Advances in Eu2+ Doped UCr4C4-type Phosphors with Narrow-band Emissions and Their Applications

Jin-di WANG; Shuai HUANG; Meng-meng SHANG

doi:10.37188/CJL.20200182

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Advances in Eu²⁺ Doped UCr₄C₄-type Phosphors with Narrow-band Emissions and Their Applications

Invited Review | 更新时间：2020-10-12

- Advances in Eu²⁺ Doped UCr₄C₄-type Phosphors with Narrow-band Emissions and Their Applications
- Chinese Journal of Luminescence Vol. 41, Issue 10, Pages: 1214-1233(2020)
- 作者机构：
  
  1.山东大学材料工程与科学学院, 山东济南 250061
  2.青岛大学化学化工学院, 山东青岛 266071
- 作者简介：
- 基金信息：
  
  National Natural Science Foundation of China;Natural Science Foundation of Shandong
- DOI：10.37188/CJL.20200182
  CLC： O482.31
- Received：29 June 2020，
  
  Accepted：24 July 2020，
  
  Published：2020-10
- 稿件说明：
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Jin-di WANG, Shuai HUANG, Meng-meng SHANG. Advances in Eu²⁺ Doped UCr₄C₄-type Phosphors with Narrow-band Emissions and Their Applications[J]. Chinese journal of luminescence, 2020, 41(10): 1214-1233.
DOI：

Jin-di WANG, Shuai HUANG, Meng-meng SHANG. Advances in Eu²⁺ Doped UCr₄C₄-type Phosphors with Narrow-band Emissions and Their Applications[J]. Chinese journal of luminescence, 2020, 41(10): 1214-1233. DOI： 10.37188/CJL.20200182.

摘要

近年来，窄带发光材料由于可扩大显示色域、改善色彩重现性、提高发光效率等优点在LED显示领域引起广泛的关注。但由于目前已报道的窄带发射材料较少以及Eu

4f-5d跃迁的扩展效应，用于新兴领域的窄带Eu

掺杂荧光材料的研发仍然面临巨大挑战。本文综述了目前已报道的具有良好发光性能的Eu

激活的UCr

型窄带荧光材料，并从结构相关的发光性质出发，分类描述了Eu

掺杂的UCr

基氮化物、氧化物及氮氧化物荧光材料的晶体结构特征、发光及应用特性，以期望为设计合成新型稀土掺杂的窄带发光材料提供有意义的启示。

Abstract

In recent years

narrow-band phosphors have attracted widespread attentions in the field of LED display due to the advantages of expanding display color gamut

improving color reproducibility and enhancing luminous efficiency. However

due to the limited number of narrow-band phosphors reported so far and the expansion effect of Eu

4f-5d transition

the research and development of Eu

-doped phosphors with narrow-bands for emerging fields still face huge challenges. This article overviews the currently reported Eu

-activated UCr

type phosphors with narrow-band emissions

describes the crystal structure characteristics

photoluminescence properties and their applications of Eu

-doped UCr

-based nitrides

oxide and oxynitride phosphors

and discusses the structure-related luminescence properties. It is expected that the review could provide meaningful enlightenment for the design of novel rare earth doped emissions.

关键词

Keywords

references

ZHAO M, LIAO H X, MOLOKEEV M S, et al .. Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition[J]. Light Sci. Appl. , 2019, 8:38.

PUST P, SCHMIDT P J, SCHNICK W. A revolution in lighting[J]. Nat. Mater. , 2015, 14(5):454-458.

PIMPUTKAR S, SPECK J S, DENBAARS S P, et al .. Prospects for LED lighting[J]. Nat. Photonics , 2009, 3(4):180-182.

STROBEL P, SCHMIECHEN S, SIEGERT M, et al .. Narrow-band green emitting nitridolithoalumosilicate Ba[Li 2 (Al 2 Si 2 )-N 6 ]: Eu 2+ with framework topology whj for LED/LCD-backlighting applications[J]. Chem. Mater. , 2015, 27(17):6109-6115.

YOSHIMURA K, FUKUNAGA H, IZUMI M, et al .. Achieving superwide-color-gamut display by using narrow-band green-emitting γ-AlON: Mn, Mg phosphor[J]. Jpn. J. Appl. Phys ., 2017, 56(4):041701.

JANG E, JUN S, JANG H, et al .. White-light-emitting diodes with quantum dot color converters for display backlights[J]. Adv. Mater ., 2010, 22(28):3076-3080.

SHIRASAKI Y, SUPRAN G J, BAWENDI M G, et al .. Emergence of colloidal quantum-dot light-emitting technologies[J]. Nat. Photonics , 2013, 7(1):13-23.

KIM B, KIM J, OHM W S, et al .. Eliminating hotspots in a multi-chip LED array direct backlight system with optimal patterned reflectors for uniform illuminance and minimal system thickness[J] . Opt. Express , 2010, 18(8):8595-8604.

CHEN L, CHU C I, LIU R S. Improvement of emission efficiency and color rendering of high-power LED by controlling size of phosphor particles and utilization of different phosphors[J]. Microelectron. Reliab. , 2012, 52(5):900-904.

LIN C C, MEIJERINK A, LIU R S. Critical red components for next-generation white LEDs[J]. J. Phys. Chem. Lett ., 2016, 7(3):495-503.

LI S X, XIE R J, TAKEDA T, et al .. Critical review-narrow-band nitride phosphors for wide color-gamut white LED backlighting[J]. ECS J. Solid State Sci. Technol ., 2018, 7(1):R3064-R3078.

HÖPPE H A, LUTZ H, MORYS P, et al .. Luminescence in Eu 2+ -doped Ba 2 Si 5 N 8 :fluorescence, thermoluminescence, and upconversion[J]. J.Phys.Chem.Solids , 2000, 61(12):2001-2006.

UHEDA K, HIROSAKI N, YAMAMOTO Y, et al .. Luminescence properties of a red phosphor, CaAlSiN 3 : Eu 2+ , for white light-emitting diodes[J]. Electrochem.Solid-State Lett ., 2006, 9(4):H22-H25.

CHO Y S, HUH Y D. Cathodoluminescence properties of red-emitting Sr 1- x Ca x S: Eu phosphors[J]. Bull. Korean Chem. Soc ., 2016, 37(7):991-996.

SCHUBERT E F, KIM J K. Solid-state light sources getting smart[J]. Science , 2005, 308(5726):1274-1278.

LI S X, WANG L, TANG D M, et al .. Achieving high quantum efficiency narrow-band β-SiAlON: Eu 2+ phosphors for high-brightness LCD backlights by reducing the Eu 3+ luminescence killer[J]. Chem. Mater ., 2018, 30(2):494-505.

CHEN X M, ZHANG F, GE Y, et al .. Centimeter-sized Cs 4 PbBr 6 crystals with embedded CsPbBr 3 nanocrystals showing superior photoluminescence:nonstoichiometry induced transformation and light-emitting applications[J]. Adv. Funct. Mater ., 2018, 28(16):1706567-1-7.

SUN J Y, RABOUW F T, YANG X F, et al .. Facile two-step synthesis of all-inorganic perovskite CsPb X 3 ( X =Cl, Br, and I) zeolite-Y composite phosphors for potential backlight display application[J]. Adv. Funct. Mater ., 2017, 27(45):1704371-1-8.

DING C, TANG W J. Crystal structure, energy transfer and tunable luminescence properties of Ca 8 ZnCe(PO 4 ) 7 : Eu 2+ , Mn 2+ phosphor[J]. Opt. Mater ., 2018, 76:56-62.

LAI S Q, ZHAO M, QIAO J W, et al .. Data-driven photoluminescence tuning in Eu 2+ -doped phosphors[J]. J. Phys. Chem. Lett. , 2020, 11(14):5680-5685.

ZHANG M L, XIA Z G, LIU Q L. Thermally stable K x Cs 1- x AlSi 2 O 6 : Eu 2+ phosphors and their photoluminescence tuning[J]. J. Mater. Chem . C, 2017, 5(30):7489-7494.

YAN J, ZHANG Z W, WEN D W, et al .. Crystal structure and photoluminescence tuning of novel single-phase Ca 8 ZnLu-(PO 4 ) 7 : Eu 2+ , Mn 2+ phosphors for near-UV converted white light-emitting diodes[J]. J. Mater. Chem . C, 2019, 7(27):8374-8382.

STROBEL P, WEILER V, SCHMIDT P J, et al .. Sr[BeSi 2 N 4 ]: Eu 2+ /Ce 3+ and Eu[BeSi 2 N 4 ]:nontypical luminescence in highly condensed nitridoberyllosilicates[J] . Chem. Eur. J ., 2018, 24(28):7243-7249.

SHANG M M, LI C X, LIN J. How to produce white light in a single-phase host?[J]. Chem. Soc. Rev ., 2014, 43(5):1372-1386.

AULL B F, JENSSEN H P. Impact of ion-host interactions on the 5d-to-4f spectra of lanthanide rare-earth-metal ions. Ⅰ. A phenomenological crystal-field model[J]. Phys. Rev. B, 1986, 34(10):6640-6646.

LI G G, TIAN Y, ZHAO Y, et al .. Recent progress in luminescence tuning of Ce 3+ and Eu 2+ -activated phosphors for pc-WLEDs[J]. Chem. Soc. Rev ., 2015, 44(23):8688-8713.

WANG L, XIE R J, SUEHIRO T, et al .. Down-conversion nitride materials for solid state lighting:recent advances and perspectives[J]. Chem. Rev ., 2018, 118(4):1951-2009.

XIA Z G, XU Z H, CHEN M Y, et al .. Recent developments in the new inorganic solid-state LED phosphors[J]. Dalton Trans ., 2016, 45(28):11214-11232.

BEHRENS R K, JEITSCHKO W. UCR 4 C 4 with filled MONI 4 type structure[J]. Monatsh. Chem ., 1987, 118(1):43-50.

SCHMIECHEN S, SCHNEIDER H, WAGATHA P, et al .. Toward new phosphors for application in illumination-grade white pc-LEDs:the nitridomagnesosilicates Ca[Mg 3 SiN 4 ]:Ce 3+ , Sr[Mg 3 SiN 4 ]: Eu 2+ , and Eu[Mg 3 SiN 4 ][J] . Chem. Mater ., 2014, 26(8):2712-2719.

SCHMIECHEN S, STROBEL P, HECHT C, et al .. Nitridomagnesosilicate Ba[Mg 3 SiN 4 ]: Eu 2+ and structure-property relations of similar narrow-band red nitride phosphors[J]. Chem.Mater ., 2015, 27(5):1780-1785.

PUST P, HINTZE F, HECHT C, et al .. Group(Ⅲ) nitrides M [Mg 2 Al 2 N 4 ]( M =Ca, Sr, Ba, Eu) and Ba[Mg 2 Ga 2 N 4 ]-structural relation and nontypical luminescence properties of Eu 2+ doped samples[J]. Chem. Mater ., 2014, 26(21):6113-6119.

MEIJERINK A. Emerging substance class with narrow-band blue/green-emitting rare earth phosphors for backlight display application[J]. Sci.China Mater ., 2019, 62(1):146-148.

STROBEL P, MAAK C, WEILER V, et al .. Ultra-narrow-band blue-emitting oxoberyllates AE Li 2 [Be 4 O 6 ]: Eu 2+ ( AE =Sr, Ba) paving the way to efficient RGB pc-LEDs[J]. Angew. Chem. Int. Ed ., 2018, 57(28):8739-8743.

DUTZLER D, SEIBALD M, BAUMANN D, et al .. Synthetic and structural investigations on the system Na 1- x Eu x [Li 3-2 x -Si 1- x Al 3 x O 4-4 x N 4 x ][J] . Eur. J. Inorg. Chem ., 2019, 2019(25):2958-2963.

ZHAO M, LIAO H X, NING L X, et al .. Next-generation narrow-band green-emitting RbLi(Li 3 SiO 4 ) 2 : Eu 2+ phosphor for backlight display application[J]. Adv. Mater ., 2018, 30(38):1802489.

PUST P, WOCHNIK A S, BAUMANN E, et al .. Ca[LiAl 3 N 4 ]: Eu 2+ -a narrow-band red-emitting nitridolithoaluminate[J]. Chem. Mater ., 2014, 26(11):3544-3549.

HOERDER G J, SEIBALD M, BAUMANN D, et al .. Sr[Li 2 Al 2 O 2 N 2 ]: Eu 2+ -a high performance red phosphor to brighten the future[J]. Nat. Commun ., 2019, 10:1824-1-9.

DUTZLER D, SEIBALD M, BAUMANN D, et al .. Alkali lithosilicates:renaissance of a reputable substance class with surprising luminescence properties[J]. Angew. Chem. Int. Ed ., 2018, 57(41):13676-13680.

LIAO H X, ZHAO M, ZHOU Y Y, et al .. Polyhedron transformation toward stable narrow-band green phosphors for wide-color-gamut liquid crystal display[J]. Adv. Funct.Mater ., 2019, 29(30):1901988-1-7.

LIAO H X, ZHAO M, MOLOKEEV M S, et al .. Learning from a mineral structure toward an ultra-narrow-band blue-emitting silicate phosphor RbNa 3 (Li 3 SiO 4 ) 4 : Eu 2+ [J]. Angew. Chem.Int.Ed ., 2018, 57(36):11728-11731.

ZHAO M, ZHOU Y Y, MOLOKEEV M S, et al .. Discovery of new narrow-band phosphors with the UCr 4 C 4 -related type structure by alkali cation effect[J]. Adv. Opt.Mater ., 2019, 7(6):1801631.

WANG W, TAO M X, LIU Y X, et al .. Photoluminescence control of UCr 4 C 4 -type phosphors with superior luminous efficiency and high color purity via controlling site selection of Eu 2+ activators[J]. Chem.Mater. , 2019, 31(21):9200-9210.

DUTZLER D, SEIBALD M, BAUMANN D, et al .. RbKLi 2 [Li 3 SiO 4 ] 4 : Eu 2+ an ultra narrow-band phosphor[J]. Z.Naturforsch . B, 2019, 74(7-8):535-546.

RUEGENBERG F, SEIBALD M, BAUMANN D, et al .. A double-band emitter with ultranarrow-band blue and narrow-band green luminescence[J]. Chem. Eur. J ., 2020, 26(10):2204-2210.

HOFFMANN J, BRANDES R, HOPPE R. Neue silicate mit "stuffed pyrgoms":CsKNaLi 9 {Li[SiO 4 ]} 4 , CsKNa 2 Li 8 {Li-[SiO 4 ]} 4 , RbNa 3 Li 8 {Li[SiO 4 ]} 4 [1] und RbNaLi 4 {Li[SiO 4 ]} 2 [2][J] . Z. Anorg Allg. Chem ., 1994, 620(9):1495-1508.

ZHAO M, CAO K, LIU M J, et al .. Dual-shelled RbLi(Li 3 SiO 4 ) 2 : Eu 2+ @Al 2 O 3 @ODTMS phosphor as a stable green emitter for high-power LED backlights[J]. Angew. Chem. Int. Ed ., 2020, 59(31):12938-12943.

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