Color-tunable Fluorescent Ink Based on Single Benzene Fluorophore

Hai-xiang MAO; Biao WANG; Bin-bin DING; Min-jie GUO; Zhi FAN; Sheng-hua LI; Jing CUI

doi:10.37188/CJL.20200280

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Color-tunable Fluorescent Ink Based on Single Benzene Fluorophore

Synthesis and Properties of Materials | 更新时间：2021-01-12

- Color-tunable Fluorescent Ink Based on Single Benzene Fluorophore
- Chinese Journal of Luminescence Vol. 42, Issue 1, Pages: 44-52(2021)
- 作者机构：
  
  1.天津科技大学化工与材料学院, 天津 300457
  2.中国石化上海石油化工研究院, 上海 201208
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;Scientific Research Project of Tianjin Educational Committee;National undergraduate innovation and entrepreneurship training program
- DOI：10.37188/CJL.20200280
  CLC： O482.31
- Received：18 September 2020，
  
  Accepted：27 October 2020，
  
  Published：2021-01
- 稿件说明：
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Hai-xiang MAO, Biao WANG, Bin-bin DING, et al. Color-tunable Fluorescent Ink Based on Single Benzene Fluorophore[J]. Chinese Journal of Luminescence, 2021, 42(1): 44-52.
DOI：

Hai-xiang MAO, Biao WANG, Bin-bin DING, et al. Color-tunable Fluorescent Ink Based on Single Benzene Fluorophore[J]. Chinese Journal of Luminescence, 2021, 42(1): 44-52. DOI： 10.37188/CJL.20200280.

摘要

以丁二酸二丁酯为原料，经过缩合、氨化、芳构化合成了单苯环荧光化合物2，5-二氨基-1，4-苯二甲酸丁酯

。溶液中化合物

的最大荧光发射峰变化范围为60 nm，即从正己烷中的514 nm到乙二醇中的574 nm。化合物

在固态下经紫外光照射可发出黄色荧光，其最大发射波长为558 nm，荧光量子产率（

）为0.28。采用氯甲酸-2，2，2-三氯乙酯（TrocCl）将化合物

的氨基酰化可得到单酰胺化产物化合物

，固态下可发出绿色荧光，其最大荧光发射峰位于493 nm，

为0.13；进一步酰化可得到双酰胺化产物化合物

，固态下可发出蓝色荧光，其最大荧光发射波长467 nm，

为0.79。这一过程可以在本色纸上原位完成，进而实现荧光三色转变。即将化合物

溶液书写于纸张上可获得黄色荧光字样，在其上涂写不同浓度的TrocCl溶液可将纸张上的化合物

转化为化合物

和

，从而使字体的发光颜色变为绿色和蓝色。

Abstract

The single benzene fluorophore dibutyl-2

5-diaminoterephthalate

was synthesized by claisen condensation of dibutyl succinate followed by amination and aromatization. The maximum emission peaks of compound

are ranged from 514 nm in n-Hexane to 574 nm in glycol

spanning 60 nm. Compound

displays efficient yellow emissions in solid-state(the emission maxima

=558 nm

fluorescence quantum yield

=0.28). The acylation of amino group in compound

by 2

2-Trichloroethyl chloroformate(TrocCl) was led tomonoamide compound

which gives green emissions in solid-state(

=493 nm

=0.13); and further acylation led to diamide compound

which gives blue emissions in solid-state(

=467 nm

=0.79). Those trichromatic fluorescent transformation also can be achieved on unbleached papers. As a result of the acylation of compound

on paper

the emission color can be changed from yellow to green and blue after writing different concentration of colorless TrocCl solution on the top of fluorescent

characters

which makes it possible to apply widely as color-tunable fluorescent ink.

关键词

Keywords

references

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Hai-Xiang Mao

Bin-Bin Ding

Minjie Guo

Sheng-Hua Li

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Related Institution

College of Chemical Engineering and Materials Science， Tianjin University of Science & Technology

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