chinese Journal of Luminescence Vol. 42, Issue 9, Pages: 1323-1330(2021)
- 作者机构：
  
  1.中国科学院长春光学精密机械与物理研究所　发光学及应用国家重点实验室，吉林　长春　 130033
  2.中国科学院大学，北京　 100049
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China(11874055;51772286;11974346;11904361);National Key R&D Program of China(2016YFB0400605;2016YFB0701003;2017YFB0403104);Youth Innovation Promotion Association CAS(2020222);Jilin Province Young and Middle-aged Science and Technology Innovation Leading Talents and Team Projects(20190101001JH);The Opening Project Key Laboratory of Transparent Opto-functional Inorganic Material,Chinese Academy of Sciences
- DOI：10.37188/CJL.20210145
  CLC： O482.31;O469
- Received：23 April 2021，
  
  Revised：30 April 2021，
  
  Published：01 September 2021
- 稿件说明：
移动端阅览
Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese journal of luminescence, 2021, 42(9): 1323-1330.
DOI：

Xue-qing LIU, Shuai HE, Liang-liang ZHANG, et al. Enhanced Luminescence of BaSi₂O₂N₂∶Eu²⁺ By Co-doping Er³⁺[J]. Chinese journal of luminescence, 2021, 42(9): 1323-1330. DOI： 10.37188/CJL.20210145.

摘要

针对Er

共掺增强BaSi

∶Eu

发光效果的内在差异和可能机理进行了研究。通过XRD测试展示了共掺下的晶体结构，分析确认了样品纯度以及生长差异；为进一步研究差异的来源，监控了不同价态掺杂离子的发射光谱，对随Er

含量变化的发射光谱规律性变化进行展示，进而分析得出Er

共掺增强发光的内部物理机理是控制择优取向和对价态进行定向竞争调节；从发光体应用场景的温度范围需求进行了温度特性测试，展示了温度变化下的发射光谱变化。这项研究为调控发光强度、提高量子效率的工作提供了新的思路。

Abstract

This work has studied the effect of co-doping Er

enhanced BaSi

∶Eu

luminescence

mainly focusing on the internal difference and possible mechanism. The Er

co-doped crystal structure was demonstrated through XRD test

and the purity of the sample and the difference in growth were confirmed by analysis. In order to find out the sources of differences

the emission spectra of doped ions with different valence states have been monitored

and the emission spectra of the changes with the content of Er

have been compared. The internal physical mechanism of co-doping Er

enhanced luminescence is seen from the change of the luminescence. The internal physical mechanism of the co-doping Er

enhanced luminescence is to control the crystal texture and adjust the valence state. For practical applications in the future

a temperature characteristic test was carried out to show the emission spectrum changes under temperature variation. This research provides new ideas for the work of regulating the luminous intensity and improving quantum efficiency.

关键词

Keywords

references

GU Y X , ZHANG Q H , LI Y G , et al . Nitridation from core-shell oxides for tunable luminescence of BaSi2O2N2∶Eu2+ LED phosphors [J]. J. Mater. Chem. , 2010 , 20 ( 29 ): 6050 - 6056 .

YUN B G , HORIKAWA T , HANZAWA H , et al . Preparation and luminescence properties of single-phase BaSi2O2N2∶Eu2+, a bluish-green phosphor for white light-emitting diodes [J]. J. Electrochem. Soc. , 2010 , 157 ( 10 ): J364 .

王灵利 , 倪海勇 , 张秋红 . LED用绿色荧光粉BaSi2N2O2∶Eu2+的发光和封装性能 [J]. 发光学报 , 2012 , 33 ( 5 ): 465 - 469 .

WANG L L , NI H Y , ZHANG Q H . Luminescence and encapsulation properties of BaSi2O2N2 doped with divalent europium [J]. Chin. J. Lumin. , 2012 , 33 ( 5 ): 465 - 469 . (in Chinese)

QIN J L , ZHANG H R , LEI B F , et al . Thermoluminescence and temperature-dependent afterglow properties in BaSi2O2N2∶Eu2+ [J]. J. Am. Ceram. Soc. , 2013 , 96 ( 10 ): 3149 - 3154 .

MA Z D , ZHOU J Y , ZHANG J C , et al . Mechanics-induced triple-mode anticounterfeiting and moving tactile sensing by simultaneously utilizing instantaneous and persistent mechanoluminescence [J]. Mater. Horiz. , 2019 , 6 ( 10 ): 2003 - 2008 .

PETIT R R , MICHELS S E , FENG A , et al . Adding memory to pressure-sensitive phosphors [J]. Light:Sci. Appl. , 2019 , 8 : 124-1-10 .

BOTTERMAN J , VAN DEN EECKHOUT K , DE BAERE I , et al . Mechanoluminescence in BaSi2O2N2∶Eu [J]. Acta Mater. , 2012 , 60 ( 15 ): 5494 - 5500 .

赵春雷 , 胡运生 , 陈凯 , 等 . 白光LED用硅基氮(氧)化物荧光粉的研究进展 [J]. 稀有金属 , 2017 , 41 ( 12 ): 1374 - 1385 .

ZHAO C L , HU Y S , CHEN K , et al . Research progress in silicon-based (oxy) nitride phosphors for phosphor-converted white LED [J]. Chin. J. Rare Met. , 2017 , 41 ( 12 ): 1374 - 1385 . (in Chinese)

PAWLIK T , MICHALIK D , BARZOWSKA J , et al . The influence of synthesis temperature on manufacturing and properties of SrSi2O2N2∶Eu2+ powders [J]. Arch. Metall. Mater. , 2017 , 62 ( 2 ): 687 - 690 .

SONG Y , SONG Y , TODA K , et al . Synthesis and photoluminescence properties of oxynitride phosphors M0.98Si2O2N2∶E http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210965&type= http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210973&type= http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=21210969&type= (M=Ba, Sr, Ca) using the cellulose assisted liquid phase precursor process [J]. Ceram. Int. , 2016 , 42 ( 8 ): 9667 - 9672 .

HUANG J S , LIU R H , LIU Y H , et al . Effect of fluxes on synthesis and luminescence properties of BaSi2O2N2∶Eu2+ oxynitride phosphors [J]. J. Rare Earths , 2018 , 36 ( 3 ): 225 - 230 .

ADAMCZYK B J , BRIK M G , NAGIRNYI V , et al . Optical properties of SrSi2O2N2∶Eu2+ phosphor enhanced by the addition of carbonate or fluoride reactive agents [J]. J. Alloys Compd. , 2020 , 845 : 155468 .

ADAMCZYK B J , JÜSTEL T , PLEWA J , et al . The influence of Na2CO3 flux on photoluminescence properties of SrSi2O2N2∶Eu2+ phosphor [J]. Ceram. Int. , 2017 , 43 ( 15 ): 12381 - 12387 .

HUO J S , LÜ W , SHAO B Q , et al . Enhanced luminescence intensity of CaSi2O2N2∶Eu2+ phosphor by using flux in the preparation process and incorporating Gd3+ ions [J]. J. Lumin. , 2016 , 180 : 46 - 50 .

LI H L , CHEN H , YANG L , et al . Facile synthesis and systematic study of Eu2+ doped SrSi2O2N2 green-emitting phosphor based on a new method [J]. J. Lumin. , 2018 , 194 : 661 - 666 .

谢安 , 王宇威 , 张裕骏 , 等 . 两步反应法制备硅基氮氧化物荧光材料SrSi2O2N2∶Eu2+及其发光性能研究 [J]. 中国科学:物理学力学天文学 , 2014 , 44 ( 7 ): 712 - 719 .

XIE A , WANG Y W , ZHANG Y J , et al . Structure and photoluminescence properties of SrSi2O2N2∶Eu2+ phosphors prepared by two-step solid state reaction using Sr2SiO4∶Eu2+ as a precursor [J]. Sci. Sinica-Phys. Mech. Astron. , 2014 , 44 ( 7 ): 712 - 719 . (in Chinese)

WU D , FU L , HE S A , et al . Significantly enhanced luminescence efficiency and thermal stability of BaSi2O2N2∶Eu2+ phosphor by doping a very small amount of SiC [J]. Ceram. Int. , 2020 , 46 ( 16 ): 25382 - 25391 .

LI X C , DENG C Y , LONG F , et al . Effect of silicon powder content in starting materials on the phase and luminescence properties of SrSi2O2N2∶Eu2+ phosphors [J]. J. Mater. Sci.:Mater. Electron. , 2017 , 28 ( 17 ): 12551 - 12554 .

SONG X F , FU R L , AGATHOPOULOS S , et al . Synthesis of BaSi2O2N2∶Ce3+, Eu2+ phosphors and determination of their luminescence properties [J]. J. Am. Ceram. Soc. , 2011 , 94 ( 2 ): 501 - 507 .

MAJEWSKA N , LEŚNIEWSKI T , MAHLIK S , et al . Study of persistent luminescence and thermoluminescence in SrSi2N2O2∶Eu2+, M3+(M=Ce, Dy, and Nd) [J]. Phys. Chem. Chem. Phys. , 2020 , 22 ( 30 ): 17152 - 17159 .

ZOU Y X , YU L X , GAO Z Y , et al . Synthesis, crystal structure, and photoluminescence of Eu2+, Ce3+, Mn2+ doped oxynitride phosphors [J]. Opt. Mater. , 2019 , 92 : 411 - 417 .

HAO J R , CAO L , WEI Y , et al . Improving photoluminescence and thermal stability of CaSi2O2N2∶Eu2+ phosphors by codoping lanthanide ions (Ln=Sc, La, Gd, Yb, Lu) [J]. Mater. Lett. , 2018 , 211 : 122 - 125 .

KECHELE J A , OECKLER O , STADLER F , et al . Structure elucidation of BaSi2O2N2—a host lattice for rare-earth doped luminescent materials in phosphor-converted (pc)-LEDs [J]. Solid State Sci. , 2009 , 11 ( 2 ): 537 - 543 .

MIYAZAKI H , YOSHIDA S , SUZUKI H , et al . Phosphorescence properties of MSi2O2N2∶Eu(M=Ca, Sr, Ba) mixture-phase phosphors using Si2N2O powder [J]. J. Ceram. Soc. Japan , 2015 , 123 ( 1435 ): 152 - 155 .

LI G G , LIN C C , CHEN W T , et al . Photoluminescence tuning via cation substitution in oxonitridosilicate phosphors:DFT calculations, different site occupations, and luminescence mechanisms [J]. Chem. Mater. , 2014 , 26 ( 9 ): 2991 - 3001 .

SEIBALD M , ROSENTHAL T , OECKLER O , et al . Highly efficient pc-LED phosphors Sr1-xBaxSi2O2N2∶Eu2+(0 x 1)-crystal structures and luminescence properties revisited [J]. Crit. Rev. Solid State Mater. Sci. , 2014 , 39 ( 3 ): 215 - 229 .

CHEN Y , ZHANG J . Investigation on luminescence of bifunctional Y4.67(SiO4)3O∶Ce3+/Tb3+/Eu3+ phosphors [J]. J. Lumin. , 2020 , 218 : 116842 .

HUANG D Y , WEI Y , DANG P P , et al . Tunable color emission in LaScO3∶Bi3+, Tb3+, Eu3+ phosphor [J]. J. Am. Ceram. Soc. , 2020 , 103 ( 5 ): 3273 - 3285 .

ZHANG L L , HAO Z D , ZHANG X , et al . Enhanced ~2 μm emission of Tm3+ in Lu2O3 by addition of a trace amount of Er3+ [J]. Inorg. Chem. , 2017 , 56 ( 21 ): 13062 - 13069 .

WU H , HAO Z D , ZHANG L L , et al . Phonon energy dependent energy transfer upconversion for the red emission in the Er3+/Yb3+ system [J]. J. Phys. Chem. C , 2018 , 122 ( 17 ): 9611 - 9618 .

KIM J S , PARK Y H , KIM S M , et al . Temperature-dependent emission spectra of M2SiO4∶Eu2+(M=Ca, Sr, Ba) phosphors for green and greenish white LEDs [J]. Solid State Commun. , 2005 , 133 ( 7 ): 445 - 448 .

BAGINSKIY I , LIU R S , WANG C L , et al . Temperature dependent emission of strontium-barium orthosilicate (Sr2-xBax)-SiO4∶Eu2+ phosphors for high-power white light-emitting diodes [J]. J. Electrochem. Soc. , 2011 , 158 ( 10 ): P118 .

XIAO W E , ZHANG X , HAO Z D , et al . Blue-emitting K2Al2B2O7∶Eu2+phosphor with high thermal stability and high color purity for near-UV-pumped white light-emitting diodes [J]. Inorg. Chem. , 2015 , 54 ( 7 ): 3189 - 3195 .

Views

326

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Improving Thermal Stability of Photoluminescence in Violet-emitting CsPbCl₃ Perovskite Nanocrystals Using Ni Doping

An Organic-inorganic Manganese Halide to Improve LED Light Output Stability and Its Brightness Optimization

Synergistic Regulation of Luminescent and Ferroelectric Properties of Er³⁺-doped AlScN Films

Luminescence Properties of Eu³⁺， Dy³⁺， Na⁺ Doped Sr₃AlO₄F

Luminescence Properties and Thermal Stability of Sm³⁺, Eu³⁺Co-doped Double Perovskite Gd₂ZnTiO₆ Phosphor

Related Author

CHEN Xiao-hui

XING Ke

CAO Zhen

YUAN Xi

ZHAO Jia-long

SUN Yiqun

ZHANG Liangliang

PAN Guohui

Related Institution

School of Science, Northeast University

Key Laboratory of Functional Materials Physics and Chemistry of The Ministry of Education, Jilin Normal University

State Key Laboratory of Luminescence Science and Technology， Changchun Institute of Optics， Fine Mechanics and Physics， Chinese Academy of Sciences

Center of Materials Science and Optoelectronics Engineering， University of Chinese Academy of Sciences

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰