Upconversion Luminescence and Temperature Sensing Properties for Sc2(WO4)3:Er3+/Yb3+

Ye JIN; Kun LI; Xu LUO; Li MA; Xiao-jun WANG

doi:10.37188/CJL.20200326

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Upconversion Luminescence and Temperature Sensing Properties for Sc₂(WO₄)₃:Er³⁺/Yb³⁺

Synthesis and Properties of Materials | 更新时间：2021-01-12

- Upconversion Luminescence and Temperature Sensing Properties for Sc₂(WO₄)₃:Er³⁺/Yb³⁺
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 91-97(2021)
- 作者机构：
  
  1.重庆理工大学理学院, 重庆 400054
  2.美国佐治亚南方大学物理系, 佐治亚斯泰茨伯勒 30460
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;Chongqing Research Program of Basic Research and Frontier Technology;Chongqing Research Program of Basic Research and Frontier Technology;Chongqing Research Program of Basic Research and Frontier Technology;Science and Technology Research Program of Chongqing Municipal Education Commission;Science and Technology Research Program of Chongqing Municipal Education Commission
- DOI：10.37188/CJL.20200326
  CLC： O482.31
- Received：29 October 2020，
  
  Accepted：26 November 2020，
  
  Published：2021-01
- 稿件说明：
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Ye JIN, Kun LI, Xu LUO, et al. Upconversion Luminescence and Temperature Sensing Properties for Sc₂(WO₄)₃:Er³⁺/Yb³⁺[J]. Chinese journal of luminescence, 2021, 42(1): 91-97.
DOI：

Ye JIN, Kun LI, Xu LUO, et al. Upconversion Luminescence and Temperature Sensing Properties for Sc₂(WO₄)₃:Er³⁺/Yb³⁺[J]. Chinese journal of luminescence, 2021, 42(1): 91-97. DOI： 10.37188/CJL.20200326.

摘要

通过高温固相法制备出一系列新型上转换材料Sc

（WO

）

：Er

/Yb

。在980 nm激光激发下，Sc

（WO

）

：Er

/Yb

样品发出肉眼可见的强绿光。利用荧光光度计测得样品的发光光谱，在500~600 nm之间有强绿光发射，分别归因于Er

的

11/2

→

15/2

和

3/2

→

15/2

跃迁发射。在650~700 nm位置处，有对应于Er

离子

9/2

→

15/2

跃迁的较弱的红光发射。随着掺杂浓度的变化，样品的红绿分支比发生变化。当样品掺杂Er

浓度为0.05%、Yb

浓度等于0.1%时，样品发射的绿光强度是红光强度的27倍。另外，利用荧光强度比方法研究了Er

的两个热耦合能级在303~573 K范围内的发光温度特性。393 K时，样品的灵敏度达到最大为0.006 8 K

-1

。对比于其他荧光粉材料，Sc

（WO

）

：Er

/Yb

的灵敏度处于较高水平，在实际测温中具有更好的应用前景。

Abstract

A series of upconversion materials Er

/Yb

co-doped Sc

(WO

)

have been prepared by a high-temperature solid-phase method. Under the 980 nm near-infrared laser

the green emission intensity of the up-conversion luminescence is greater than that of the red

and the green light is visible to the naked eyes. When 0.05% Er

and 0.1%Yb

are doped

the green emission is 27 times more than the red emission. Furthermore

the fluorescence intensity ratio method was used to describe the optical temperature sensor with two thermal coupling energy levels of Er

in the range of 303~573 K. At 393 K

the sensitivity of the sample reached the maximum 0.006 8 K

-1

. Compared with some reported materials

the sensitivity of Sc

(WO)

:Er

/Yb

is higher and it has a better prospect in temperature measurement.

关键词

Keywords

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Related Author

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Related Institution

School of Science， Chongqing University of Technology

Department of Physics， Georgia Southern University， Statesboro

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