An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg<sup>2+</sup> Detection

Ting WANG; Tian-hao LI; Yu ZHANG; Xi-long WEI; Bing BAI; Yuan-yuan LIU; Kai LI; Shuang-quan ZANG

doi:10.37188/CJL.20200400

您当前的位置：

首页 >

文章列表页 >

An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg²⁺ Detection

Invited Paper | 更新时间：2021-03-19

- An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg²⁺ Detection
- Chinese Journal of Luminescence Vol. 42, Issue 3, Pages: 303-310(2021)
- 作者机构：
  
  郑州大学化学学院绿色催化中心，河南郑州　 450001
- 作者简介：
- 基金信息：
  
  Research and Practice Project of Undergraduate Education and Teaching Reform of Zhengzhou University(2020zzuJXLX002;2020zzuJXLX062);Undergraduate Innovation and Entrepreneurship Training Program of Zhengzhou University(202010459003)
- DOI：10.37188/CJL.20200400
  CLC： O482.31
- Received：27 December 2020，
  
  Revised：2021-01-18，
  
  Published：01 March 2021
- 稿件说明：
移动端阅览
Ting WANG, Tian-hao LI, Yu ZHANG, et al. An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg²⁺ Detection[J]. Chinese Journal of Luminescence, 2021, 42(3): 303-310.
DOI：

Ting WANG, Tian-hao LI, Yu ZHANG, et al. An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg²⁺ Detection[J]. Chinese Journal of Luminescence, 2021, 42(3): 303-310. DOI： 10.37188/CJL.20200400.

摘要

设计合成了一种新型聚集诱导发光分子三苯乙烯炔金-三苯基膦(1)。1溶解在DMSO中几乎无荧光，在固体状态下具有明亮的蓝色荧光，表现出典型的聚集诱导发光性能。研究表明，其聚集诱导发光特性来自于限制分子内旋转机理。1在水溶液中表现出对Hg

2＋

的荧光猝灭响应，并表现出良好的选择性和抗干扰能力。

Abstract

A new aggregation-induced emission(AIE) molecule of triphenylvinylacetylene gold triphenylphosphine complex(1) was designed and synthesized in this work. 1 showed no emission in DMSO solution but intense emission in solid state

suggesting a typical AIE property. The AIE property of 1 was proven to be originated from a restriction of intramolecular rotation(RIR) mechanism. A fluorescence "turn-off" response of 1 for Hg

ion was observed in aqueous solution

which exhibited good selectivity and anti-interference property.

关键词

Keywords

references

ZHOU N , HUO F J , YUE Y K , et al . Specific fluorescent probe based on “protect-deprotect” to visualize the norepinephrine signaling pathway and drug intervention tracers [J]. J. Am. Chem. Soc. , 2020 , 142 ( 41 ): 17751 - 17755 .

YANG M L , PARK I S , YASUDA T . Full-color,narrowband,and high-efficiency electroluminescence from boron and carbazole embedded polycyclic heteroaromatics [J]. J. Am. Chem. Soc. , 2020 , 142 ( 46 ): 19468 - 19472 .

ZHANG M M , LI K , ZANG S Q . Progress in atomically precise coinage metal clusters with aggregation-induced emission and circularly polarized luminescence [J]. Adv. Opt. Mater. , 2020 , 8 ( 14 ): 1902152 .

ZHAO Z , ZHANG H K , LAM J W Y , et al . Aggregation-induced emission:new vistas at the aggregate level [J]. Angew. Chem. Int. Ed. , 2020 , 59 ( 25 ): 9888 - 99077 .

ZHANG T , MA X , WU H W , et al . Molecular engineering for metal-free amorphous materials with room-temperature phosphorescence [J]. Angew. Chem. Int. Ed. , 2020 , 59 ( 28 ): 11206 - 11216 .

QIAN J , TANG B Z . AIE luminogens for bioimaging and theranostics:from organelles to animals [J]. Chem , 2017 , 3 ( 1 ): 56 - 91 .

YE S Y , CUI C X , CHENG X J , et al . Red light-initiated cross-linking of NIR probes to cytoplasmic RNA:an innovative strategy for prolonged imaging and unexpected tumor suppression [J]. J. Am. Chem. Soc. , 2020 , 142 ( 51 ): 21502 - 21512 .

JIANG X Y , GAO H F , ZHANG X Q , et al . Highly-sensitive optical organic vapor sensor through polymeric swelling induced variation of fluorescent intensity [J]. Nat. Commun. , 2018 , 9 : 3799 .

ALAM P , LEUNG N L C , CHENG Y H , et al . Spontaneous and fast molecular motion at room temperature in the solid state [J]. Angew. Chem. Int. Ed. , 2019 , 58 ( 14 ): 4536 - 4540 .

HONG Y N , LAM J W Y , TANG B Z . Aggregation-induced emission:phenomenon,mechanism and applications [J]. Chem. Commun. , 2009 ,( 29 ): 4332 - 4353 .

BU F , DUAN R H , XIE Y J , et al . Unusual aggregation-induced emission of a coumarin derivative as a result of the restriction of an intramolecular twisting motion [J]. Angew. Chem. Int. Ed. , 2015 , 54 ( 48 ): 14492 - 14497 .

MEI J , LEUNG N L C , KWOK R T K , et al . Aggregation-induced emission:together we shine,united we soar! [J]. Chem. Rev. , 2015 , 115 ( 21 ): 11718 - 11940 .

LAI Q , LIU Q , ZHAO K , et al . Rational design and synthesis of yellow-light emitting triazole fluorophores with AIE and mechanochromic properties [J]. Chem. Commun. , 2019 , 55 ( 32 ): 4603 - 4606 .

李振 , 李倩倩 . 分子聚集态发光展望:聚散不同性相远集体效应叹观止 [J]. 发光学报 , 2020 , 41 ( 6 ): 651 - 654 .

LI Z , LI Q Q . Prospect of luminogens as aggregates:collective effect of molecular aggregation [J]. Chin. J. Lumin. , 2020 , 41 ( 6 ): 651 - 654 . (in Chinese)

秦安军 , 胡蓉 . 聚集诱导发光聚合物的机遇与挑战:聚合物之美与聚集体之光相辉映 [J]. 发光学报 , 2020 , 41 ( 9 ): 1082 - 1086 .

QIN A J , HU R . Prospect and challenge of polymers featuring aggregation-induced emission characteristics [J]. Chin. J. Lumin. , 2020 , 41 ( 9 ): 1082 - 1086 . (in Chinese)

CHEN Y H , FANG Y , GU H , et al . Color-tunable and esipt-inspired solid fluorophores based on benzothiazole derivatives:aggregation-induced emission,strong solvatochromic effect,and white light emission [J]. ACS Appl. Mater. Interfaces , 2020 , 12 ( 49 ): 55094 - 55106 .

LI Y , TANG R B , LIU X Y , et al . Bright aggregation-induced emission nanoparticles for two-photon imaging and localized compound therapy of cancers [J]. ACS Nano , 2020 , 14 ( 12 ): 16840 - 16835 .

ROUHANI F , MORSALI A , RETAILLEAU P . Simple one-pot preparation of a rapid response AIE fluorescent metal-organic framework [J]. ACS Appl. Mater. Interfaces , 2018 , 10 ( 42 ): 36259 - 36266 .

KONG Y J , YAN Z P , LI S , et al . Photoresponsive propeller-like chiral AIE copper(Ⅰ) clusters [J]. Angew. Chem. Int. Ed. , 2020 , 59 ( 13 ): 5336 - 5340 .

ZHANG R Y , DUAN Y K , LIU B . Recent advances of aie dots in NIR imaging and phototherapy [J]. Nanoscale , 2019 , 11 ( 41 ): 19241 - 19250 .

LI Y Y , LIU S J , HAN T , et al . Sparks fly when AIE meets with polymers [J]. Mater. Chem. Front. , 2019 , 3 ( 11 ): 2207 - 2220 .

XING C , LIU J X , CHEN F , et al . Diphenyl-1-pyrenylphosphine:photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change [J]. Chem. Commun. , 2020 , 56 ( 30 ): 4220 - 4223 .

HAN Z , DONG X Y , LUO P , et al . Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency [J]. Sci. Adv. , 2020 , 6 ( 6 ): eaay0107 .

余娟 , 雷婧 , 姜婧 , 等 . 系列金(Ⅰ)有机膦化合物的合成 [J]. 贵金属 , 2015 , 36 ( 2 ): 38 - 43 .

YU J , LEI J , JIANG J , et al . Synthesis of organic phosphine gold(Ⅰ) compounds [J]. Precious Metals , 2015 , 36 ( 2 ): 38 - 43 . (in Chinese)

FELDMAN K S , HESTER D K , LÓPEZ C S , et al . Allenyl azide cycloaddition chemistry. Photochemical initiation and CuI mediation leads to improved regioselectivity [J]. Org. Lett. , 2008 , 10 ( 8 ): 1665 - 1668 .

CHEN J W , LAW C C W , LAM J W Y , et al . Synthesis,light emission,nanoaggregation,and restricted intramolecular rotation of 1,1-substituted 2,3,4,5-tetraphenylsiloles [J]. Chem. Mater. , 2003 , 15 ( 7 ): 1535 - 1546 .

TANG W X , XIANG Y , TONG A J . Salicylaldehyde azines as fluorophores of aggregation-induced emission enhancement characteristics [J]. J. Org. Chem. , 2009 , 74 ( 5 ): 2163 - 2166 .

邢其毅 . 基础有机化学 [M]. 第 4 版. 北京 : 北京大学出版社 , 2019 .

XING Q Y . Basic Organic Chemistry [M]. 4 th ed. Beijing : Peking University Press , 2019 . (in Chinese)

Views

298

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research Progress of Functional Aggregation-induced Emission Fluorescent Coatings

Aggregation-induced Emission Properties and Latent Fingerprint Imaging of Biphenyl-based Schiff Base Compounds

A “Turn-On” Fluorescent Probe for Detection of Perfluorooctane Sulfonate

Conjugated Materials Containing Ethyl Benzoate Structure for Fluorescent Detection of Nitroaromatic Explosives

Synthesis and Characterization of Aggregation-induced Red Emitter Based on Dibenzophenazine Core

Related Author

CAO Yuqi

LI Lu

SHI Hui

LIU Guoliang

YANG Jinlong

GAO Anran

JIANG Qingyi

CHEN Chunlin

Related Institution

Tianjin Jialong Environmental Protection Technology Co.， Ltd

School of Biological and Environmental Engineering， Tianjin Vocational Institute

Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device， School of Chemistry and Chemical Engineering， Kunming University

College of Life Science， Hebei Normal University

Zhejiang Institute of Tianjin University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China Postal code：130033
Tel：0431-86176862 Email：fgxbt@126.com
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg2+ Detection

DOI：10.37188/CJL.20200400

摘要

Abstract

关键词

Keywords

references

An Aggregation-induced Emission Molecule Based on Gold Complex and Its Application for Hg²⁺ Detection